A process includes periodically or continuously introducing an olefin monomer and periodically or continuously introducing a catalyst system or catalyst system components into a reaction mixture within a reaction system, oligomerizing the olefin monomer within the reaction mixture to form an oligomer product, and periodically or continuously discharging a reaction system effluent comprising the oligomer product from the reaction system. The reaction system includes a total reaction mixture volume and a heat exchanged portion of the reaction system comprising a heat exchanged reaction mixture volume and a total heat exchanged surface area providing indirect contact between the reaction mixture and a heat exchange medium. A ratio of the total heat exchanged surface area to the total reaction mixture volume within the reaction system is in a range from 0.75 in.sup.1 to 5 in.sup.1, and an oligomer product discharge rate from the reaction system is between 1.0 (lb)(hr.sup.1)(gal.sup.1) to 6.0 (lb)(hr.sup.1)(gal.sup.1).

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 m to 20 m.

Liquid flow in a reaction processing vessel 10 is set to a spiral flow, a liquid A and B as an additional liquid containing an inorganic substance to be added is injected at a center-side position with respect to an inner surface of the reaction processing vessel 10 in a reaction field of the reaction processing vessel 10 so as to perform reaction processing.

A system and method is provided for upgrading a continuously flowing process stream including heavy crude oil (HCO). A reactor receives the process stream in combination with water, at an inlet temperature within a range of about 60 C. to about 200 C. The reactor includes one or more process flow tubes having a combined length of about 30 times their aggregated transverse cross-sectional dimension, and progressively heats the process stream to an outlet temperature T(max)1 within a range of between about 260 C. to about 400 C. The reactor maintains the process stream at a pressure sufficient to ensure that it remains a single phase at T(max)1. A controller selectively adjusts the rate of flow of the process stream through the reactor to maintain a total residence time of greater than about 1 minute and less than about 25 minutes.

The invention provides a continuous process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of: i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream; ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel; iii) withdrawing a product stream comprising glycols from the reactor vessel; iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and v) recycling the remainder of said product stream via the external recycle loop.

The invention provides a continuous process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of: i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream; ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel; iii) withdrawing a product stream comprising glycols from the reactor vessel; iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and v) recycling the remainder of said product stream via the external recycle loop.

A reactor system for high temperature reactions of reactants includes at least one reactant containing carbon. The reactor includes a reactor, a liquid media disposed within the reactor, and a solid carbon reaction product. The liquid media does not react irreversibly with the reactant to form products, and the liquid media wets at least a portion of a surface within the reactor. The solid carbon reaction product does not contact at least the portion of the surface within the reactor where the liquid media wets the portion of the surface within the reactor.

A butanol production system and method for producing refined mixed butanols includes an internal baffle single pass reactor having an internal fluid conduit defined by an internal wall. The internal fluid conduit contains a process fluid comprising water, mixed butenes and mixed butanols, to form a crude product. Internal flow baffles are located along a length of the internal fluid conduit. Baffled cells are defined at an outer diameter by the internal wall and at ends by the internal flow baffles. A separation system separates water and mixed butenes from the crude product to produce refined mixed butanols. An oscillator assembly is coupled to the internal baffle single pass reactor and has a reciprocating oscillator head selectively movable in a back and forth linear motion, and in communication with the process fluid such that the process fluid undergoes a general sinusoidal movement along the internal baffle single pass reactor.

A process for preparing crystalline particles of an active principal in the presence of ultrasonic irradiation that comprises contacting a solution of a solute in a solvent in a first flowing stream with an anti-solvent in a second flowing stream causing the mixing thereof, wherein the flow rate ratio of the anti-solvent: solvent is higher than 20:1, and collecting crystals that are generated.

The invention provides a method and system for extracting stranded gas (such as natural gas or hydrogen) or a mixture of oil and natural gas from a subterranean environment such as beneath the ocean floor and converting it into a solid hydrate such as a clathrate featuring a) extracting stranded gas (such as natural gas or hydrogen) or a mixture of oil and natural gas; b) optionally separating the natural gas from the mixture of oil and natural gas in a first tank or vessel; c) transporting the stranded gas to a second tank or vessel; d) introducing sea water into the second tank or vessel; e) mixing the stranded gas and water to form a clathrate hydrate/water slurry; f) removing excess water from the clathrate hydrate slurry to form a solid comprising a clathrate hydrate; and g) processing the solid comprising a clathrate hydrate into a transportable form; and h) optionally collecting the gas into a transportable vessel.