Provided are catalyst articles, methods of manufacturing catalyst articles, and methods for controlling emissions in diesel engine exhaust streams with catalyst articles, where the emission treatment system of various embodiments effectively treats diesel engine exhaust with a catalyst article. In one or more embodiments, the catalyst articles have a platinum group metal end coating covering an outlet end surface of the catalytic article. In one or more embodiments, a method is provided where an applicator transfers a platinum group metal coating to an outlet end face of a catalytic article.

An emissions control substrate for treating exhaust from an engine including a plurality of hexagonal cells extending between a first end and a second end of the substrate. Wash coats are at an interior of the hexagonal cells. At an inner region of the substrate through which a longitudinal axis of the emissions control substrate extends, for every group of three adjacent hexagonal cells of the plurality of hexagonal cells two are plugged at the first end and open at the second end, and one is open at the first end and plugged at the second end. At an outer region of the substrate surrounding the inner region, for every group of three adjacent hexagonal cells of the plurality of hexagonal cells, one is plugged at the first end and open at the second end, and two are open at the first end and plugged at the second end.

A honeycomb filter includes a pillar-shaped honeycomb structure having porous partition walls placed, surrounding a plurality of cells which serve as fluid through channels extending from an inflow end face to an outflow end face; and porous plugging portions provided either at the ends on the inflow end face side of the cells or at the ends on the outflow end face side of the cells, wherein the plugging portions include plugging portions that have voids therein, and in the plugging portions having the voids, porosity including the voids as pores ranges from 68% to 83%.

A honeycomb structure including a plurality of porous honeycomb block bodies bound via joining material layers A. Each of the porous honeycomb block bodies includes a plurality of porous honeycomb segments bound via joining material layers B, each of the porous honeycomb segment includes: partition walls that defines a plurality of cells to form flow paths for a fluid, each of cells extending from an inflow end face that is an end face on a fluid inflow side to an outflow end face that is an end face on a fluid outflow side; and an outer peripheral wall located at the outermost periphery. At least a part of the joining material layers A has higher toughness than that of the joining material layers B.

A honeycomb filter includes a pillar-shaped honeycomb structure having porous partition walls provided, surrounding a plurality of cells which serve as fluid through channels extending from an inflow end face to an outflow end face, and porous plugging portions provided either at the ends on the inflow end face or the outflow end face of the cells, wherein the plugging portions are composed of a porous material, the honeycomb structure has a central region and a circumferential region, and a ratio of an area of the circumferential region with respect to that of the central region ranges from 0.1 to 0.5, a plugging length L1 in the cell extending direction of a central plugging portion in the central region is larger than a plugging length L2 of a circumferential plugging portion in the circumferential region, L1 ranges from 7 to 9 mm, and L2 from 3 to 6 mm.

A plugged honeycomb structure has a plurality of cells defined by partition walls to become through channels for fluid, one end of each of the predetermined cells is plugged by a plugging member, the other end of each of the residual cells is plugged by the plugging member, the partition wall is made of a cordierite component as a main component, and a value obtained by dividing Young's modulus of a plugging structure portion formed by the partition walls and the plugging member by Young's modulus of a cell structure portion formed by the partition walls is in a range of 1.05 to 2.00.

A plugged honeycomb structure includes: a honeycomb substrate and a plugging portion, and is configured to trap particulate matter included in fluid flowing from an inflow side end face to an outflow side end face. The partition wall includes, as raw materials, particulates of a base material and a binder and having a melting point lower than that of the base material, the base material has a particle diameter in a range of 5 m to 60 m, a mass ratio of the binder to a total mass of the raw material of the base material and the binder is in a range of 22 mass % to 45 mass %, and the cells include round cells as a part, the round cells being defined by a circular-arc partition wall having a circular-arc shape that is at least a part of the partition wall to have a circular shape or the like.

A composition for applying to a honeycomb body includes a refractory filler, an organic binder, an inorganic binder, and a liquid vehicle, wherein the refractory filler, the particle size distribution of the refractory filler, the organic binder, and the inorganic binder are selected such that, when the composition is applied to plug a plurality of channels of the honeycomb body, the plug depth variability is reduced.

A plugged honeycomb structure includes a honeycomb structure body, and a plurality of plugging portions, the honeycomb structure body further includes pass-through hole portions each of which is formed in at least a part of a partition wall intersection portion in which the partition walls intersect in one end face and each of which interconnects a pair of cells facing each other at a position corresponding to the partition wall intersection portion to enable pass-through of a fluid, and a value obtained by dividing a diameter of a first virtual inscribed circle inscribed at a position of a minimum hole width of the pass-through hole portion by a diameter of a second virtual inscribed circle inscribed at a position of a minimum plugging width between the plugging portions facing each other is in a range of 0.05 to 0.74.

An exhaust gas purification filter includes a plurality of cells extending in a filter axial direction, a porous partition separating and defining the plurality of cells, and a sealing section sealing the plurality of cells alternately at both filter ends. In the exhaust gas purification filter, the partition has a void volume of a reduced dale, Vvv, and a material volume of a reduced peak, Vmp, as volume parameters determined in noncontact surface roughness measurement on a surface of the partition, with their total value being 1.8 m.sup.3/m.sup.2 or less.