N.sup.2-phosphinyl formamidine compounds and N.sup.2-phosphinyl formamidine metal salt complexes are described. Methods for making N.sup.2-phosphinyl formamidine compounds and N.sup.2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N.sup.2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N.sup.2-phosphinyl amidine compounds and N.sup.2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

A process to produce 1-octene and 1-decene includes (a) separating a composition containing an oligomer productwhich contains 15 to 80 mol % C.sub.6 olefins, 20 to 80 mol % C.sub.8 olefins, and 5 to 20 mol % C.sub.10+ olefinsinto a first oligomer composition containing C.sub.6 alkanes and at least 85 mol % C.sub.6 olefins (e.g., 1-hexene), a second oligomer composition containing at least 20 mol % C.sub.8 olefins (e.g., 1-octene), and a heavies stream containing C.sub.10+ olefins, then (b) contacting a metathesis catalyst system with the first oligomer composition to form a first composition comprising C.sub.10 linear internal olefins, (c) contacting the C.sub.10 linear internal olefins with a catalytic isomerization catalyst system in the presence of photochemical irradiation to form a second composition comprising 1-decene, and (d) purifying the second composition to isolate a third composition comprising at least 90 mol % 1-decene. Processes to produce 1-hexene and 1-decene also are described, as well as related manufacturing systems and processes to produce higher carbon number normal alpha olefins from lower carbon number normal alpha olefins.

Provided are a catalyst system for olefin oligomerization reaction and a method for olefin oligomerization, and more particularly, a catalyst system for olefin oligomerization reaction and a method for olefin oligomerization, which enable more efficient preparation of alpha-olefin, because a catalytic active ingredient is supported on a support, thereby exhibiting high activity in olefin oligomerization reaction even by using smaller amounts of a catalyst composition and a cocatalyst.

The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

Provided are a catalyst composition and a method of oligomerizing olefins using the same. When the catalyst composition according to the present invention is used, oligomerization and copolymerization of olefin monomers may be performed in a single reactor at the same time with high efficiency without a separate process of preparing alpha-olefin. Therefore, costs for preparing or purchasing comonomers which are expensive raw materials may be reduced, thereby reducing the production cost of a final product. Contents of SCB (short chain branch) and LCB (long chain branch) in the polyolefin may be increased without separate feeding of comonomers, thereby producing high-quality linear low-density polyethylene.

A metal-ligand complex has formula (I): wherein J, L, M, R.sup.1, R.sup.2, R.sup.3, R.sup.4, X, p, q, and r are defined herein. The metal-ligand complex is useful as a catalyst or catalyst precursor for olefin polymerization. ##STR00001##

Catalyst materials for olefin metathesis reactions. The catalyst materials comprise a ruthenium phosphinimine complex. The ruthenium phosphinimine may be synthesized without bound N-heterocyclic carbene (NHC) or phosphine ligands, thereby providing significant advantageous in conversion, selectivity, and stability compared to existing ruthenium-based catalysts.

A catalyst for ethylene dimerization is provided. The catalyst includes a metal-organic framework; a phosphinamine ligand; and a salt.

N.sup.2-phosphinyl amidine compounds, N.sup.2-phosphinyl amidinates, N.sup.2-phosphinyl amidine metal salt complexes, N.sup.2-phosphinyl amidinate metal salt complexes are described. Methods for making N.sup.2-phosphinyl amidine compounds, N.sup.2-phosphinyl amidinates, N.sup.2-phosphinyl amidine metal salt complexes, and N.sup.2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N.sup.2-phosphinyl amidine metal salt complexes and N.sup.2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N.sup.2-phosphinyl amidine compounds, N.sup.2-phosphinyl amidinates, N.sup.2-phosphinyl amidine metal salt complexes, and N.sup.2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

The method for oligomerizing olefin according to the present disclosure is a method for oligomerizing olefin using an oligomerization catalyst system and includes deteriorating the activity of the oligomerization catalyst system by injecting a deactivator in a latter part of a multimerization reaction of olefin. The deactivator may include an additive for polymer containing at least one functional group selected from the group consisting of a hydroxyl group, an amine group and an amide group. According to the oligomerizing method, the isomer of 1-hexene and/or 1-octene and alpha-olefins with C.sub.10 to C.sub.40 may be decreased via the restraint of the additional side reaction of a product. Since the deactivator is an additive for enhancing the physical properties of a polymer, a separating process thereof is not required, thereby improving economic feasibility and productivity.