B01J29/14

Suspended-bed hydrogenation catalyst and regeneration method therefor

A suspended-bed hydrogenation catalyst and a regeneration method are disclosed. A composite support comprises a semi-coke pore-expanding material, a molecular sieve and a spent catalytic cracking catalyst. The hydrogenation catalyst for heavy oil is obtained through mixing the semi-coke pore-expanding material, the molecular sieve and the spent catalytic cracking catalyst, followed by molding, calcining and activating, and then loading an active metal oxide to the composite support. According to the composite support, a macropore, mesopore and micropore uniformly-distributed structure is formed, so that full contact between all ingredients in the heavy oil and active ingredients in a hydrogenation process is facilitated, and the conversion ratio of the heavy oil is increased. The hydrogenation catalyst integrates adsorption, cracking and hydrogenation properties. According to a regeneration method, the loading performance of an active-metal-loaded support in a spent hydrogenation catalyst cannot be destroyed.

HYDRODEOXYGENATION OF LIGNIN TO HYDROCARBONS USING BIMETALLIC CATALYSTS
20190233743 · 2019-08-01 ·

Bimetallic catalysts for the hydrodeoxygenation (HDO) conversion of lignin into useful hydrocarbons are provided. The catalysts are bifunctional bimetallic ruthenium catalysts Ru-M/X.sup.+Y comprising a metal M such as iron (Fe), nickel (Ni), copper (Cu) or zinc (Zn), zeolite Y and cation X.sup.+ (e.g. H.sup.+) associated with zeolite Y.

Process for preparing a catalyst

The present disclosure relates to a process for preparing a catalyst. The process comprises coating zeolite gel over the alumina support to obtain a chloride free zeolite gel coated alumina support, crystallizing the chloride free zeolite gel coated alumina support, washing, drying and calcining the crystallized zeolite coated alumina support to obtain a calcined crystallized chloride free zeolite coated alumina support, treating the calcined crystallized chloride free zeolite coated alumina support with ammonium nitrate to obtain sodium free support, washing, drying, and calcining the support to obtain a calcined chloride free zeolite coated alumina support, immersing the calcined chloride free zeolite coated alumina support in an active metal and a promoter metal solution mixture followed by stirring to obtain a metal coated chloride free zeolite coated alumina support, and drying and calcining the metal coated chloride free zeolite coated alumina support to obtain the catalyst.

Ceria-zirconia-zeolite catalyst body

A catalyst body which includes ceria:zirconia and a metal-zeolite, and is substantially free, or free, of tungsten or tungsten compounds, and methods of manufacture. The ceria and zirconia are present with a zirconia/ceria mole ratio of less than or equal to 1.0. The catalyst body is especially useful in NOx reduction applications.

Ceria-zirconia-zeolite catalyst body

A catalyst body which includes ceria:zirconia and a metal-zeolite, and is substantially free, or free, of tungsten or tungsten compounds, and methods of manufacture. The ceria and zirconia are present with a zirconia/ceria mole ratio of less than or equal to 1.0. The catalyst body is especially useful in NOx reduction applications.

Process for preparing a mesoporized catalyst, catalyst thus obtained and use thereof in a catalytic process

The invention relates to a process for preparing a catalyst comprising a mesoporized zeolite, comprising the steps of: preparation of a protonic mesoporized zeolite, which contains at least one network of micropores and at least one network of mesopores, and treatment in a gas or liquid phase containing ammonia or ammonium ions. The invention also related to the obtained catalyst and the use of this catalyst in hydroconversion processes.

METHOD FOR PRODUCING HYDROCARBON LIQUID FUEL

A method for producing a hydrocarbon liquid fuel including hydrocracking a raw material oil in the presence of a hydrocracking catalyst, at a supplying pressure of hydrogen of from 0.1 to 1.0 MPa, a liquid space velocity of liquid volume of the raw material oil of from 0.05 to 10.0 hr.sup.1, and a flow rate of the hydrogen from 50 to 3,000 NL per 1 L of the raw material oil, wherein the hydrocracking catalyst is produced by a method including stirring a sulfur compound and a cracking catalyst in an aqueous medium to allow liquid-solid separation (step 1); stirring a solid product obtained in the step 1 and a metal component in an aqueous medium to allow liquid-solid separation (step 2); baking a solid product obtained in the step 2 (step 3); and reducing a solid product obtained in the step 3, or reducing a solid product obtained in the step 3, and then subjecting a reduced product to sulfurization treatment (step 4). According to the present invention, the hydrocracking of a raw material oil such as fats and oils and biomass retort oils, or a hydrocarbon or the like in petroleum oils, in a given composition can be accomplished by supplying a low-pressure hydrogen of a normal pressure or so.

Coating for reducing nitrogen oxides
10322403 · 2019-06-18 · ·

A catalyst coating for use in a hydrolysis catalyst (H-catalyst) for the reduction of nitrogen oxides, a manufacturing method for such a coating, a catalyst structure and its use are described. The H-catalyst includes alkaline compounds, which are capable of adsorbing HNCO and/or nitrogen oxides and which include alkali and alkaline earth metals, lanthanum and/or yttrium and/or hafnium and/or prasedium and/or gallium, and/or zirconium for promoting reduction, such as for promoting the hydrolysis of urea and the formation of ammonia and/or the selective reduction of nitrogen oxides.

PROCESS FOR THE PREPARATION OF A ZEOLITIC MATERIAL HAVING A FAU-TYPE FRAMEWORK STRUCTURE AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOx

The present invention relates to a process for the preparation of a zeolitic material having a FAU-type framework M structure comprising YO.sub.2 and X.sub.2O.sub.3, said process comprising: (a) preparing a mixture comprising one or more sources of YO.sub.2, one or more sources of X.sub.2O.sub.3, and one or more structure directing agents (SDA); (b) crystallizing the zeolitic material from the mixture obtained in (a); wherein Y is a tetravalent element and X is a trivalent element, and wherein the one or more structure directing agents comprise one or more isomers of diaminomethylcyclohexane as well as to a zeolitic material having an FAU-type framework structure obtainable and/or obtained according to the inventive process, to processes for preparing a coated substrate and a shaped body, respectively, from the zeolitic material having a FAU-type framework structure obtainable and/or obtained according to the inventive process, as well as to a method for selectively reducing nitrogen oxides NO.sub.x employing said zeolitic material.

PROCESS FOR THE PREPARATION OF A ZEOLITIC MATERIAL HAVING A FAU-TYPE FRAMEWORK STRUCTURE AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOx

The present invention relates to a process for the preparation of a zeolitic material having a FAU-type framework M structure comprising YO.sub.2 and X.sub.2O.sub.3, said process comprising: (a) preparing a mixture comprising one or more sources of YO.sub.2, one or more sources of X.sub.2O.sub.3, and one or more structure directing agents (SDA); (b) crystallizing the zeolitic material from the mixture obtained in (a); wherein Y is a tetravalent element and X is a trivalent element, and wherein the one or more structure directing agents comprise one or more isomers of diaminomethylcyclohexane as well as to a zeolitic material having an FAU-type framework structure obtainable and/or obtained according to the inventive process, to processes for preparing a coated substrate and a shaped body, respectively, from the zeolitic material having a FAU-type framework structure obtainable and/or obtained according to the inventive process, as well as to a method for selectively reducing nitrogen oxides NO.sub.x employing said zeolitic material.