B01J29/7876

BASE METAL ISOMERIZATION CATALYSTS

An isomerization catalyst is provided, along with corresponding systems and methods, which provides improved isomerization for bio-derived feeds in reaction environments where by-products from deoxygenation are present. The catalyst provides unexpectedly increased activity and/or selectivity in situations where, for example, a deoxygenation effluent is cascaded to the isomerization catalyst. Additionally, the isomerization catalyst can assist with reducing or minimizing hydrogen consumption during isomerization. The increased activity, stability, and/or reduced hydrogen consumption is achieved in part based on using a dispersion agent when adding base metals to the catalyst. In addition to the base metals, the catalyst includes a zeolitic framework structure suitable for isomerization.

CATALYSTS SUPPORTED ON MODIFIED-CARRIER FOR OXIDATIVE COUPLING REACTION OF METHANE AND METHOD FOR OXIDATIVE COUPLING REACTION OF METHANE USING THE SAME

The present disclosure relates to catalysts supported on a modified-carrier for oxidative coupling reaction of methane and a method for oxidative coupling reaction of methane using the same. The catalysts in which sodium tungstate is supported on a delaminated zeolite carrier increase the methane conversion rate and the selectivity to C.sub.2+ hydrocarbon compounds and thereby improve the reactivity of the oxidative coupling reaction of methane.

Supported nano sized zeolite catalyst for alkylation reactions

A catalyst containing nanosize zeolite particles supported on a support material for alkylation reactions, such as the alkylation of benzene to form ethylbenzene, and processes using such a catalyst is disclosed.

Catalyst composition and process for producing aromatic hydrocarbon using the catalyst composition

It is an object of the present invention to provide a catalyst that is excellent in stability even at a high catalyst-regeneration temperature. It is another object of the present invention to provide a process for producing an aromatic hydrocarbon from a lower hydrocarbon by using the above catalyst. The catalyst composition comprises molybdenum, a second metal that is not molybdenum, and a crystalline metallosilicate, wherein the content of molybdenum is 1 to 20% by weight in terms of a molybdenum atom, and the content of the second metal is 2 to 20% by weight in terms of a metal atom.

Process for dehydroaromatization of alkanes with in-situ hydrogen removal
10196330 · 2019-02-05 · ·

A process for conversion of natural gas to aromatic hydrocarbons in a catalytic membrane reactor is described herein. The catalytic membrane reactor comprises a dehydrogenation catalyst and a membrane that can selectively transport hydrogen under high temperature operating conditions such as 600 C. to 800 C. Aromatic hydrocarbons are produced stably for a long time by a process characterized by hydrogen co-feed with the reaction gases to the one end of the to the reaction zone while hydrogen is extracted selectively with use of the membrane as the reactive gas mix passes through the reaction zone.

Fixed-bed alkyl-aromatic conversion process

A method of preparing a metal-doped zeolite catalyst with a modified topology (e.g. a pillared zeolite or a delaminated zeolite), and a method of using thereof in a process for converting an alkyl-aromatic hydrocarbon stream to BTX (benzene/toluene/xylene), wherein an enhanced pore topology in the metal-doped zeolite catalyst determines a selectivity to transalkylation of trimethylbenzene to xylene, which in turn leads to a higher xylene yield. Various embodiments of the method of preparing the metal-doped zeolite catalyst, and the process for converting the alkyl-aromatic hydrocarbon stream to BTX are also provided.

Process for forming a xylene-rich stream

A method of preparing a metal-doped zeolite catalyst with a modified topology (e.g. a pillared zeolite or a delaminated zeolite), and a method of using thereof in a process for converting an alkyl-aromatic hydrocarbon stream to BTX (benzene/toluene/xylene), wherein an enhanced pore topology in the metal-doped zeolite catalyst determines a selectivity to transalkylation of trimethylbenzene to xylene, which in turn leads to a higher xylene yield. Various embodiments of the method of preparing the metal-doped zeolite catalyst, and the process for converting the alkyl-aromatic hydrocarbon stream to BTX are also provided.

Method for forming a zeolite catalyst and use thereof to form a BTX-rich stream

A method of preparing a metal-doped zeolite catalyst with a modified topology (e.g. a pillared zeolite or a delaminated zeolite), and a method of using thereof in a process for converting an alkyl-aromatic hydrocarbon stream to BTX (benzene/toluene/xylene), wherein an enhanced pore topology in the metal-doped zeolite catalyst determines a selectivity to transalkylation of trimethylbenzene to xylene, which in turn leads to a higher xylene yield. Various embodiments of the method of preparing the metal-doped zeolite catalyst, and the process for converting the alkyl-aromatic hydrocarbon stream to BTX are also provided.

Method of Forming a Catalyst with an Ion-Modified Binder
20180297017 · 2018-10-18 ·

An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.

AN ADDITIVE AND A CATALYST COMPOSITION COMPRISING THE ADDITIVE FOR FCC PROCESS

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.