In a method of hydroprocessing, hydrogen gas for the hydroprocessing reaction is combined with a liquid feed composition comprising a feedstock to be treated and a diluent to form a feed stream, at least a portion of the hydrogen gas being dissolved in the liquid feed composition of the feed stream, with non-dissolved hydrogen gas being present in the feed stream in an amount of from 1 to 70 SCF/bbl of the liquid feed composition. The feed stream is contacted with a hydroprocessing catalyst, within a reactor while maintaining a liquid mass flux within the reactor of at least 5000 lb/hr.Math.ft.sup.2 to form a hydroprocessed product.

Producing C5 olefins from steam cracker C5 reeds may include reacting a mixed hydrocarbon stream comprising cyclopentadiene, C5 olefins, and C6+ hydrocarbons in a dimerization reactor where cyclopentadiene is dimerized to dicyclopentadiene. The dimerization reactor effluent may be separated into a traction comprising the C6+ hydrocarbons and dicyclopentadiene and a second fraction comprising C5 olefins and C5 dienes. The second fraction, a saturated hydrocarbon diluent stream, and hydrogen may be fed to a catalytic distillation reactor system for concurrently separating linear C5 olefins from saturated hydrocarbon diluent, cyclic C5 olefins, and C5 dienes contained in the second fraction and selectively hydrogenating C5 dienes. An overhead distillate including the linear C5 olefins and a bottoms product including cyclic C5 olefins are recovered from the catalytic distillation reactor system. Other aspects of the C5 olefin systems and processes, including catalyst configurations and control schemes, are also described.

Producing C5 olefins from steam cracker C5 feeds may include reacting a mixed hydrocarbon stream comprising cyclopentadiene, C5 olefins, and C6+ hydrocarbons in a dimerization reactor where cyclopentadiene is dimerized to dicyclopentadiene. The dimerization reactor effluent may be separated into a fraction comprising the C6+ hydrocarbons and dicyclopentadiene and a second fraction comprising C5 olefins and C5 dienes. The second fraction, a saturated hydrocarbon diluent stream, and hydrogen may be fed to a catalytic distillation reactor system for concurrently separating linear C5 olefins from saturated hydrocarbon diluent, cyclic C5 olefins, and C5 dienes contained in the second fraction and selectively hydrogenating C5 dienes. An overhead distillate including the linear C5 olefins and a bottoms product including cyclic C5 olefins are recovered from the catalytic distillation reactor system. Other aspects of the C5 olefin systems and processes, including catalyst configurations and control schemes, are also described.

The invention is a naphtha hydrotreating process, using at least three catalysts, comprising: a first step a) in the presence of the first catalyst comprising a support; a second step b) in the presence of the second catalyst comprising a support and an active phase, said active phase containing a Group 9 or 10 metal and a Group 6 metal; a third step c) in the presence of the third catalyst comprising a support and an active phase, said active phase containing a Group 6 metal; the content of Group 6 metal of the third catalyst is less than the content of Group 6 metal of said second catalyst; the ratio of the loaded specific surface area of said first catalyst to that of said second catalyst is greater than or equal to 1.20; the ratio of the loaded specific surface area of said third catalyst to that of said second catalyst is greater than 1.07.

The invention relates to a process and a plant for producing an olefins-containing hydrocarbon product by reaction of an oxygenates-containing reactant mixture, which is divided into a plurality of reactant mixture substreams, in a multi-stage oxygenate-to-olefin (OTO) synthesis reactor comprising a plurality of serially connected reaction sections comprising catalyst zones, wherein a feeding apparatus for a reactant mixture substream is arranged upstream of each catalyst zone. In each of these reaction sections a reactant mixture substream is introduced and therein under oxygenates conversion conditions converted into olefins and further hydrocarbons, wherein all reaction sections save for the first are additionally supplied with the product stream from the respective upstream reaction section. In addition at least one steam stream is introduced into at least one reaction section and at least one hydrocarbons-containing recycle stream is introduced into at least one reaction section. The OTO synthesis reactor product is fractionated in a multi-stage workup apparatus to obtain a plurality of hydrocarbon product fractions of which at least one is recycled to the OTO synthesis reactor as a recycle stream. According to the invention all reactant mixture substreams, steam streams and recycle streams are introduced into the OTO synthesis reactor in gaseous/vaporous form.

The present invention concerns a device for filtration and distribution of a gaseous phase and a liquid phase, which can be disposed upstream of a fixed catalytic bed of a reactor operating with a descending co-current of gas and liquid, comprising: a solid plate on which substantially vertical risers are fixed, said risers are open at their upper and lower ends and have openings over at least a fraction of their height; a plurality of removable baskets capable of retaining at least one filtration medium, each removable basket being defined by an ellipsoidal vertical wall or by at least three vertical lateral walls and a bottom, the vertical walls and/or the bottom being permeable to a gas and to liquid.

Each basket is provided support means cooperating with a riser of the plate in order to support the basket.

Axial reactor for exothermic or endothermic chemical reactions, comprising at least a first catalytic bed (3) and a second catalytic bed (4) operating in series and at least one heat exchanger (5) between the two catalytic beds, wherein the first catalytic bed has a collector bottom (6) having a box-like structure with flat and parallel walls, which are gas-permeable, and a plurality of parallel channels (15, 16) defined between the walls, wherein a first series of said channels collects the gaseous flow exiting the catalytic bed and passing through the first wall, said gaseous flow is directed towards the heat exchanger, and the flow exiting the exchanger is directed towards the second catalytic bed via a second series of said channels of the collector bottom.

A method for preparing methyl methacrylate from methacrolein and methanol. The method comprises contacting in a tubular reactor having at least four zones a mixture comprising methacrolein, methanol, oxygen and a base with a catalyst bed of heterogeneous catalyst comprising a support and a noble metal, wherein reaction zones comprising catalyst beds alternate with mixing zones not comprising catalyst beds.

Incorporating into a fixed bed reactor for an exothermal reaction having a catalyst supported on a support having a thermal conductivity typically less than 30 W/mk within the reaction temperature control limits heat dissipative particles having a thermal conductivity of at least 50 W/mk less than 30 W/mk within the reaction temperature control limits helps control the temperature of the reactor bed.

The invention relates to a device for the upflow of a single-phase fluid comprising at least two beds of solid particles and at least one bypass means for a portion of said fluid, and also to the use thereof.