In one aspect, catalytic assemblies are described herein. A catalytic assembly, in some embodiments, comprises a plurality of honeycomb catalyst segments bonded to one another by a bonding material, the honeycomb catalyst segments comprising an outer peripheral wall and a plurality of inner partition walls defining flow channels extending longitudinally through the catalyst segments, wherein the outer peripheral wall and inner partition walls have dispersed throughout a chemical composition comprising 50-99.9 weight percent an inorganic oxide composition and at least 0.1 weight percent a catalytically active metal functional group.

The present disclosure relates to porous ceramic articles and a method of making the same. The porous ceramic articles have microstructure of sinter bonded or reaction bonded large pre-reacted particles and pore network structure exhibiting large pore necks. The method of making the porous ceramic articles involves using pre-reacted particles having one or more phases. A plastic ceramic precursor composition is also disclosed. The composition includes a mixture of at least one of dense, porous, or hollow spheroidal pre-reacted particles and a liquid vehicle.

There is provided a honeycomb structure where a crack at honeycomb segments, which constitute a honeycomb bonded assembly, is reduced. A honeycomb structure has a pillar-shaped honeycomb bonded assembly that has a plurality of pillar-shaped honeycomb segments having a porous partition wall defining a plurality of cells extending from an inflow end face as one end face to an outflow end face as another end face and becoming channels for a fluid, and a bonding layer bonding side surfaces of the plurality of honeycomb segments, and in the honeycomb bonded assembly, at 25 to 800 C., a thermal expansion coefficient of the bonding layer is larger than a thermal expansion coefficient of the honeycomb segment.

There is provided a honeycomb structure where a crack at a honeycomb substrate is reduced. A honeycomb structure has a honeycomb substrate that has a porous partition wall defining a plurality of cells extending from an inflow end face as one end face to an outflow end face as another end face and becoming channels for a fluid, and an outer circumference coating layer disposed at an outer circumference of the honeycomb substrate. At 25 to 800 C., a thermal expansion coefficient of the outer circumference coating layer is larger than a thermal expansion coefficient of the honeycomb substrate. The thermal expansion coefficients of the outer circumference coating layer and the thermal expansion coefficient at 25 to 800 C. preferably meet a relationship represented by the expression: 1.1<(the thermal expansion coefficient of the outer circumference coating layer/the thermal expansion coefficient of the honeycomb substrate)<40.

A honeycomb catalyst support structure including a honeycomb body and an outer layer or skin formed of a cement is described. The cement includes an amorphous glass powder with a multimodal particle size distribution applied to an exterior surface of the honeycomb body. The multimodal particle size distribution is achieved through the use of a first glass powder having a first median particle size and at least a second glass powder having a second median particle size. In some embodiments, the first and second glass powders are the same amorphous glass consisting of fused silica. The cement may further include a fine-grained, sub-micron sized silica in the form of colloidal silica. The cement exhibits a coefficient of thermal expansion less than 1510.sup.7/ C., and preferably about 510.sup.7/ C. after drying.

There is disclosed a plugged honeycomb structure. A plugged honeycomb structure includes a honeycomb structure body of a segment structure and plugging portions disposed in open ends of cells formed in the honeycomb structure body, the honeycomb structure body has outer segments and inner segments disposed on an inner side than the outer segments in a cross section of the honeycomb structure body, and a material constituting the outer segments has a smaller heat capacity per unit volume than a material constituting the inner segments.

A pillar shaped honeycomb structure includes: an outer peripheral wall; and porous partition walls disposed on an inner side of the outer peripheral wall, the partition walls defining a plurality of cells, each of the cells extending from one end face to other end face to form a flow path, wherein the cells include a plurality of wire pieces made of a magnetic substance, the wire pieces being provided apart from each other via spaces or buffer materials in an extending direction of the cells.

A pillar-shaped honeycomb structure, wherein a cell density based on a total number of a plurality of inlet cells and a plurality of outlet cells is 22 to 70 cells/cm.sup.2, wherein a thickness of each of partition walls is in a range of 0.15 mm or more and 0.38 mm or less, wherein an opening ratio at an inlet end surface is 44% or more, and wherein assuming a total surface area of all partition walls partitioning the plurality of inlet cells excluding the inlet cells adjacent to an outer peripheral side wall is S.sub.1, and a total surface area of all partition walls sandwiched between adjacent inlet cells among the plurality of inlet cells excluding the inlet cells adjacent to the outer peripheral side wall is S.sub.2, 33%S.sub.2/S.sub.175% is satisfied.

A pillar shaped honeycomb structure, including: an outer peripheral wall; and porous partition walls disposed inside the outer peripheral wall, the partition walls defining a plurality of cells, each of the cells penetrating from one end face to other end face to form a flow path, wherein one or both of the one end face and the other end face includes a groove portion; and wherein at least one annular conductive loop containing a conductive material is embedded in the groove portion.

A honeycomb filter includes: a honeycomb substrate having porous partition walls disposed so as to surround cells extending from an inflow end face to an outflow end face, an outer peripheral coating layer disposed so as to surround an outer periphery of the honeycomb substrate, and plugging portions that are disposed at any one of ends on the inflow end face and ends on the outflow end face, of the cells, wherein, the outer peripheral coating layer has an inflection point at which thermal expansion in thermal expansion behavior of the outer peripheral coating layer turns to contraction and a temperature T1 of which is 1000 to 1500 C., and the outer peripheral coating layer has a porosity P1 of 36 to 48%, and a thermal expansion coefficient C1 between 40 to 800 C. of 2.5 to 3.510.sup.6/ C.