Method for the preparation of a monolithic catalyst for the reduction of nitrogen oxides VOC and carbon monoxide in an off-gas, the catalyst comprises at least one platinum group metal, vanadium, titania and optionally tungsten oxide.

A novel catalyst composition and its use in the dehydrogenation of alkanes to olefins. The catalyst comprises a Group VIII noble metal and a metal selected from the group consisting of manganese, vanadium, chromium, titanium, and combinations thereof, on a support. The Group VIII noble metal can be platinum, palladium, osmium, rhodium, rubidium, iridium, and combinations thereof. The support can be silicon dioxide, titanium dioxide, aluminum oxide, silica-alumina, cerium dioxide, zirconium dioxide, magnesium oxide, metal modified silica, silica-pillared clays, silica-pillared micas, metal oxide modified silica-pillared mica, silica-pillared tetrasilicic mica, silica-pillared taeniolite, zeolite, molecular sieve, and combinations thereof. The catalyst composition is an active and selective catalyst for the catalytic dehydrogenation of alkanes to olefins.

The present specification discloses a membrane reactor comprising a reaction region; a permeate region; and a composite membrane disposed at a boundary of the reaction region and the permeate region, wherein the reaction region comprises a bed filled with a catalyst for dehydrogenation reaction, wherein the composite membrane comprises a support layer including a metal with a body-centered-cubic (BCC) crystal structure, and a catalyst layer including a palladium (Pd) or a palladium alloy formed onto the support layer, wherein ammonia (NH.sub.3) is supplied to the reaction region, the ammonia is converted into hydrogen (H.sub.2) by the dehydrogenation reaction in the presence of the catalyst for dehydrogenation reaction, and the hydrogen permeates the composite membrane and is emitted from the membrane reactor through the permeate region.

An outer peripheral coating member contains first particles containing titanium oxide, second particles containing zirconium oxide, third particles containing niobium oxide or aluminum oxide, and a dispersion medium. It is preferable for the first particles to have at least two peak values R1 in a distribution of particle sizes of the first particles. One of the peak values R1 is within a range of 1 to 50 nm, and the other peak value R1 is within a range of 100 to 500 nm.

Provided in this disclosure is a process for the oxidative dehydrogenation of a lower alkane into a corresponding alkene. The process includes providing a gas stream comprising the lower alkane to a reactor; contacting, in the oxidative dehydrogenation reactor, the lower alkane with a catalyst that includes a mixed metal oxide; and providing to the last 50% of the oxidative dehydrogenation reactor a stream comprising from 0.01 vol. % to 10 vol. % of a C.sub.1-C.sub.3 alcohol.

In this fuel cell electrode catalyst layer, a catalyst is supported on a carrier comprising inorganic oxide particles. The fuel cell electrode catalyst layer is provided with a porous structure. When a mercury penetration method is used to measure the pore size distribution of the porous structure, a peak is observed in the range spanning from 0.005 m to 0.1 m inclusive, and a peak is also observed in the range spanning from over 0.1 m to not more than 1 m. When P1 represents the peak intensity in the range spanning from 0.005 m to 0.1 m inclusive, and P2 represents the peak intensity in the range spanning from over 0.1 m to not more than 1 m, the value of P2/P1 is 0.2-10 inclusive. It is preferable that the inorganic oxide be tin oxide.

In this fuel cell electrode catalyst layer, a catalyst is supported on a carrier comprising inorganic oxide particles. The fuel cell electrode catalyst layer is provided with a porous structure. When a mercury penetration method is used to measure the pore size distribution of the porous structure, a peak is observed in the range spanning from 0.005 m to 0.1 m inclusive, and a peak is also observed in the range spanning from over 0.1 m to not more than 1 m. When P1 represents the peak intensity in the range spanning from 0.005 m to 0.1 m inclusive, and P2 represents the peak intensity in the range spanning from over 0.1 m to not more than 1 m, the value of P2/P1 is 0.2-10 inclusive. It is preferable that the inorganic oxide be tin oxide.

The invention relates to a catalyst composition suitable for the dehydrogenation of paraffins having 2-8 carbon atoms comprising zinc oxide and titanium dioxide, optionally further comprising oxides of cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), lanthanum (La), neodymium (Nd), praseodymium (Pr), samarium (Sm), terbium (Tb), ytterbium (Yb), yttrium (Y), tungsten (W) and Zirconium (Zr) or mixtures thereof, wherein said catalyst composition is substantially free of chromium and platinum. The catalysts possess unique combinations of activity, selectivity, and stability. Methods for preparing improved dehydrogenation catalysts and a process for dehydrogenating paraffins having 2-8 carbon atoms, comprising contacting the mixed metal oxide catalyst with paraffins are also described. The catalyst may also be disposed on a porous support in an attrition-resistant form and used in a fluidized bed reactor.

The present disclosure provides an exhaust gas purification apparatus for motor vehicles that has succeeded in suppressing peeling of a coat layer from an exhaust gas purification catalyst. Such exhaust gas purification apparatus for motor vehicles comprises: an exhaust gas purification catalyst comprising a substrate and a coat layer coated on the substrate comprising a microwave-absorbing material, a noble metal, and aluminum oxide (Al.sub.2O.sub.3); and a microwave-generating apparatus for heating the microwave-absorbing material located ahead of the exhaust gas purification catalyst with respect to an exhaust gas flow direction, wherein the microwave-absorbing material includes NiFe.sub.2O.sub.4, the noble metal includes at least one metal selected from the group consisting of platinum (Pt), palladium (Pd), and rhodium (Rh), and contents of zinc oxide (ZnO) and copper(II) oxide (CuO) in the coat layer are equivalent to or lower than the given levels.

The present disclosure relates to a reforming catalyst composition comprising a spherical gamma AI.sub.2O.sub.3 support; at least one Group VB metal oxide sheet coated on to the AI.sub.2O.sub.3 support; and at least one active metal and at least one promoter metal impregnated on the AI.sub.2O.sub.3 coated support. The reforming catalyst composition of the present disclosure has improved activity, better selectivity for total aromatics during naphtha reforming and results in less coke formation. The reforming catalyst composition has improved catalyst performance with simultaneous modification of acidic sites as well as metallic sites through metal support interaction. The acid site cracking activity of the catalyst is inhibited because of the use of chloride free alumina support modified with solid acid such as Group VB metal oxide and impregnated with active metals. The present disclosure provides a process for naphtha reforming in the presence of the reforming catalyst composition of the present disclosure to obtain reformates of naphtha.