A process for reducing the environmental contaminants in a ISO 8217:2017 Table 2 compliant Feedstock Heavy Marine Fuel Oil and resulting product, the process involving: mixing a Feedstock Heavy Marine Fuel Oil with a Activating Gas to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture; separating the Product Heavy Marine Fuel Oil from the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil complies with ISO 8217:2017 Table 2 for residual marine fuel and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, are less than 0.5 wt. %. The Product Heavy Marine Fuel Oil can be used as blending stock for an ISO 8217:2017 Table 2 compliant, IMO 2020 compliant, low sulfur heavy marine fuel composition.

To allow hydrogen to be supplied to a dehydrogenation reaction unit for dehydrogenating an organic hydride by using a highly simple structure so that the activity of the dehydrogenation catalyst of the dehydrogenation reaction unit is prevented from being rapidly reduced. The hydrogen production system (1) comprises a first dehydrogenation reaction unit (3) for producing hydrogen by a dehydrogenation reaction of an organic hydride in presence of a first catalyst, and a second dehydrogenation reaction unit (4) for receiving a product of the first dehydrogenation reaction unit, and producing hydrogen by a dehydrogenation reaction of the organic hydride remaining in the product in presence of a second catalyst, wherein an amount of the first catalyst used in the first dehydrogenation reaction unit is equal to or less than an amount of the second catalyst used in the second dehydrogenation reaction unit, and an amount of hydrogen produced in the first dehydrogenation reaction unit is less than an amount of hydrogen produced in the second dehydrogenation reaction unit.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

Systems for upgrading pyrolysis oil include a first fixed-bed reactor having a first catalyst bed and a second catalyst bed. The first catalyst bed includes: a first treating catalyst containing alumina, binder, Mo, Ni, and P; a second treating catalyst made of Al.sub.2O.sub.3, SiO.sub.2, ZrO.sub.2, NiO, and WO.sub.3; or both. The second catalyst bed includes mixed metal oxide catalyst. The first fixed-bed reactor contacts the pyrolysis oil with hydrogen in the presence of the treating catalyst and the mixed metal oxide catalyst to produce an intermediate stream comprising light aromatic compounds. The system includes a second fixed-bed reactor downstream that includes a mesoporous supported metal catalyst having nickel and tungsten on a mesoporous support. The second fixed-bed reactor contacts the intermediate stream with hydrogen in the presence of the mesoporous supported metal catalyst to produce a second reactor effluent comprising aromatic compounds having six to eight carbon atoms.

A process for preparing succinic anhydride by hydrogenation of maleic anhydride includes the steps of: 1) mixing a maleic anhydride solution with hydrogen to obtain a first liquid phase feed; 2) carrying out a first hydrogenation reaction by passing the first liquid phase feed from bottom to top through fixed bed layer(s) of a first maleic anhydride hydrogenation catalyst arranged in a first reaction unit under first hydrogenation reaction conditions to obtain a first reaction effluent containing succinic anhydride; 3) mixing the first reaction effluent from the first reaction unit with make-up hydrogen to obtain a second liquid phase feed; and 4) carrying out a second hydrogenation reaction by passing the second liquid phase feed from bottom to top through fixed bed layer(s) of a second maleic anhydride hydrogenation catalyst arranged in a second reaction unit under second hydrogenation reaction conditions to obtain a second reaction effluent containing succinic anhydride.

A multi-stage process for the production of an ISO8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core process under reactive conditions in a Reaction System composed of one or more reaction vessels, wherein one or more of the reaction vessels contains one or more catalysts in the form of a structured catalyst bed and is operated under reactive distillation conditions. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed.

A process for reducing the environmental contaminants in a ISO 8217:2017 Table 2 compliant Feedstock Heavy Marine Fuel Oil and resulting product, the process involving: mixing a Feedstock Heavy Marine Fuel Oil with a Activating Gas to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture; separating the Product Heavy Marine Fuel Oil from the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil complies with ISO 8217:2017 Table 2 for residual marine fuel and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, are less than 0.5 wt. %. The Product Heavy Marine Fuel Oil can be used as blending stock for an ISO 8217:2017 Table 2 compliant, IMO 2020 compliant, low sulfur heavy marine fuel composition.

The invention concerns a process and apparatus for cracking ammonia in which heated ammonia gas at super-atmospheric pressure is partially cracked in at least two adiabatic reactors in series with interstage heating in which the feed temperature to a first reactor is higher than the feed temperature to a further reactor to produce a partially cracked ammonia gas which is then fed to catalyst-containing reactor tubes in a furnace to produce a cracked gas comprising hydrogen gas, nitrogen gas and residual ammonia gas. The use of the adiabatic reactors enables more efficient heat integration within the process and the higher temperature in the first reactor enables the use of a nickel-based catalyst in that reactor as an alternative solution to the potential problem of the presence of oil in the ammonia.

A method for producing an alkylene carbonate using a first reaction vessel in which a reaction liquid containing a catalyst and carbon dioxide in a gaseous state are contained, comprising; a step (A) of feeding a raw material liquid containing an alkylene oxide through a nozzle so that the raw material liquid moves from the upper part of the first reaction vessel along the inner surface to the lower part thereof to feed the raw material liquid having dissolved carbon dioxide in the first reaction vessel to the reaction liquid; and a step (B) of reacting the alkylene oxide and carbon dioxide in the reaction liquid containing the catalyst in the lower part of the first reaction vessel to obtain the alkylene carbonate; wherein the ratio (DL/DT) of the height DL from the liquid level in the first reaction vessel to the discharge outlet of the nozzle to the height DT from the bottom tangent line of the first reaction vessel to the discharge outlet of the nozzle is 0.1 to 0.7.

A thermal configuration for use during sulfidation and operation is disclosed which may involve multiple of the following heating steps, (a) heating a process feed by a charge heater, heating (b) a process feed stream or a recycle oil stream by heat exchange with a process effluent, heating (c) a process feed stream or a recycle oil stream by heat exchange with a said process feed after having been heated in the charge heater. Furthermore, the steps may be made independent by controlling the ratio of the streams directed to (b) or (c), controlling an amount of feed stream or recycle oil stream by-passed around the heating of (b) or (c) and controlling the temperature of step (a).