A print head is disclosed for use with an additive manufacturing system. The print head may include a nozzle tip, a first matrix source configured to selectively supply a structural matrix to the nozzle tip, and a second matrix source configured to selectively supply a temporary support matrix to the nozzle tip. The print head may also include a reinforcement supply configured to supply a continuous reinforcement through the nozzle tip only when the first matrix source is supplying the structural matrix to the nozzle tip.

A method of forming a three-dimensional object is carried out by: (a) providing a cyanate ester dual cure resin; (b) forming a three-dimensional intermediate from said resin, where said intermediate has the shape of, or a shape to be imparted to, said three-dimensional object, and where said resin is solidified by exposure to light; (c) optionally washing the three-dimensional intermediate, and then (d) heating and/or microwave irradiating said three-dimensional intermediate sufficiently to further cure said resin and form said three-dimensional object. Compositions useful for carrying out the method, and products made from the method, are also described.

The present disclosure is directed to additive manufacturing cartridges having an oxygen impermeable layer and to processes for producing cured polymeric products by additive manufacturing wherein the oxygen content during additive manufacturing is limited such as by use of the cartridge and/or by use of an inert gas.

The present application provides not only a heating device for additive manufacturing but also a heating module and a manufacturing apparatus utilizing the heating device. The heating device utilizes a rotational reflective cover to modulate a heating direction of a heating source, which expands an area correspondingly irradiated by the heating source and enhances uniformity of heating. Besides, the heating modules can be coupled and controlled by a controlling subsystem so as to respectively irradiate different areas with ranges at least partially intersecting each other, which also improves heating uniformity for heating a large area.

A method of activating a surface of a plastics substrate formed from: (a) polyaryletherketone such as polyether ether ketone (PEEK) polyether ketone ketone (PEKK), polyether ketone (PEK); polyether ether ketone ketone (PEEKK); or polyether ketone ether ketone ketone (PEKEKK); (b) a polymer containing a phenyl group directly attached to a carbonyl group, for example polybutadiene terephthalate (PBT) optionally wherein the carbonyl group is part of an amide group, such as polyarylamide (PARA); (c) polyphenylene sulfide (PPS); or (d) polyetherimide (PEI); for subsequent bonding, the method comprising the step of exposing the surface to actinic radiation wherein the actinic radiation: includes radiation with wavelength in the range from about 10 nm to about 1000 nm; the energy of the actinic radiation to which the surface is exposed is in the range from about 0.5 J/cm.sup.2 to about 300 J/cm.sup.2.

Hard to bond substrates are then more easily subsequently bonded for example using acrylic, epoxy or anaerobic adhesive.

According to examples, an apparatus includes a processor and a memory on which is stored machine readable instructions. The instructions may cause the processor to identify an intended surface property level for a surface of a three-dimensional (3D) object, determine an amount of radiation to be applied as a flash of radiation onto the surface to obtain the intended surface property level, and output the determined amount of radiation to be applied as a flash of radiation, in which a radiation source is to flash apply the determined amount of radiation onto the surface of the 3D object.

A method of forming a three-dimensional object is carried out by: (a) providing a cyanate ester dual cure resin; (b) forming a three-dimensional intermediate from said resin, where said intermediate has the shape of, or a shape to be imparted to, said three-dimensional object, and where said resin is solidified by exposure to light; (c) optionally washing the three-dimensional intermediate, and then (d) heating and/or microwave irradiating said three-dimensional intermediate sufficiently to further cure said resin and form said three-dimensional object. Compositions useful for carrying out the method, and products made from the method, are also described.

According to examples, an apparatus includes a processor and a memory on which is stored machine readable instructions. The instructions may cause the processor to identify an intended surface property level for a surface of a three-dimensional (3D) object, determine an amount of radiation to be applied as a flash of radiation onto the surface to obtain the intended surface property level, and output the determined amount of radiation to be applied as a flash of radiation, in which a radiation source is to flash apply the determined amount of radiation onto the surface of the 3D object.

According to an example, in a method, a radiation source that is to output radiation at a preset energy level onto a surface of a three-dimensional (3D) printed object may be activated. In addition, the radiation source may be deactivated after a predefined period of time sufficient to cause an outer portion of about a predetermined thickness of the surface of the 3D printed object to begin to melt to finish the surface of the 3D printed object.

The present application describes a system for curing moldable material. The system comprises an energy source, a mold, and/or other components. The mold comprises internal mold surfaces forming a mold cavity. The mold is formed from one or more materials configured to absorb electromagnetic radiation emitted by the energy source. The mold has a hot zone and a cold zone. The hot zone and the cold zone have the one or more materials thereof comprising at least one different physical characteristic so that the hot zone and the cold zone absorb the electromagnetic radiation at different rates and/or in different amounts. The hot zone absorbs more electromagnetic radiation than, and/or electromagnetic radiation faster than, the cold zone.