Patent classifications
B01J29/74
Low-temperature NO.SUB.x .storage catalyst used for automobile exhaust purification and preparation method thereof
A low-temperature NO.sub.x storage catalyst for automobile exhaust purification and a preparation method thereof. Loading a noble metal salt solution on molecular sieve by equal volume impregnation method, wherein the noble metal salt solution comprises palladium nitrate and platinum nitrate, and the molecular sieve comprises SSZ, SAPO and BETA, then drying at 60-120° C. for 2-6 h, roasting at 500-550° C. in air for 2-5 h, and further roasting at 750-850° C. in air for 2-5 h, and then mixing with aluminum sol, ball milling and pulping, and then coating the slurry on a carrier, wherein the loading on the coating is 100-250 g/L and the noble metal content is 10-150 g/ft.sup.3, drying at 60-120° C. for 2-6 h, then roasting at 500-550° C. in air for 2-5 h, and further continuing roasting at 750-850° C. in air for 2-5 h, to obtain the catalyst. Loading the noble metals Pt and Pd into a pore channel of a molecular sieve improves NO.sub.x storage capacity of a catalyst at low temperatures, and selecting a different type of molecular sieve as an NO.sub.x storage unit and increasing a roasting temperature of a molecular sieve material on which Pt and Pd are loaded significantly increases NO.sub.x storage capacity.
Low-temperature NO.SUB.x .storage catalyst used for automobile exhaust purification and preparation method thereof
A low-temperature NO.sub.x storage catalyst for automobile exhaust purification and a preparation method thereof. Loading a noble metal salt solution on molecular sieve by equal volume impregnation method, wherein the noble metal salt solution comprises palladium nitrate and platinum nitrate, and the molecular sieve comprises SSZ, SAPO and BETA, then drying at 60-120° C. for 2-6 h, roasting at 500-550° C. in air for 2-5 h, and further roasting at 750-850° C. in air for 2-5 h, and then mixing with aluminum sol, ball milling and pulping, and then coating the slurry on a carrier, wherein the loading on the coating is 100-250 g/L and the noble metal content is 10-150 g/ft.sup.3, drying at 60-120° C. for 2-6 h, then roasting at 500-550° C. in air for 2-5 h, and further continuing roasting at 750-850° C. in air for 2-5 h, to obtain the catalyst. Loading the noble metals Pt and Pd into a pore channel of a molecular sieve improves NO.sub.x storage capacity of a catalyst at low temperatures, and selecting a different type of molecular sieve as an NO.sub.x storage unit and increasing a roasting temperature of a molecular sieve material on which Pt and Pd are loaded significantly increases NO.sub.x storage capacity.
Molecular Sieve Intergrowths of cha and aft having an "sfw-GME tail," Methods of Preparation and Use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Molecular Sieve Intergrowths of cha and aft having an "sfw-GME tail," Methods of Preparation and Use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Heteroatom-Doped Zeolites For Bifunctional Catalytic Applications
Provided herein are methods for hydroisomerization of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with hydrogen and a catalyst to yield a hydrocarbon product having an increase in branched hydrocarbons relative to the hydrocarbon feedstock. The present catalysts comprise a heteroatom-doped Beta zeolite having a trivalent cation as a framework metal oxide, an extra-framework species comprised of cerium and/or cobalt, and from 0.01 to 1.5 wt. % of a group VIII or VIB metal, or a combination thereof.
PASSIVE NOx ADSORBER
A passive NOx absorber for treating an exhaust gas from a diesel engine is described. The passive NOx absorber comprises a first washcoat region comprising a zeolite catalyst, the zeolite catalyst comprising a noble metal and a zeolite having a SAR of 2-15.
PASSIVE NOx ADSORBER
A passive NOx absorber for treating an exhaust gas from a diesel engine is described. The passive NOx absorber comprises a first washcoat region comprising a zeolite catalyst, the zeolite catalyst comprising a noble metal and a zeolite having a SAR of 2-15.
COPPER CHA ZEOLITE CATALYSTS
Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
PLATINUM AND ZINC-CONTAINING ZEOLITE
The present invention relates to a zeolite comprising zinc and platinum, and to a catalyst containing said zeolites.
PLATINUM AND ZINC-CONTAINING ZEOLITE
The present invention relates to a zeolite comprising zinc and platinum, and to a catalyst containing said zeolites.