B01J23/888

METHOD FOR PRODUCING GUERBET ALCOHOL
20230037136 · 2023-02-02 · ·

A method for producing a Guerbet alcohol, including reacting a raw material alcohol having 8 or more and 22 or less carbon atoms, in the presence of a catalyst (A) containing a first component, a second component, and a third component below: first component: copper, second component: one kind selected from the group consisting of cobalt, nickel, molybdenum, and rhenium, and third component: at least one kind selected from the group consisting of elements that are elements belonging to Groups 3 to 10 and 12 of the fourth period of the periodic table and elements belonging to Groups 3 to 7, 11, and 12 of the fifth and sixth periods of the periodic table, and are different from the element selected as the second component.

Catalytic coatings, methods of making and use thereof

Described herein are coatings. The coatings can, for example, catalyze carbon gasification. In some examples, the coatings comprise: a first region having a first thickness, the first region comprising a manganese oxide, a chromium-manganese oxide, or a combination thereof; a second region having a second thickness, the second region comprising Ni, Fe, W, Cr, Co, Mn, Ti, Mo, V, Nb, Zr, Si, C, or a combination thereof; and an alkaline earth metal, an alkaline earth oxide, an alkaline earth carbonate, an alkaline earth silicate, molybdemun, a molybdenum oxide, a molybdenum carbide, a mixed-metal perovskite, a mixed metal inorganic oxide, or a combination thereof.

Catalytic coatings, methods of making and use thereof

Described herein are coatings. The coatings can, for example, catalyze carbon gasification. In some examples, the coatings comprise: a first region having a first thickness, the first region comprising a manganese oxide, a chromium-manganese oxide, or a combination thereof; a second region having a second thickness, the second region comprising Ni, Fe, W, Cr, Co, Mn, Ti, Mo, V, Nb, Zr, Si, C, or a combination thereof; and an alkaline earth metal, an alkaline earth oxide, an alkaline earth carbonate, an alkaline earth silicate, molybdemun, a molybdenum oxide, a molybdenum carbide, a mixed-metal perovskite, a mixed metal inorganic oxide, or a combination thereof.

NEAR-INFRARED PHOTOTHERMAL CATALYST AND PREPARATION METHOD AND USE THEREOF
20230076330 · 2023-03-09 ·

The present disclosure provides a near-infrared (NIR) photothermal catalyst and a preparation method and use thereof. The method includes: mixing a graphene oxide (GO) dispersion and a dehydrating agent to obtain a GO solution; mixing the GO solution and branched polyethyleneimine (PEI) and then drying to obtain a GO-PEI carrier; and mixing the GO-PEI carrier with water and adjusting a pH value to be within a range of 2 to 4.5, adding dropwise a monosubstituted Keggin-type polyoxometalate (POM) aqueous solution, and conducting an ion replacement reaction to obtain the NIR photothermal catalyst, wherein a solute of the monosubstituted Keggin-type POM aqueous solution is K.sub.6SiW.sub.11Co(H.sub.2O)O.sub.39 or H.sub.4SiW.sub.11Ce(H.sub.2O).sub.4O.sub.39.

MATERIALS COMPRISING CARBON-EMBEDDED IRON NANOPARTICLES, PROCESSES FOR THEIR MANUFACTURE, AND USE AS HETEROGENEOUS CATALYSTS

The present invention relates to catalytically active material, comprising grains of non-graphitizing carbon with iron nanoparticles dispersed therein, wherein d.sub.p, the average diameter of iron nanoparticles in the non-graphitizing carbon grains, is in the range of 1 nm to 20 nm, D, the average distance between iron nanoparticles in the non-graphitizing carbon grains, is in the range of 2 nm to 150 nm, and ω, the combined total mass fraction of metal in the non-graphitizing carbon grains, is in the range of 30 wt % to 70 wt % of the total mass of the non-graphitizing carbon grains, and wherein d.sub.p, D and ω conform to the following relation: 4.5 d.sub.p/ω>D≥0.25 d.sub.p/ω. The present invention, further, relates to a process for the manufacture of material according to the invention, as well as its use as a catalyst.

ODH CATALYST FORMULATIONS

The oxidative dehydrogenation of ethane comprises contacting a mixture of ethane and oxygen in an ODH reactor with an ODH catalyst under conditions that promote oxidation of ethane into ethylene. Conditions within the reactor are controlled by the operator and include, but are not limited to, parameters such as 5 temperature, pressure, and flow rate. Conditions will vary and can be optimized for a specific catalyst, or whether an inert diluent is used in the mixing of the reactants. Disclosed herein is a catalyst consisting of: Mo.sub.0-1W.sub.0.3-1V.sub.0.2-0.4Te.sub.0.06-0.10Fe.sub.0.0-0.10Nb.sub.0.08-0.18O.sub.X where X is determined by the valance of the metals.

ODH CATALYST FORMULATIONS

The oxidative dehydrogenation of ethane comprises contacting a mixture of ethane and oxygen in an ODH reactor with an ODH catalyst under conditions that promote oxidation of ethane into ethylene. Conditions within the reactor are controlled by the operator and include, but are not limited to, parameters such as 5 temperature, pressure, and flow rate. Conditions will vary and can be optimized for a specific catalyst, or whether an inert diluent is used in the mixing of the reactants. Disclosed herein is a catalyst consisting of: Mo.sub.0-1W.sub.0.3-1V.sub.0.2-0.4Te.sub.0.06-0.10Fe.sub.0.0-0.10Nb.sub.0.08-0.18O.sub.X where X is determined by the valance of the metals.

Catalyst for chemical looping combustion

A catalyst for use in chemical looping combustion is provided. The catalyst includes a mixture of metal oxides dispersed on a ceramic support. The mixture of metal oxides forms a nickel tungsten oxide (NiWO.sub.4) interaction complex which functions as an oxygen carrier in the chemical looping combustion reaction.

Catalyst for chemical looping combustion

A catalyst for use in chemical looping combustion is provided. The catalyst includes a mixture of metal oxides dispersed on a ceramic support. The mixture of metal oxides forms a nickel tungsten oxide (NiWO.sub.4) interaction complex which functions as an oxygen carrier in the chemical looping combustion reaction.

HYDROTREATING CATALYST WITH A TITANIUM CONTAINING CARRIER AND SULFUR CONTAINING ORGANIC ADDITIVE

Generally, it is disclosed a catalyst for use in a hydrotreating hydrocarbon feedstocks and the method of making such catalyst. It is generically provided that the catalyst comprises at least one Group VIB metal component, at least one Group VIII metal component, about 1 to about 30 wt % C, and preferably about 1 to about 20 wt % C, and more preferably about 5 to about 15 wt % C of one or more sulfur containing organic additive and a titanium-containing carrier component, wherein the amount of the titanium component is in the range of about 3 to about 60 wt %, expressed as an oxide (TiO.sub.2) and based on the total weight of the catalyst. The titanium-containing carrier is formed by co-extruding or precipitating a titanium source with a Al.sub.2O.sub.3 precursor to form a porous support material comprising Al.sub.2O.sub.3 or by impregnating a titanium source onto a porous support material comprising Al.sub.2O.sub.3.