A reactor system for aromatization of higher hydrocarbons within a given temperature range T upon bringing a reactant stream including higher hydrocarbons into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate a catalytic mixture. The catalytic mixture includes a catalyst material and a ferromagnetic material. The catalyst material is arranged to catalyze the aromatization of higher hydrocarbons. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range T, where the temperature range T is the range from between about 400° C. and about 700° C. or a subrange thereof. The reactor system also includes an induction coil arranged to be powered by a power source supplying alternating current, whereby the ferromagnetic material is heated to a temperature within the temperature range T by means of an alternating magnetic field.

Ceramic compositions with catalytic activity are provided, along with methods for using such catalytic ceramic compositions. The ceramic compositions correspond to compositions that can acquire increased catalytic activity by cyclic exposure of the ceramic composition to reducing and oxidizing environments at a sufficiently elevated temperature. The ceramic compositions can be beneficial for use as catalysts in reaction environments involving swings of temperature and/or pressure conditions, such as a reverse flow reaction environment. Based on cyclic exposure to oxidizing and reducing conditions, the surface of the ceramic composition can be converted from a substantially fully oxidized state to various states including at least some dopant metal particles supported on a structural oxide surface.

A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.

A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.

The invention relates to process for the manufacture or preparation of fluorinated benzene, in particular monofluorobenzene, in a vapor-phase fluorination process. The process of the invention, for example, can comprise a batch or continuous manufacture or preparation of fluorinated benzene, in particular monofluorobenzene, using hydrogen fluoride (HF) in gas phase as fluorination gas. Also, in this process of the invention, for example, fluorination catalysts are involved.

A process for steam reforming a hydrocarbon feedstock containing one or more nitrogen compounds, including passing a mixture of the hydrocarbon feedstock and steam through a catalyst bed of one or more nickel steam reforming catalysts disposed within a plurality of externally heated tubes in a tubular steam reformer, each tube having an inlet to which the mixture of hydrocarbon and steam is fed, an outlet from which a reformed gas containing hydrogen, carbon monoxide, carbon dioxide, steam, ammonia and methane is recovered. The steam reforming catalyst at least at the outlet of the tubes comprises nickel dispersed over a porous metal oxide surface present as a coating on a non-porous metal or ceramic structure. The nickel content of the metal oxide coating is in the range of 5 to 50% by weight and the thickness of the coating is in the range of 5 to 150 micrometres.

A method of providing a particulate material from an at least substantially metallic and/or ceramic starting material, comprising the following steps:

(a) generating the particulate material from the starting material by vaporizing the starting material by introducing energy, preferably radiation energy, in particular by means of at least one laser, into the starting material and subsequently at least partially condensing the vaporized starting material,

b) collecting the particulate material in at least one receiving and/or transporting device, in particular at least one container,

c) receiving, in particular storing, and/or transporting the particulate material in the receiving and/or transporting device and/or in a further receiving and/or transporting device such that it can be used for a subsequent process, in particular in a state of at least non-permanent passivation, and

d) providing the particulate material for the subsequent process.

A honeycomb structure including: an outer peripheral wall; a partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the cells extending from one end face to other end face to form a flow path; and magnetic particles, wherein the magnetic particles contain secondary particles with primary particles combined, wherein in a cross-sectional image of the honeycomb structure, a ratio of a number of the primary particles forming the secondary particles to a total number of the primary particles of the magnetic particles is 40 to 100%, and wherein a particle size D50 corresponding to a cumulative frequency of 50% by number for the primary particles is 5 to 100 μm.

Perovskite oxides and catalysts containing the perovskite oxides are provided for the thermochemical conversion of carbon dioxide to carbon monoxide. The perovskite oxides can exhibit large carbon monoxide production rates and/or low carbon monoxide production onset temperatures as compared to existing materials. Reactors are provided containing the perovskite oxides and catalysts, as well as methods of use thereof for the thermochemical conversion of carbon dioxide to carbon monoxide.

The present invention is to provide an electron or hydride ion intake/release material comprising a lanthanoid oxyhydride represented by the formula Ln(HO) (in the formula, Ln represents a lanthanoid element) or an electron or hydride ion intake/release composition comprising at least one kind of lanthanoid oxyhydride; a transition metal-supported material wherein a transition metal is supported by the above electron or hydride ion intake/release material or electron or hydride ion intake/release composition; and a catalyst comprising the transition metal-supported material. The electron or hydride ion intake/release material or electron or hydride ion intake/release composition according to the present invention has a higher ability for intake/release of electron or hydride ion than that of a conventional hydride-containing compound, and can be used effectively as a catalyst such as a catalyst having excellent ammonia synthesis activity by supporting a transition metal thereon.