A method comprising: digital printing a heat curable aqueous composition onto a substrate, wherein the composition comprises: (a) at least one water soluble synthetic alkali metal silicate; and (b)(i) at least one pigment or (b)(ii) at least one additive selected from aluminum oxide, ceramic microspheres, recycled ground glass, or calcium carbonate; and wherein the substrate comprises a material selected from glass, ceramic, textile, polymeric, metal, wood, or a combination thereof.

A solvent type curable ink for ink-jet printing obtained by dissolving or dispersing, in a volatile organic solvent, polyesterpolyol having a molecular weight of not more than 8000, a hydroxyl value (KOH mg/g) of 17 to 50 and a glass transition point (Tg) of not higher than 70° C., and blocked polyisocyanate. The ink is capable of forming ink-jet-printed image on the surfaces of various kinds of formed articles without burring and maintaining close adhesion upon being heated at a low temperature for a short period of time.

A method of inkjet printing includes the steps of: printing a first ink onto a print medium, the first ink including a first self-dispersible pigment, the first ink having a first pigment content A; and subsequently printing a second ink onto the print medium at least partially over the first ink, the second ink including a second pigment and a polymeric dispersant encapsulating the second pigment, the second ink having a second pigment content B. The first self-dispersible pigment and the second pigment have a same color; the pigment content A of the first ink and the pigment content B of the overprinted second ink have a relationship 0.8≦A/B≦1.2; and a polymer acid value of the polymeric dispersant is in the range of 100 to 170.

The present invention relates to an aqueous reaction liquid composition including an anti-deforming agent. selected from the group consisting of a choline salt (formate, acetate, chloride), a guanidine salt (formate, acetate, chloride), trimethylglycine (betaine), potassium formate and ammonium nitrate. The present invention also relates to an aqueous reaction liquid composition including a Deep Eutectic Solvent (DES) having urea in combination with an anti-deforming agent as disclosed above. In another aspect the invention relates to an ink set including such aqueous reaction liquid composition and an ink composition, preferably a pigmented ink composition. In another aspect the present invention relates to a printing method including application of an aqueous reaction liquid composition according to the present invention and application of an ink composition.

Provided is an ink jet recording method including: discharging an ultraviolet ray-curable ink, which has a viscosity at 20° C. of 25 mPa.Math.s or less and an average equivalent of polymerizable unsaturated double bond of 100 to 150, from a head onto a recording medium at a discharge temperature of 30° C. to 40° C.; and irradiating the ultraviolet ray-curable ink, attached onto the recording medium, with ultraviolet rays emitted from a light source to cure the ultraviolet ray-curable ink.

A manufacturing method for decorating natural leather with a decorative image includes applying on a crusted leather a base coat containing a pigment for providing a chromatic colour or an achromatic colour different from black, inkjet printing a colour image on the base coat using one or more pigmented UV curable inkjet inks, optionally applying a protective top coat on the image, and optionally applying a heat pressing or embossing step, wherein the chromatic colour or the achromatic colour different from black of the base coat and the inkjet printed colour image are used in combination to provide the decorative image.

An image recording method including the steps of applying a liquid composition to a recording medium and applying an ink containing a pigment to the recording medium so as to overlap at least with a part of a region of the recording medium to which the liquid composition is applied. The water absorption amount of the recording medium at a contact time of 1 second according to the Bristow's method is 15 ml/m.sup.2 or less. The ink contains a compound having a polyoxyalkylene unit. The liquid composition contains a tannin compound.

An indirect inkjet printing method including providing a jettable ink composition, jetting said ink composition on a surface of an intermediate transfer member forming a film having an image thereon, and transferring said image to a printable substrate. The jettable ink composition includes a hydrocarbon carrier liquid, colorant and polymeric binder resin which is soluble in the hydrocarbon carrier liquid.

A fluid set can include an ink composition having an acidic pH and a crosslinker composition having a basic pH from pH 8 to pH 10. The ink composition can include from 60 wt % to 90 wt % water, from 5 wt % to 30 wt % organic co-solvent, from 1 wt % to 6 wt % pigment, a sulfonated dispersant, and an acrylic polymer binder. The crosslinker composition can include from 70 wt % to 95 wt % water, from 1 wt % to 25 wt % organic co-solvent, and from 0.5 wt % to 5 wt % polycarbodiimide.

An aqueous ink set for ink jet including a combination of a first ink and a second ink. The first ink includes a self-dispersible pigment to a particle surface of which a functional group that includes a phosphonic acid group is bonded, wherein the redispersion viscosity of the first ink is 5 mPa.Math.s or less. The second ink includes an anionic dye, a lithium ion, and a sodium ion, wherein the total concentration of the lithium ion and the sodium ion in the second ink is 0.050 mol/L or more, and the proportion of the concentration of the lithium ion in the total concentration of the lithium ion and the sodium ion in the second ink is 45% or more to 85% or less.