Integrated gaseous fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the gaseous fuel CPOX reformer.

A liquid fuel catalytic partial oxidation (CPOX) reformer can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. At least the exterior surface of the CPOX reaction zone can include a hydrogen barrier. The liquid fuel CPOX reformer can include a vaporizer, one or more igniters, and a source of liquid reformable fuel.

A quenching medium is delivered directly to selected regions or locations within a catalyst bed in a hydroprocessing reactor vessel in order to control the reactivity of a hydroprocess occurring in the selected regions or locations separately from other regions or locations. Temperature sensors for providing temperature indications and conduits for delivering the quench medium are distributed throughout the catalyst bed. One or more conduits can be selected for delivery of the quenching medium to selected regions or locations so that separate control of the level of reactivity in each of various regions or locations throughout the bed can be achieved.

A process includes periodically or continuously introducing an olefin monomer and periodically or continuously introducing a catalyst system or catalyst system components into a reaction mixture within a reaction system, oligomerizing the olefin monomer within the reaction mixture to form an oligomer product, and periodically or continuously discharging a reaction system effluent comprising the oligomer product from the reaction system. The reaction system includes a total reaction mixture volume and a heat exchanged portion of the reaction system comprising a heat exchanged reaction mixture volume and a total heat exchanged surface area providing indirect contact between the reaction mixture and a heat exchange medium. A ratio of the total heat exchanged surface area to the total reaction mixture volume within the reaction system is in a range from 0.75 in.sup.1 to 5 in.sup.1, and an oligomer product discharge rate from the reaction system is between 1.0 (lb)(hr.sup.1)(gal.sup.1) to 6.0 (lb)(hr.sup.1)(gal.sup.1).

The present invention relates to a steam to carbon ratio control device including: a heat source, and an evaporation mixer and a steam separator interconnected by pipelines, said connecting pipelines of the evaporation mixer and the steam separator are provided with a temperature control device and a pressure control device, said evaporation mixer is provided with a natural gas inlet, a desalinated water inlet and a mixed gas outlet, the inlet of said heat source is connected with a end closer to the natural gas inlet of the evaporation mixer, the outlet of said heat source is connected to a end closer to the mixed gas outlet. Comparing with the prior art, the beneficial effect of the present invention is that it can accurately control the proportion of natural gas to steam and stably control the flow rates of natural gas and steam.

A method is described that includes contacting an olefin with a catalyst in a polymerization reactor, polymerizing at least a portion of the olefin to form an alpha olefin reaction product, detecting a condition within the polymerization reactor, determining an average temperature of at least one olefin product particle based on the condition, determining an operating particle temperature threshold using a foul curve, comparing the average temperature of the polymer particle to the operating particle temperature threshold, changing one or more operating parameters in response to the comparing, and maintaining the average temperature of the olefin polymer particle at or below the operating particle temperature threshold in response to changing the one or more operating parameters. The alpha olefin reaction product includes a plurality of olefin polymer particles, and the polymerization reactor includes a reaction mixture that includes the olefin, the catalyst, a diluent, and the alpha olefin reaction product.

Systems and methods conducive to the formation of one or more alkene hydrocarbons using a methane source and an oxidant in an oxidative coupling of methane (OCM) reaction are provided. One or more vessels each containing one or more catalyst beds containing one or more catalysts each having similar or differing chemical composition or physical form may be used. The one or more catalyst beds may be operated under a variety of conditions. At least a portion of the catalyst beds may be operated under substantially adiabatic conditions. At least a portion of the catalyst beds may be operated under substantially isothermal conditions.

Various examples are provided related to nanoparticle synthesis. In one example, a system includes a self-driven fluidics platform including a chemical handling module and a reactor module. A mixer can form an initial mixture and deliver it through the ejector port as part of a segmented flow. The reactor module can control environmental conditions during synthesis of a nanoparticle. A flow reactor includes a channel that allows the segmented flow to move through the flow reactor via the channel and at least one observation window to enable real-time characterization of nanoparticles in individual droplets in the segmented flow through the flow reactor. In another example, a method comprises forming and flowing a segmented flow of droplets into a reactor, measuring a target property of nanoparticles in droplets in the segmented flow, and adjusting formation of droplets added to the segmented flow based upon the measured target property.

A method is described for shutting down a Fischer-Tropsch reactor fed with a reactant gas mixture comprising a synthesis gas and a recycle gas recovered from the Fischer-Tropsch reactor in a synthesis loop, said Fischer-Tropsch reactor containing a Fischer-Tropsch catalyst cooled indirectly by a coolant under pressure, comprising the steps of: (a) depressurising the coolant to cool the reactant gas mixture to quench Fischer-Tropsch reactions taking place in the Fischer-Tropsch reactor, (b) stopping the synthesis gas feed to the Fischer-Tropsch reactor, and (c) maintaining circulation of the recycle gas through the Fischer-Tropsch reactor during steps (a) and (b) to remove heat from the Fischer-Tropsch reactor. The method safely facilitates a more rapid return to operating conditions than a full shut-down.