Patent classifications
B01J29/74
Process and Materials for Trim Dewaxing of Distillates
Described herein are novel and inventive dewaxing processes that employ dewaxing catalysts which are co-extrusions of two different zeolites, particularly two different 10MR zeolites or a co-extrusion of a 10MR zeolite and a 12MR zeolite in combination with a hydrogenation component. The hydrogenation component can be a mixture of non-noble metal components or a mixture of noble metal components. This novel and inventive process demonstrated a significant activity boost (as measured by increased cloud point reduction) and/or selectivity boost (as measured by reduced diesel loss) compared to either single zeolite component.
Catalyst comprising a mixture of an AFX-structure zeolite and a BEA-structure zeolite and at least one transition metal for selective reduction of NOx
The invention relates to a catalyst comprising a mixture of AFX-structure and BEA-structure zeolites and at least one additional transition metal, to the process for preparing same and to the use thereof for the selective catalytic reduction of NOx in the presence of a reducing agent such as NH.sub.3 or H.sub.2.
Process for the preparation of an aromatic compound from biomass
A process for the production of an aromatic compound which comprise reacting a mixture comprising ethylene and a furan compound over a zeolitic material having a BEA-type framework structure is described, wherein the zeolitic material having a BEA-type framework structure comprised in the catalyst is obtainable and/or obtained according to an organotemplate-free synthetic process.
Catalyst for exhaust gas oxidation, method for producing same, and exhaust gas oxidation method using same
Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.
Molecular sieve intergrowths of <i>cha </i>and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Molecular sieve intergrowths of <i>cha </i>and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
LOW TEMPERATURE NOX ADSORBER WITH ENHANCED REGENERATION EFFICIENCY
The present disclosure provides Low Temperature NO.sub.x-Absorber (LT-NA) catalyst compositions, catalyst articles, and an emission treatment system for treating an exhaust gas, each including the LT-NA catalyst compositions. Further provided are methods for reducing a NO.sub.x level in an exhaust gas stream using the LT-NA catalyst articles. In particular, the LT-NA catalyst compositions include a first zeolite, a first palladium component, and a plurality of platinum nanoparticles. The LT-NA catalyst compositions exhibit enhanced regeneration efficiency with respect to NO.sub.x adsorption capacity, even after hydrothermal aging.
LOW TEMPERATURE NOX ADSORBER WITH ENHANCED REGENERATION EFFICIENCY
The present disclosure provides Low Temperature NO.sub.x-Absorber (LT-NA) catalyst compositions, catalyst articles, and an emission treatment system for treating an exhaust gas, each including the LT-NA catalyst compositions. Further provided are methods for reducing a NO.sub.x level in an exhaust gas stream using the LT-NA catalyst articles. In particular, the LT-NA catalyst compositions include a first zeolite, a first palladium component, and a plurality of platinum nanoparticles. The LT-NA catalyst compositions exhibit enhanced regeneration efficiency with respect to NO.sub.x adsorption capacity, even after hydrothermal aging.
Heteroatom-Doped Zeolites For Bifunctional Catalytic Applications
Provided herein are methods for hydroisomerization of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with hydrogen and a catalyst to yield a hydrocarbon product having an increase in branched hydrocarbons relative to the hydrocarbon feedstock. The present catalysts comprise a heteroatom-doped Beta zeolite having a trivalent cation as a framework metal oxide, an extra-framework species comprised of cerium and/or cobalt, and from 0.01 to 1.5 wt. % of a group VIII or VIB metal, or a combination thereof.
Copper CHA zeolite catalysts
Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.