The present disclosure provides processes for producing polyethylene resins. In at least one embodiment, a polyethylene has: a density of from about 0.91 g/cm.sup.3 to about 0.94 g/cm.sup.3; a value of Mz of about 1,500,000 g/mol or greater; and a ratio of Mz to Mw of about 7 or greater. A process includes introducing a first feed stream having ethylene monomer and a first free radical initiator to a first inlet of a first reaction zone, where the first reaction zone has a first inlet temperature. The process further includes introducing a second feed stream having ethylene monomer and a second free radical initiator to a second inlet of a second reaction zone, where the second reaction zone has a second inlet temperature that is the same or different than the first inlet temperature.

This disclosure relates to an article (e.g., a vapor-permeable, substantially water-impermeable multilayer article) that includes a nonwoven substrate and a film supported by the nonwoven substrate. The film includes a polyolefin, a nanoclay, and a pore-forming filler.

This disclosure relates to an article that includes a nonwoven substrate, a first film supported by the nonwoven substrate, and a second film such that the first film is between the nonwoven substrate and the second film. The first film includes a first polymer and a pore-forming filler. The difference between a surface energy of the first film and a surface energy of the nonwoven substrate is at most about 10 mN/m. The second film includes a second polymer capable of absorbing and desorbing moisture and providing a barrier to aqueous fluids.

This invention provides a food container which can be manufactured cheaply by using inexpensive general PET resin or further inexpensive PET resin for fiber or recovered PET flakes, and nevertheless, which has a high heat resistance up to 250° C., and the container is obtained by adding a chain extender and a compatibilizer and talc to PET resin, charging the mixture into an extruder 30 having two or more vent holes, degassing under a condition where the PET resin is melted with heating by sucking at a high vacuum of −99.99 kPa or lower from the vent holes 33, 34, thereafter, forming a sheet by extrusion molding, pressure-forming with vacuum the sheet by a thermoforming machine, forming the container by keeping in a mold at 100-220° C. The container has a total of the content of crystal portion represented by the following formula and the content of talc being 25% by weight or more.

A metal member according to the present invention is a metal member having a surface in contact with a rubber material, wherein at least a portion of the surface of the metal member in contact with the rubber material is formed from an alloy containing cobalt and chromium, and the metal member comprises a fluid passage for adjusting a temperature of the at least a portion of the surface of the metal member in contact with the rubber material.

The present invention aims to provide an ETFE film having excellent transparency and heat resistance and cost efficiency. The present invention relates to a film including a copolymer containing an ethylene unit, a tetrafluoroethylene unit, and a (fluoroalkyl)ethylene unit represented by Formula (1):
CH.sub.2═CX—Rf  (1)
wherein X represents H or F, and Rf represents a fluoroalkyl group having 2 or more carbon atoms, the copolymer containing the (fluoroalkyl)ethylene unit in an amount of 0.8 to 2.5 mol % relative to the amount of all the monomer units and containing the ethylene unit and the tetrafluoroethylene unit at a molar ratio of 30.0/70.0 to 50.0/50.0, the film having a crystallinity of 68% or less, the crystallinity being calculated on the basis of a diffraction intensity curve of the film resulting from X-ray diffraction measurement.

The smoothing device for plastic films comprises plastic-melt-producing means (1, 5), an adjustable slit die (10) and a roller smoothing unit (16) having cooled smoothing rollers (11, 12), which form an adjustable smoothing gap (13) between each other. Optionally, further rollers (15) are arranged downstream. A thickness gauge (23) measures the thickness of the plastic-film web (22). A controller (30) for controlling the thickness of the plastic-film web (22) may set a setpoint thickness (SD) of the plastic-film web (22) and the volumetric flow rate (SS) of the plastic melt or the line speed (LS). The controller (30) captures the current torques and rotational speeds of the rollers (11, 12, 15) and the current thickness (FD, FD1-FDn) of the plastic-film web (22).

The controller (30) sends setpoint rotational speed signals (C0S, C2S-CnS, CAS) calculated from the captured torques of the rollers (11, 12, 15) to the drives of the rollers and a smoothing-gap setpoint distance signal (GW) for adjusting the smoothing gap (13), and furthermore—in the case of a specified line speed (LS)—setpoint plastic-melt volumetric flow rate signals (SS) to the plastic-melt-producing means, or—in the case of a specified plastic-melt volumetric flow rate (SS)—setpoint line speed signals (LS) to the drives of the rollers (12).

Printed, breathable thermoplastic films, laminates, and methods of making films having a basis weight less than or equal to 15 gsm and a water vapor transmission rate of at least about 500 grams H.sub.2O/24-hour/m.sup.2, wherein the film has a ratio of the MD load at break to the CD load at break of less than about 10, and at least one of a machine-direction notched Elmendorf tear strength of at least about 5 g or a machine-direction notched trapezoidal tear strength of at least about 15 g.

A film that comprises a thermoplastic composition that contains a continuous phase that includes a polyolefin matrix polymer and a nanoinclusion additive dispersed within the continuous phase in the form of discrete domains is provided. The film is biaxially stretched in a machine direction and cross-machine direction to form a porous network in the composition. The porous network contains nanopores having a maximum cross-sectional dimension of about 800 nanometers or less. At least a portion of the nanopores are oriented in the cross-machine direction so that the axial dimension generally extends in the cross-machine direction and the cross-sectional dimension generally extends in the machine direction.

The polyester sheet in accordance with an aspect of the present invention contains crystals of polyester which is a polycondensate of polyvalent carboxylic acid and polyalcohol. The polyester sheet contains nano-oriented crystals which contain crystals of polyester in each of which a polymer chain is highly oriented and each of which has a crystal size of 50 nm or less. A heatproof temperature of the polyester sheet is higher than a temperature that is lower than an equilibrium melting point of the polyester by 80° C., and a melting point of the polyester sheet is higher than a temperature that is lower than the equilibrium melting point of the polyester by 40° C.