Provided herein is a catalytic article including a catalytic coating disposed on a substrate, wherein the catalytic coating comprises a bottom coating on the substrate and a top coating layer on the bottom coating layer, one such coating layer containing a platinum group metal on a refractory metal oxide support and the other such coating layer containing a ceria-containing molecular sieve. Such catalytic articles are effective toward treating exhaust gas streams of internal combustion engines and exhibit outstanding resistance to sulfur.

The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2. The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.

Disclosed herein is a continuous process for preparing zeolitic material with a CHA-type framework structure comprising SiO.sub.2 and X.sub.2O.sub.3 and the zeolitic material so-obtained. The processes comprises (i) preparing a mixture comprising one or more sources of SiO.sub.2, one or more sources of X.sub.2O.sub.3, seed crystals, one or more tetraalkylammonium cation R.sup.5R.sup.6R.sup.7R.sup.8N.sub.+-containing compounds as structure directing agent, and a liquid solvent system; (ii) continuously feeding the mixture prepared in (i) into a continuous flow reactor at a liquid hourly space velocity; and (iii) crystallizing the zeolitic material with a CHA-type framework structure from the mixture in the continuous flow reactor.

A gas purification catalyst device comprises: a substrate; and one or more catalyst layers on the substrate. Among the one or more catalyst layers, at least one catalyst layer contains both Cu-CHA-type zeolite particles and iron-supporting metal oxide particles in which iron is supported on metal oxide particles.

The present invention relates to a hydrocarbon adsorbent with metal-impregnated zeolite particles having regular mesopores and a manufacturing method therefor. The hydrocarbon adsorbent includes a metal cation and a metal oxide that are impregnated in zeolite particles, in particular, the zeolite particles include regularly formed mesopores having a size of 2 to 10. By adjusting a Si/Al ratio and mesoporosity of the mesopores, a hydrocarbon adsorbent may have increased adsorption capacity for hydrocarbons in a cold-start section and can rapidly oxidize the hydrocarbon upon desorption thereof, thereby reducing the discharge of exhaust gas produced in automobiles and industries.

The honeycomb catalyst body is equipped with a honeycomb structure body having partition walls that define a plurality of cells extending from a first end face as one of the end faces to a second end face as the other end face and serving as through channels of a fluid. The partition walls each have a base layer containing from 50 to 90 mass % of zeolite and a coat layer with which the surface of the base layer 11 is coated with a thickness of from 1 to 50 μm. The coat layer is either a coat layer (A) containing from 1 to 5 mass % vanadia and titania or a coat layer (B) containing from 1 to 5 mass % vanadia and a composite oxide of titania and tungsten oxide.

The present disclosure provides a method for preparing a selective catalytic reduction (SCR) catalyst, the SCR catalyst comprises a metal ion-exchanged zeolite. A method uses an in-situ ion exchange process. A process includes admixing a zeolite in the ammonium (NH.sub.4.sup.+) form with an aqueous mixture comprising water, a transition metal ion source, and, optionally, an acid, to form a slurry containing a metal ion-exchanged zeolite.

The present invention relates to a compressed natural gas combustion and exhaust system comprising: (i) a natural gas combustion engine; and (ii) an exhaust treatment system, the exhaust treatment system comprising a intake for receiving an exhaust gas from the combustion engine and a catalyst article arranged to receive and treat the exhaust gas, wherein the catalyst article comprises: a substrate having at least first and second coatings, the first coating being free from platinum-group-metals and comprising a copper-containing zeolite having the CHA framework-type and the second coating comprising a palladium-containing zeolite, wherein the first coating is arranged to contact the exhaust gas before the second coating. The present invention further relates to a method and a use.

The present invention relates to a catalyst comprising a carrier substrate of length L, coating A arranged as the first layer on the carrier and containing platinum on a metal oxide, and coating B applied as the second layer to coating A and containing a Cu-exchanged molecular sieve and no noble metal, wherein the total washcoat quantity of coating A is 40 g/l or more of washcoat in relation to the coated catalyst volume.

The present invention relates to a method for the preparation of a molecular sieve of the CHA-type as well as catalytic applications thereof.