The invention relates to the field of gas chemistry and, more specifically, to methods and devices for producing aromatic hydrocarbons from natural gas, which involve producing synthesis gas, converting same into methanol producing, from the methanol, in the presence of a catalyst, a concentrate of aromatic hydrocarbons and water, separating the water, air stripping hydrocarbon residues from the water, and separating-out the resultant concentrate of aromatic hydrocarbons and hydrogen-containing gas, the latter being at least partially used in the production of synthesis gas to adjust the ratio therein of H.sub.2:CO 1.8-2.3:1, and can be used for producing aromatic hydrocarbons. According to the invention, the production of aromatic hydrocarbons from methanol in the presence of a catalyst is carried out in two consecutively-connected reactors for synthesizing aromatic hydrocarbons: in a first, low-temperature isothermal reactor for synthesizing aromatic and aliphatic hydrocarbons, and in a second, high-temperature adiabatic reactor for synthesizing aromatic and aliphatic hydrocarbons from aliphatic hydrocarbons formed in the first reactor, and the subsequent stabilization thereof in an aromatic hydrocarbon concentrate stabilization unit. At least a portion of the hydrogen-containing gas is fed to a synthesis gas production unit and is used for producing synthesis gas using autothermal reforming technology. The installation carries out the method. The achieved technical result consists in increasing the efficiency of producing concentrates of aromatic hydrocarbons.

A method of making a heat generating catalyst for hydrocarbon cracking. The method includes providing at least one mordenite framework-inverted (MFI) zeolite having a Si/Al molar ratio of 15 or greater and providing at least one metal oxide precursor. Further, the at least one metal oxide precursor is dispersed within a microstructure of the MFI zeolite catalyst. The method additionally includes calcining the heat generating material with the at least one metal oxide precursor dispersed within the microstructure of the MFI zeolite catalyst to form at least one metal oxide in situ. The heat generating catalyst includes at least one MFI zeolite and at least one metal oxide in a ratio between 50:50 and 95:5. Additionally, an associated method of using the heat generating catalyst in a hydrocarbon cracking process is provided.

This invention relates to processes and systems for converting acyclic hydrocarbons to alkenes, cyclic hydrocarbons and/or aromatics, for example converting acyclic C.sub.5 hydrocarbons to cyclopentadiene in a reactor system. The process includes heating an electrically-conductive reaction zone by applying an electrical current to the first electrically-conductive reaction zone; and contacting a feedstock comprising acyclic hydrocarbons with a catalyst material in the electrically-conductive reaction zone under reaction conditions to convert at least a portion of the acyclic hydrocarbons to an effluent comprising alkenes, cyclic hydrocarbons, and/or aromatics.

An exhaust system for an internal combustion engine, the exhaust system comprising, a lean NO.sub.x trap, and a wall flow monolithic substrate having a pre-coated porosity of 40% or greater, and comprising an oxidation catalytic zone, the oxidation catalytic zone comprising a platinum group metal loaded on a first support, the first support comprising at least one inorganic oxide and a zinc compound.

Provided is a system for treating a flowing exhaust gas comprising a lean NOx trap, a catalyzed soot filter, an ammonia or an ammonia precursor metering system for metering ammonia or an ammonia precursor into the flowing exhaust gas; and an SCR catalyst, wherein the SCR catalyst is disposed downstream of the lean NOx trap and comprises copper and/or iron supported on a small pore molecular sieve.

The present invention provide a method for purifying exhaust gas in which nitrogen oxides (NOx) gas is removed from a combustion exhaust gas. The method for purifying exhaust gas according to the invention is characterized in that water vapor is further added to raw exhaust gas to be processed to increase the water vapor concentration in the exhaust gas and the resulting moisture-adjusted exhaust gas is introduced into a denitration catalyst layer. The water vapor concentration in the moisture-adjusted exhaust gas is preferably 22.0% by volume or less in the total of the water vapor originally contained in the raw exhaust gas and the added water vapor.

The present invention provide a method for purifying exhaust gas in which nitrogen oxides (NOx) gas is removed from a combustion exhaust gas. The method for purifying exhaust gas according to the invention is characterized in that water vapor is further added to raw exhaust gas to be processed to increase the water vapor concentration in the exhaust gas and the resulting moisture-adjusted exhaust gas is introduced into a denitration catalyst layer. The water vapor concentration in the moisture-adjusted exhaust gas is preferably 22.0% by volume or less in the total of the water vapor originally contained in the raw exhaust gas and the added water vapor.

Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C.sub.8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m.sup.2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C.sub.8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m.sup.2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

Selective conversion from cyclohexene to methylcyclopentene can occur via skeletal isomerization reaction under mild temperature and near atmospheric pressure with the existence of a catalyst structure as described herein. The catalyst structure includes a porous zeolite as the support and one or more loaded metals to further modify its acidity and pore structures. Industrially available cyclohexene feedstock can be effectively converted to a high value-added product methylcyclopentene with over 90 wt % conversion and 95 wt % selectivity, which is highly profitable for potential application in the fine chemical industry.