Patent classifications
B01J29/68
Catalyst for direct production of isoparaffins-rich synthetic oil and a method for preparing the catalyst
A catalyst for producing isoparaffins-rich synthetic oil is a granulated porous composite material comprising a three-dimensional heat-conducting structure of metal aluminum and Raney cobalt, and a binding component comprising an H-form zeolite. The particles of Raney cobalt and zeolite are in mutual direct contact. Fractions of macropores in an open porosity of the catalyst granules and of mesopores of the size of 70-500 in an open porosity of the catalyst granules are respectively 55-79% and 7-20%, a fraction of micropores being the rest. A method for preparing the catalyst comprises mixing binding component powders, peptizing the mixture with a nitric acid solution, mixing obtained homogeneous gel with powders of Raney cobalt and metal aluminum and a liquid phase to form a paste, extruding same into granules and calcinating the granules. The catalyst improves reagents mass transfer inside the granules and increases isoparaffine content in the produced oil.
Catalyst for direct production of isoparaffins-rich synthetic oil and a method for preparing the catalyst
A catalyst for producing isoparaffins-rich synthetic oil is a granulated porous composite material comprising a three-dimensional heat-conducting structure of metal aluminum and Raney cobalt, and a binding component comprising an H-form zeolite. The particles of Raney cobalt and zeolite are in mutual direct contact. Fractions of macropores in an open porosity of the catalyst granules and of mesopores of the size of 70-500 in an open porosity of the catalyst granules are respectively 55-79% and 7-20%, a fraction of micropores being the rest. A method for preparing the catalyst comprises mixing binding component powders, peptizing the mixture with a nitric acid solution, mixing obtained homogeneous gel with powders of Raney cobalt and metal aluminum and a liquid phase to form a paste, extruding same into granules and calcinating the granules. The catalyst improves reagents mass transfer inside the granules and increases isoparaffine content in the produced oil.
Method for making functional structural body
A method for making a functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.
Method for making functional structural body
A method for making a functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.
Method for Removing N2O and NOx From the Nitric Acid Production Process, and an Installation Suitable for Same
The invention relates to a process and apparatus for preparing nitric acid by catalytic oxidation of NH.sub.3 by means of oxygen and subsequent reaction of the NO.sub.x formed with an absorption medium in an absorption tower, which comprises a catalyst bed for N.sub.2O decomposition arranged in the process gas downstream of the catalytic NH.sub.3 oxidation and upstream of the absorption tower in the flow direction and a catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas downstream of the absorption tower in the flow direction, wherein the amount of N.sub.2O removed in the catalyst bed for N.sub.2O removal arranged in the process gas is not more than that which results in an N.sub.2O content of >100 ppmv and a molar N.sub.2O/NO.sub.x ratio of >0.25 before entry of the tailgas into the catalyst bed for NO.sub.x reduction and the catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas contains at least one iron-loaded zeolite catalyst and NH.sub.3 is added to the tailgas before entry into the catalyst bed in such an amount that an NO.sub.x concentration of <40 ppmv results at the outlet from the catalyst bed and the operating parameters are selected in such a way that an N.sub.2O concentration of <200 ppmv results.
Hydrocarbon dehydrocyclization
The invention relates to the production of aromatic hydrocarbon by the conversion of a feed comprising saturated hydrocarbon. At least a portion of the saturated hydrocarbon is converted to olefinic hydrocarbon. Aromatic hydrocarbon is produced from at least a portion of the olefinic hydrocarbon using at least one dehydrocyclization catalyst comprising dehydrogenation and molecular sieve components.
Ethanol production via dimethylether recycle
This invention relates to a process for producing ethanol comprises supplying a feed comprising carbon monoxide, hydrogen and dimethyl ether to a reaction zone operated under conditions such that (i) part of the carbon monoxide in the feed reacts with part of the hydrogen in the feed to produce methanol; (ii) part of the carbon monoxide in the feed reacts with at least part of the dimethyl ether in the feed to produce methyl acetate; and (iii) part of the hydrogen in the feed reacts with at least part of the methyl acetate produced in (ii) to produce an effluent comprising methanol and ethanol. At least part of the ethanol is recovered from the effluent and at least part of the methanol is dehydrated to produce dimethyl ether, which is recycled to the reaction zone.
Ethanol production via dimethylether recycle
This invention relates to a process for producing ethanol comprises supplying a feed comprising carbon monoxide, hydrogen and dimethyl ether to a reaction zone operated under conditions such that (i) part of the carbon monoxide in the feed reacts with part of the hydrogen in the feed to produce methanol; (ii) part of the carbon monoxide in the feed reacts with at least part of the dimethyl ether in the feed to produce methyl acetate; and (iii) part of the hydrogen in the feed reacts with at least part of the methyl acetate produced in (ii) to produce an effluent comprising methanol and ethanol. At least part of the ethanol is recovered from the effluent and at least part of the methanol is dehydrated to produce dimethyl ether, which is recycled to the reaction zone.
Metal doped zeolite and process for its preparation
A metal-doped or metal-exchanged zeolite is disclosed, wherein the doping metal is present in the zeolite in the form of individual atoms i.e. as monomeric and/or dimeric species. Further, a process for the preparation of such a metal-doped or metal-exchanged zeolite is disclosed. The metal-doped zeolites are useful, in particular, as catalysts for the reduction of nitrogen oxides.
Metal doped zeolite and process for its preparation
A metal-doped or metal-exchanged zeolite is disclosed, wherein the doping metal is present in the zeolite in the form of individual atoms i.e. as monomeric and/or dimeric species. Further, a process for the preparation of such a metal-doped or metal-exchanged zeolite is disclosed. The metal-doped zeolites are useful, in particular, as catalysts for the reduction of nitrogen oxides.