Patent classifications
B01J8/388
Steam-enhanced catalytic cracking of hydrocarbons to produce light olefins
A steam-assisted catalytic cracking process for a hydrocarbon feed is provided. The process includes: introducing the hydrocarbon feed, a fluid catalytic cracking (FCC) catalyst, and steam to a FCC reactor with a mass ratio of steam to hydrocarbon feed between 0.05 and 1.0; cracking the hydrocarbon feed in the presence of the FCC catalyst and steam to produce a cracked hydrocarbon feed and spent FCC catalyst, the spent FCC catalyst comprising coke deposits and hydrocarbon deposits; stripping the hydrocarbon deposits from the spent FCC catalyst with steam in a stripper to obtain a hydrocarbon-stripped spent FCC catalyst; regenerating the hydrocarbon-stripped spent FCC catalyst in a regenerator by subjecting the stripped spent FCC catalyst to heat in the presence of oxygen to combust the coke deposits on the stripped spent FCC catalyst and produce a regenerated FCC catalyst; recycling the regenerated FCC catalyst.
PROCESS AND REACTOR ASSEMBLY FOR THE ENHANCEMENT OF HYDRODYNAMICS IN A GAS-SOLIDS FLUIDIZED BED REACTOR
A process for polymerizing olefin monomer(s) in a gas-solids olefin polymerization reactor comprising a top zone; a middle zone, which comprises a top end in direct contact with said top zone and which is located below said top zone, the middle zone having a generally cylindrical shape; and a bottom zone, which is in direct contact with a bottom end of the middle zone and which is located below the middle zone; comprising the following steps: introducing a fluidization gas stream into the bottom zone; polymerizing olefin monomer(s) in the presence of a polymerization catalyst in a dense phase formed by particles of a polymer of the olefin monomer(s) suspended in an upwards flowing stream of the fluidization gas in the middle zone; introducing a jet gas stream through one or more jet gas feeding ports in a jet gas feeding area of the middle zone at the dense phase in the middle zone of the gas-solids olefin polymerization reactor; wherein the kinetic energy (E.sub.JG) input in the reactor by the jet stream is between 1.5 and 50 times higher than the kinetic energy (E.sub.FG) input in the reactor by the fluidization gas stream (FG).
Arrangement for and a method of controlling flow of solid particles and a fluidized bed reactor
An arrangement for controlling a flow of solid particles includes a vertical inlet pipe for directing solid particles downwards and having a bottom at a level L0, a first outlet chute and a second outlet chute in particle flow connection with the vertical inlet pipe and a fluidizing device for directing controlled first and second sub flows to the first and second outlet chutes. The arrangement includes a branch in particle flow connection with an opening on a side wall of the vertical inlet pipe for directing the first sub flow of solid particles to the first outlet chute and a horizontally extending intermediate pipe for directing the second sub flow of solid particles to the second outlet chute. The intermediate pipe includes at least one nozzle feeding fluidizing gas to the intermediate pipe and has a first end in particle flow connection with the bottom of the inlet pipe.
Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
An ebullated bed hydroprocessing system is upgraded and operated at modified conditions using a dual catalyst system to produce less fouling sediment. The less fouling sediment produced by the upgraded ebullated bed reactor reduces the rate of equipment fouling at any given sediment production rate and/or concentration compared to the sediment produced by the ebullated bed reactor prior to upgrading. In some cases, sediment production rate and/or concentration are maintained or increased, after upgrading the ebullated bed reactor, while equipment fouling is reduced. In other cases, sediment production rate and/or concentration are increased, after upgrading the ebullated bed reactor, without increasing equipment fouling. In some cases, sediment production rate and/or concentration are decreased by a given percentage, after upgrading the ebullated bed reactor, and the rate of equipment fouling is decreased by a substantially greater percentage.
FCC CO-PROCESSING OF BIOMASS OIL
Systems and methods are provided for co-processing of biomass oil in a fluid catalytic cracking (FCC) system that include recovering an additional source of H.sub.2 or synthesis gas from the overhead product gas stream. The additional H.sub.2 can be used to partially hydrogenate biomass oil prior to co-processing the biomass oil in the fluid catalytic cracking system. Additionally or alternately, the additional synthesis gas can represent an additional yield of products from the process, such as an additional yield that can be used for synthesis of further liquid products.
Method for Catalytic Conversion of Hydrocarbon with Downer Reactor and Device Thereof
Provided are a method for the catalytic conversion of hydrocarbons with a downer reactor and a device thereof. The specific process of the method is as follows: a raw material of hydrocarbons after being pre-heated (or not) and a low-temperature regenerant from a regenerant cooler entering an entry end of a downer reactor, flowing down along the reactor for reactions such as catalytic cracking, and a mixture of a reactive oil and gas and a catalyst descending to the end of the reactor for rapid separation, thereby achieving the rapid separation of the catalyst and the oil and gas. The main operation conditions thereof are as follows: the reaction temperature is 460 to 680° C., the reaction pressure is 0.11 to 0.4 MPa, the contact time is 0.05 to 2 seconds, and the weight ratio of the catalyst to the raw material (a catalyst-to-oil ratio) is 6 to 50. The separated catalyst to be regenerated (abbreviated as a spent agent) is stripped by means of a stripper, and enters a regenerator and is burned for regeneration, wherein the regeneration temperature is controlled at 630-730° C. The regenerant from the regenerator enters the regenerant cooler to be cooled to 200-720° C., and then enters the downer reactor for recycling
ETHYLENE POLYMERIZATION PROCESSES AND REACTOR SYSTEMS FOR THE PRODUCTION OF MULTIMODAL POLYMERS USING COMBINATIONS OF A LOOP REACTOR AND A FLUIDIZED BED REACTOR
Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.
Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.
Mixing tee assembly and process
A mixing tee assembly suitable for phosphate acid attack reaction is described. The mixing tee assembly comprises an outer pipe having a mixing end and a tee end, wherein a tee structure is formed near the tee end to connect with additional piping; an inner pipe comprising a nozzle end connected to a nozzle and a open end; wherein the inner pipe is lined with a corrosion-resistant material on its inside surface; wherein when the inner pipe is assembled within the outer pipe, the nozzle extends beyond the mixing end of the outer pipe by at least ⅓ of the inside diameter of the outer pipe.
Process and apparatus for removing polymer material from a gas-solids olefin polymerization reactor
The present invention relates to a process for removing polymer material from a gas-solids olefin polymerization reactor wherein the gas-solids olefin polymerization reactor is connected to the top part of an outlet vessel via a feed pipe wherein the powder surface of discharged polymer material and the barrier gas injection point are situated in the outlet vessel as such to fulfill the following criteria: R′=X/Y≤2.0; and R″=X/D≥1.0; wherein X=Distance between the powder surface and the barrier gas injection point; Y=Distance between the barrier gas injection point and the vessel outlet; and D=Equivalent outlet vessel diameter, an apparatus for continuously removing polymer material comprising a gas-solids olefin polymerization reactor, an outlet vessel and a feed pipe connecting the gas-solids olefin polymerization reactor with the top part of the outlet vessel and the use of said apparatus for polymerizing alpha-olefin homo- or copolymers having alpha-olefin monomer units of from 2 to 12 carbon atoms and for increasing the barrier gas efficiency of the gas-solids olefin reactor to at least 75%.