Patent classifications
B01J23/644
METHOD FOR PREPARING A MULTI-METAL CATALYST HAVING AN OPTIMIZED SITE PROXIMITY
The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.
Oxidation catalyst for a diesel engine exhaust
An oxidation catalyst is described for treating an exhaust gas produced by a diesel engine comprising a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi) or an oxide thereof; an alkali metal or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material comprising a mixed oxide of alumina and silica, a mixed oxide of silica and a refractory oxide, a composite oxide of alumina and silica, a composite oxide of silica and a refractory oxide, alumina doped with a silica or silica doped with a refractory oxide.
Catalyst capable of directly decomposing urea and method for urea decomposition using the same
The present disclosure relates to a catalyst for directly decomposing urea, a method for preparing the same and a system for decomposing urea including the same, whereby the efficiency of decomposing urea to ammonia may be improved while preventing the formation of a byproduct such as biuret at temperatures of 200° C. or below by controlling the oxygen composition of the catalyst including titania and ceria.
Method for producing catalyst for air secondary battery, method for producing air secondary battery, catalyst for air secondary battery, and air secondary battery
A battery includes an electrode group including an air electrode and a negative electrode stacked with a separator therebetween, and an accommodating bag accommodating the electrode group along with an alkali electrolyte solution. The air electrode includes a catalyst for an air secondary battery. This catalyst for an air secondary battery is produced by a method for producing a catalyst for an air secondary battery, the method including a precursor preparation step of preparing a bismuth-ruthenium oxide precursor, a calcination step of calcining the bismuth-ruthenium oxide precursor obtained in this precursor preparation step to form a bismuth-ruthenium oxide, and a nitric acid treatment step of immersing the bismuth-ruthenium oxide obtained by this calcination step in a nitric acid aqueous solution.
CATALYST CAPABLE OF DIRECTLY DECOMPOSING UREA AND METHOD FOR UREA DECOMPOSITION USING THE SAME
The present disclosure relates to a catalyst for directly decomposing urea, a method for preparing the same and a system for decomposing urea including the same, whereby the efficiency of decomposing urea to ammonia may be improved while preventing the formation of a byproduct such as biuret at temperatures of 200 C. or below by controlling the oxygen composition of the catalyst including titania and ceria.
CONVERSION OF 1,2,5,6-HEXANETETROL (HTO) TO TETRAHYDROFURAN dicarboxylic acid (THFDCA)
Disclosed herein are methods for synthesizing useful intermediates and/or products from 1,2,5,6-hexanetetrol (HTO), which itself can be derived from a sugar. In an aspect, a process is provided for production of THFDCA from 1,2,5,6-hexanetetrol (HTO). The process comprises the steps of (a) ring closing to form a ring compound and (b) oxidizing using a catalyst comprising platinum and bismuth to form an acid mixture. Step (a) may be performed before or after step (b).
Denitration catalyst and denitration device
A denitration catalyst for removing nitrogen oxide in an exhaust gas is represented by the following chemical formula: Ba.sub.3Y.sub.(4-x)A.sub.xO.sub.9, wherein A is an element selected from the group consisting of Bi, Sn, Ga, Mn, Ti, and Al; and X is 0.4 or more and 2 or less. A denitration device has the denitration catalyst for removing nitrogen oxide in an exhaust gas discharged from an exhaust gas generation source including a gas engine, a gas turbine, a melting furnace, or a boiler.
Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
A method for preparing methyl methacrylate from methacrolein and methanol; said method comprising contacting in a reactor a mixture comprising methacrolein, methanol and oxygen with a catalyst bed of heterogeneous catalyst comprising a support and a noble metal, wherein mass transfer rate of oxygen in hour.sup.1 divided by space-time yield in moles methyl methacrylate/kg.Math.catalyst hour in the catalyst bed is at least 20.
Process for producing hydrofluoroolefin
A method for producing a hydrofluoroolefin is provided. The formation of by-products of an over-reduced product having hydrogen added to a material chlorofluoroolefin and an over-reduced product having not only chlorine atoms but also fluorine atoms in the chlorofluoroolefin replaced with hydrogen atoms is suppressed in the method. The method includes reacting a specific chlorofluoroolefin with hydrogen in the presence of a catalyst supported on a carrier to obtain the hydrofluoroolefin. The catalyst is a catalyst composed of an alloy containing at least one platinum group element of palladium and platinum, and at least one second element of copper, gold, lithium, potassium, silver, zinc, tin, lead, and bismuth.
Process for producing hydrofluoroolefin
A method for producing a hydrofluoroolefin is provided. The formation of by-products of an over-reduced product having hydrogen added to a material chlorofluoroolefin and an over-reduced product having not only chlorine atoms but also fluorine atoms in the chlorofluoroolefin replaced with hydrogen atoms is suppressed in the method. The method includes reacting a specific chlorofluoroolefin with hydrogen in the presence of a catalyst supported on a carrier to obtain the hydrofluoroolefin. The catalyst is a catalyst composed of an alloy containing at least one platinum group element of palladium and platinum, and at least one second element of copper, gold, lithium, potassium, silver, zinc, tin, lead, and bismuth.