The present disclosure provides a process for the preparation of perfluoroalkyl sulfenyl chloride by reacting a compound of formula [I] with at least one fluoride compound and thiophosgene. ##STR00001##

A reservoir for one or more chemical reactants has means for heating the reactants and optional means for stirring the reactants. A pumped reactant feed line and a return line provide fluid communication between the reservoir and a 4-way valve system. The 4-way valve system is also in fluid communication with a reactor vessel and a source of inert gas for purging the system. In a first state, the 4-way valve provides fluid communication between the reservoir and the reactor. In a second state, the 4-way valve provides a continuous circulation path for the heated reactants from the reservoir, to the valve system, and back to the reservoir via the return line. In a third state, the 4-way valve provides a fluid pathway for purging the reactor with inert gas. In a fourth state, the 4-way valve provides a fluid pathway for purging the reservoir with inert gas.

A process is provided for carrying out an oxidation on a sprayable feed including a furanic substrate to be oxidized and a catalytically effective combination of cobalt, manganese, and bromide components for catalyzing the oxidation of the furanic substrate, which process comprises spraying the feed into a reactor vessel as a mist, supplying an oxidant, reacting the furanic substrate and the oxidant, and managing the exothermic temperature rise due to the reaction through a selection and control of the operating pressure within the reactor vessel. A crude dehydration product from the dehydration of fructose, glucose or both, including 5-hydroxymethylfurfural, can be directly oxidized by the process to produce 2,5-furandicarboxylic acid in surprisingly increased yields.

A method is described that includes contacting an olefin with a catalyst in a polymerization reactor, polymerizing at least a portion of the olefin to form an alpha olefin reaction product, detecting a condition within the polymerization reactor, determining an average temperature of at least one olefin product particle based on the condition, determining an operating particle temperature threshold using a foul curve, comparing the average temperature of the polymer particle to the operating particle temperature threshold, changing one or more operating parameters in response to the comparing, and maintaining the average temperature of the olefin polymer particle at or below the operating particle temperature threshold in response to changing the one or more operating parameters. The alpha olefin reaction product includes a plurality of olefin polymer particles, and the polymerization reactor includes a reaction mixture that includes the olefin, the catalyst, a diluent, and the alpha olefin reaction product.

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

A method for shutting down a gas treatment plant to minimize flaring and allow for continued production during the shutdown procedure. The method includes reducing a sour gas feed flow rate and monitoring pressures in headers for various process units to identify when pressure equalization occurs. The method includes sampling the rich solvent in the system to verify a setpoint concentration of hydrogen sulfide has been reached to initiate a final system shutdown.

Systems for producing hydrogen gas for local distribution, consumption, and/or storage, and related devices and methods are disclosed herein. A representative system includes a pyrolysis reactor that can be coupled to a supply of reaction material that includes a hydrocarbon. The reactor includes one or more flow channels positioned to transfer heat to the reaction material to convert the hydrocarbon into an output that includes hydrogen gas and carbon particulates. The system also includes a carbon separation system operably coupled to the pyrolysis reactor to separate the hydrogen gas the carbon particulates in the output. In various embodiments, the system also includes components to locally consume the filtered hydrogen gas.

A polyolefin reactor flashline heater system may include an enclosure, a heating section, and a transformer. The heating section is contained in the enclosure and extends between a first end and a second end. The first end is fluidically coupled to a polyolefin reactor product inlet. The second end is fluidically coupled to a heated product outlet. One or more pipe sections are coupled in series between the first end and the second end. The one or more pipe sections are formed of an electrically conducting material and have a predetermined diameter to transport a polyolefin reactor stream from the first end to the second end. The transformer is electrically coupled to the first end and the second end and configured to heat the heating section by impedance heating. A polymerization system may include a polyolefin reactor coupled to the polyolefin reactor flashline heater system.