Patent classifications
B01J29/7057
FILTER FOR FILTERING PARTICULATE MATTER FROM EXHAUST GAS EMITTED FROM A COMPRESSION IGNITION ENGINE
A filter for filtering particulate matter (PM) from exhaust gas emitted from a compression ignition engine, which filter comprising a porous substrate having inlet surfaces and outlet surfaces, wherein the inlet surfaces are separated from the outlet surfaces by a porous structure containing pores of a first mean pore size, wherein the porous substrate is coated with a wash coat comprising a plurality of solid particles comprising a molecular sieve promoted with at least one metal wherein the porous structure of the wash coated porous substrate contains pores of a second mean pore size, and wherein the second mean pore size is less than the first mean pore size.
A TIN-CONTAINING ZEOLITIC MATERIAL HAVING A BEA FRAMEWORK STRUCTURE
A process for preparing a tin-containing zeolitic material having framework type BEA, comprising providing an aqueous synthesis mixture comprising a boron source, a silicon source, and a BEA structure directing agent; subjecting the synthesis mixture provided in to hydrothermal pre-crystallization conditions; adding the tin source to the obtained mixture; subjecting the obtained aqueous synthesis mixture to hydrothermal crystallization conditions, obtaining a tin-containing zeolitic material having framework type BEA comprised in its mother liquor.
A TIN-CONTAINING ZEOLITIC MATERIAL HAVING A BEA FRAMEWORK STRUCTURE
An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.
CLUSTER-SUPPORTING CATALYST AND PROCESS FOR PRODUCING THE SAME
Cluster-supporting catalyst having an improved heat resistivity, and method for producing the same are provided. The cluster-supporting catalyst includes boron-substitute zeolite particles, and catalyst metal clusters supported within the pores of the boron-substitute zeolite particles. The method for producing a cluster-supporting catalyst, includes the following steps: providing a dispersion liquid containing a dispersion medium and boron-substitute zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters on the acid sites within the pores of the boron-substitute zeolite particles through an electrostatic interaction.
METHOD FOR THE PREPARATION OF DEFECT-FREE NANOSIZED SYNTHETIC ZEOLITE MATERIALS
Some embodiments are directed to a method for the preparation of defect-free nanosized synthetic zeolite materials, to the defect-free nanosized synthetic zeolite materials, to stable colloidal suspensions of the defect-free synthetic zeolite materials, and to the use of the defect-free nanosized synthetic zeolite materials and the stable colloidal suspensions in various applications.
Bound catalyst for selective conversion of oxygenates to aromatics
A catalyst composition includes a zeolite, a binder, and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition comprising about 50 wt % or less of the binder based on a total weight of the catalyst composition, the catalyst composition having a micropore surface area of at least about 340 m.sup.2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of (a) a mesoporosity of greater than about 20 m.sup.2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 110.sup.2 sec.sup.1 when measured at a temperature of about 120 C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
Method of Forming a Catalyst with an Ion-Modified Binder
An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.
METAL-LOADED ZEOLITE CATALYST FOR DEHYDROGENATION OF LIGHT ALKANE AND PREPARATION METHOD THEREOF
The present invention relates to a zeolite catalyst for preparing light alkene by dehydrogenation of light alkane including a cocatalyst metal selected from tin (Sn), germanium (Ge), lead (Pb), gallium (Ga) and indium (In), and a preparation method of the same. The catalyst of the present invention is prepared by using the zeolite having a relatively high pore diameter, a structure of at least 12-membered ring, and a low acidity due to a SiO.sub.2/Al.sub.2O.sub.3 ratio of at least 50, so that it can suppress the inactivation of a catalyst caused by pore clogging due to the formation of coke. Therefore the catalyst of the present invention can be effectively used as a catalyst for the preparation of light alkene by dehydrogenation of light alkane.
Alumina bound catalyst for selective conversion of oxygenates to aromatics
A catalyst composition comprising a zeolite, an alumina binder, and a Group 12 transition metal selected from Zn and/or Cd, the zeolite having a Si/Al ratio of at least about 10 and a micropore surface area of at least about 340 m.sup.2/g, the catalyst composition comprising about 50 wt % or less of the binder, based on a total weight of the catalyst composition, and having a micropore surface area of at least about 290 m.sup.2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: a mesoporosity of about 20 m.sup.2/g to about 120 m.sup.2/g; a diffusivity for 2,2-dimethylbutane of greater than about 110.sup.2 sec.sup.1 when measured at a temperature of about 120 C. and a 2,2-dimethylbutane pressure of about 60 torr (8 kPa); and a combined micropore surface area and mesoporosity of at least about 380 m.sup.2/g.
Method for producing monocyclic aromatic hydrocarbons
A catalyst is provided for production of monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 from feedstock in which a 10 vol % distillation temperature is 140 C. or higher and a 90 vol % distillation temperature is 380 C. or lower. The catalyst contains crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure, and intermediate-pore zeolite having a 10-membered ring structure.