B01J8/0457

Premixer, radially fixed bed reactor, reaction system for oxidative dehydrogenation

The present disclosure provides a premixer for at least two gases, comprising: a tubular body having a closed end and an opposite, open end; a first flow passage for receiving a first gas, the first flow passage axially extending through the closed end into the tubular body in a sealable manner; a conical tube arranged in the tubular body, wherein a small end of the conical tube communicates with the first flow passage, and a large end of the conical tube extends toward the open end with an edge thereof being fixed to an inner wall of the tubular body, thereby defining a sealed distribution chamber between the tubular body and the conical tube; and a second flow passage arranged on a side portion of the tubular body for receiving a second gas, wherein the second flow passage communicates with the distribution chamber, so that the second gas can be introduced into said conical tube via the distribution chamber in a substantially radial manner. The present disclosure further relates to a radially fixed bed reactor comprising the premixer, a reaction system of oxidative dehydrogenation of butene comprising the racially fixed bed reactor, and a corresponding process.

Method for producing A-hydroxyisobutyric acid amide and reactor

The present invention provides a method for producing α-hydroxyisobutyric acid amide by hydration of acetone cyanohydrin under the presence of a catalyst composed mainly of manganese oxide using a reactor in which at least two reaction regions are connected in series, the method being characterized by comprising: a step (B) of cyclically supplying at least a portion of a reaction liquid withdrawn from at least one reaction region to a first reaction region (I) in the reactor; and a step (b1) of further cyclically supplying at least a portion of the reaction liquid withdrawn from at least one reaction region to at least one reaction region other than the first reaction region. The method is also characterized in that an oxidizing agent is supplied to at least one reaction region in the reactor.

METHOD AND DEVICE SYSTEM FOR PRODUCING DIMETHYL OXALATE THROUGH MIDHIGH AND HIGH-PRESSURE CARBONYLATION OF INDUSTRIAL SYNTHESIS GAS AND PRODUCING ETHYLENE GLYCOL THROUGH DIMETHYL OXALATE HYDROGENATION
20170267615 · 2017-09-21 ·

A method and a device system for producing dimethyl oxalate through high-pressure carbonylation of industrial synthesis gases and producing ethylene glycol through dimethyl oxalate hydrogenation. The method comprises the following steps: adopting industrial NO, O.sub.2 and methanol as raw materials to perform an esterification reaction to produce methyl nitrite, then adopting industrial CO and methyl nitrite to perform a carbonylation reaction in a plate reactor to produce carbonylation products which mainly include dimethyl oxalate and dimethyl carbonate, separating the carbonylation products to obtain dimethyl carbonate products, and subsequently performing hydrogenation to dimethyl oxalate in the plate reactor to produce ethylene glycol products; and performing coupling recovery treatment to waste acid in the esterification reaction and purge gas in the carbonylation reaction for recycling. The system comprises an esterification reaction system, a carbonylation reaction system, a purge gases and waste acid coupling recovery system and a hydrogenation reaction system.

PROCESS FOR THE CONTROLLED OLIGOMERIZATION OF BUTENES

The selective dimerization of isoolefins, such as isobutene or isopentane, or mixtures thereof, may be conducted in a system including a series of fixed bed reactors and a catalytic distillation reactor. The system may provide for conveyance of the fixed bed reactor effluents, without componential separation, to a downstream reactor. It has been found that a high selectivity to the dimer may be achieved even though intermediate separation of the desired product from unreacted components between reactors is not performed. Further, embodiments provide for use of a divided wall column for recovery of a high purity dimer product, reducing unit piece count and plot size.

Multi-stage process and device for treatment heavy marine fuel oil and resultant composition including ultrasound promoted desulfurization

A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a ultrasound treatment process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

CO-PRODUCTION OF METHANOL, AMMONIA AND UREA
20210380427 · 2021-12-09 ·

A process and plant for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide is removed from flue gas from reforming section and used to convert partially or fully all ammonia into urea.

Process and Device for Producing Hydrogen, Carbon Monoxide and a Carbon-Containing Product
20210380417 · 2021-12-09 ·

The invention relates to a process for producing hydrogen, carbon monoxide and a carbon-containing product in at least one reaction apparatus, wherein the at least one reaction apparatus comprises a bed of carbon-containing material and is characterized in that the bed of carbon-containing material in the at least one reaction apparatus is alternately heated to a temperature of >800° C. and, no later than upon reaching a temperature of 1800° C., cooled to a maximum of 800° C., wherein hydrogen and carbon monoxide are produced during the heating phase and carbon and hydrogen are produced during the cooling phase.

PROCESS AND PLANT FOR PRODUCING METHANOL FROM SUBSTOICHIOMETRIC SYNTHESIS GAS
20220185752 · 2022-06-16 ·

Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example two-stage, heterogeneously catalyzed methanol synthesis, wherein the methanol product formed in every synthesis stage is separated by condensation and the remaining residual gas is supplied to the downstream synthesis stage or after separation of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention after each synthesis stage the residual gas streams have separated from them a respective purge stream, from which, using one or more hydrogen recovery apparatuses, hydrogen is separated and recycled to the first synthesis stage. The ratio of the individual purge streams and their total molar flow may optionally be varied to allow better control of the reaction in the individual synthesis stages and to allow reaction to the advancing deactivation of the catalysts present therein.

Heavy marine fuel oil composition

A process for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil (Feedstock), the process involving: mixing a quantity of the Feedstock with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid (Product) components of the Process Mixture from the gaseous components and by-product hydrocarbons of the Process Mixture and, discharging the Product. The Product is compliant with ISO standards for residual marine fuel oils and has a maximum sulfur content between the range of 0.05% wt. to 0.50% wt. The Product can be used as or as a blending stock for compliant, low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.

System and apparatus for testing and/or evaluating an industrial catalyst

The invention relates to an integrated process for assessing one or more properties of a catalyst. In the method, a standard chemical reactor or reactors is/are provided, and a bypass means is also provided, to transport a sample of whatever is added to the industrial reactor, to the test reactor. Both gases and liquids are transferred to the test reactor.