Patent classifications
B01J27/0515
FE-DOPED MOS2 NANO-MATERIAL, PREPARATION METHOD THEREFOR AND USE THEREOF
The invention discloses a method for preparing a Fe-doped MoS.sub.2 nano-material, which comprises the following steps: dissolving a ferric salt and ammonium tetrathiomolybdate in DMF and reacting at 180-200 C. for 6-24 hrs to obtain a Fe-doped MoS.sub.2 nano-material. The present invention also provides a Fe-doped MoS.sub.2 nano-material supported by nickel foam, which includes a nickel foam substrate and the Fe-doped MoS.sub.2 nano-material loaded on the nickel foam substrate. Furthermore, the present invention also provides a preparation method and use of the above materials. In the invention, the desired product can be obtained by a one-pot solvothermal reaction, and thus the operation is simple. There is no need to introduce a surfactant for morphological control during the preparation process, and the resulting product has a clean surface and is easy to wash.
Ammonia-free synthesis for Al or Si based multimetallic materials
A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
METHOD OF PREPARING SILICA SUPPORTED CoMoS HYDRODESULFURIZATION CATALYSTS
A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.
Catalyst for converting syngas to mixed alcohols
Higher mixed alcohols are produced from syngas contacting a catalyst in a reactor. The catalyst has a first component of molybdenum or tungsten, a second component of vanadium, a third component of iron, cobalt, nickel or palladium and optionally a fourth component of a promoter. The first component forms alcohols, while the vanadium and the third component stimulates carbon chain growth to produce higher alcohols.
Crystalline oxy-hydroxide transition metal molybdotungstate
A unique crystalline transition metal molybdotungstate material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
CATALYST FOR SELECTIVE HYDRODESULPHURIZATION OF CRACKED NAPHTHA STREAMS, METHOD OF PREPARATION THEREOF, AND PROCESS FOR SELECTIVE HYDRODESULPHURIZATION OF CRACKED NAPHTHA
The present invention relates to a catalyst for selective hydrodesulphurization of cracked naphtha streams in the form of an extrudate, which comprises a support based on an inorganic oxide and an outer layer bound to the support, wherein the outer layer comprises desulphurization metals dispersed therein forming a crown, the desulphurization metals being cobalt and molybdenum. The present invention also relates to the preparation of said catalyst by the incipient wetness impregnation method and to the process for selective hydrodesulphurization of cracked naphtha employing same.
METHOD OF MAKING HIGHLY ACTIVE METAL OXIDE AND METAL SULFIDE MATERIALS
A method of making highly an active mixed transition metal oxide material has been developed. The method may include sulfiding the metal oxide material to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.
Catalyst containing 2-acetylbutyrolactone and/or the hydrolysis products thereof, and use thereof in a hydrotreatment and/or hydrocracking process
The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and at least one additive that is selected from among 2-acetylbutyrolactone and/or its hydrolysis products, 2-(2-hydroxyethyl)-3-oxobutanoic acid, and 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.
Process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics
The present invention relates to a process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics, the process comprising contacting the feed at process conditions with a catalyst comprising a mixture of zeolite Y and a hydrogenation catalyst comprising one or more hydrogenation metals on a solid catalyst support.
HYDROTREATMENT CATALYSTS AND PROCESS FOR PREPARING SAID CATALYSTS
The present invention is in the field of heterogeneous catalysis. Particularly, the present invention relates to a process for preparing catalysts advantageously usable in the hydrotreatment processes, for example in hydrodesulphurization, hydrodenitrogenation, hydrodearomatization processes of hydrocarbons. More in particular, the present invention relates to a process for obtaining said catalysts, which comprise mixed oxides of Nickel, Aluminum, Molybdenum and Tungsten and optionally a transition metal Me selected from the group consisting of Zn, Mn, Cd, and a mixture thereof, an organic component C, and possibly an inorganic binder B. Said mixed oxides comprise an amorphous phase and a pseudo-crystalline phase isostructural to Wolframite. The present invention further relates to said hydrotreatment catalysts and a hydrotreatment process wherein said catalysts are used.