Patent classifications
B01J23/626
METHANE COMBUSTION CATALYST, METHOD FOR PRODUCING THE SAME AND METHOD FOR PURIFYING COMBUSTION EXHAUST GAS
The present invention relates to a methane combustion catalyst including platinum and iridium supported on a tin oxide carrier for combusting methane in a combustion exhaust gas containing sulfur oxide. In the methane combustion catalyst, a ratio R.sub.TO of platinum oxides to metal platinum is 8.00 or more, wherein the ratio R.sub.TO is based on existence percentages of the metal platinum (Pt) and the platinum oxides (PtO and PtO.sub.2) obtained from a platinum 4f spectrum analyzed and measured by X-ray photoelectron spectroscopy (XPS) and calculated in accordance with the following expression. In the following expression, R.sub.Pt is an existence percentage of the metal platinum (Pt), R.sub.Pto is an existence percentage of PtO, and R.sub.Pto2 is an existence percentage of PtO.sub.2.
R.sub.TO=(R.sub.PtO+R.sub.PtO2)/R.sub.Pt [Expression 1]
RADIAL BED REACTOR ALLOWING THE USE OF A SMALL QUANTITY OF CATALYST
The present invention describes a type of radial bed reactor which can allow a small quantity of catalyst to be used. Application to a regenerative reforming process reactor.
DEHYDROGENATION OF PROPANE USING A METAL-CONTAINING CATALYST ON A SUPPORT
The present invention relates to a process of producing a metal-containing catalyst. The process involves mixing a support material with one or more metals in a solution to produce a catalyst comprising a metal-loaded support. The catalyst comprising a metal-loaded support is treated with an atmosphere comprising 0.01 to 100% carbon-containing agents and 0-100% hydrogen at a temperature of 50 to 500° C. to produce a treated metal-containing catalyst on a support. Also disclosed is the resulting treated metal-containing catalyst and its use in a process for converting propane to propylene.
IMPROVED AIR PURIFICATION SYSTEM AND METHOD FOR REMOVING FORMALDEHYDE
A system for decomposing contaminants, including volatile compounds (VOCs), with a visible-spectrum photocatalytic composition.
Alkane dehydrogenation catalyst and process for its preparation
The invention relates to a catalyst composition comprising (a) a metal M selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh), rhenium (Re), ruthenium (Ru) and iridium (Ir), (b) tin (Sn), (c) zinc (Zn), (d) alkaline earth metal and (e) a porous metal oxide catalyst support, wherein the amount of each of elements (a), (b) and (d) is independently chosen in the range of from 0.1 to 5 wt. % based on the porous metal oxide catalyst support and wherein the amount of element (c) is chosen in the range of from 0.1 to 2 wt. % based on the porous metal oxide catalyst support. Furthermore, the invention also relates to a process for the preparation of said catalyst composition and its use in non-oxidative dehydrogenation of an alkane, preferably propane.
CATALYST PARTICLES, CARBON-SUPPORTED CATALYST PARTICLES AND FUEL CELL CATALYSTS, AND METHODS OF MANUFACTURING SUCH CATALYST PARTICLES AND CARBON-SUPPORTED CATALYST PARTICLES
A catalyst particle is composed of an inner particle and an outermost layer that includes platinum and covers the inner particle. The inner particle includes on at least a surface thereof a first oxide having an oxygen defect.
METHODS AND REFORMING SYSTEMS FOR RE-DISPERSING PLATINUM ON REFORMING CATALYST
Methods and systems for re-dispersing platinum on catalysts used in continuous catalyst regeneration reformer systems are disclosed. Some aspects of the disclosure provide, for example, methods of evaluating the platinum re-dispersion of a reforming catalyst in a small-scale reactor for use in a continuous catalyst regeneration reformer system and methods of improving the activity and selectivity of reforming catalysts for use in a continuous catalyst regeneration reformer system by selection of appropriate reaction parameters in a small-scale reactor for use in a continuous catalyst regeneration reformer system.
REFORMING CATALYST AND A METHOD OF PREPARATION THEREOF
The present disclosure relates to a reforming catalyst composition comprising a spherical gamma AI.sub.2O.sub.3 support; at least one Group VB metal oxide sheet coated on to the AI.sub.2O.sub.3 support; and at least one active metal and at least one promoter metal impregnated on the AI.sub.2O.sub.3 coated support. The reforming catalyst composition of the present disclosure has improved activity, better selectivity for total aromatics during naphtha reforming and results in less coke formation. The reforming catalyst composition has improved catalyst performance with simultaneous modification of acidic sites as well as metallic sites through metal support interaction. The acid site cracking activity of the catalyst is inhibited because of the use of chloride free alumina support modified with solid acid such as Group VB metal oxide and impregnated with active metals. The present disclosure provides a process for naphtha reforming in the presence of the reforming catalyst composition of the present disclosure to obtain reformates of naphtha.
DIRECT SYNTHESIS METHOD OF NANOSTRUCTURED CATALYST PARTICLES ON VARIOUS SUPPORTS AND CATALYST STRUCTURE PRODUCED BY THE SAME
Disclosed is a direct synthesis method of nanostructured catalyst particles on surfaces of various supports. In the disclosed synthesis method of a catalyst structure having a plurality of nanostructured catalyst particles dispersed in a support by a one-step process using a high-temperature high-pressure closed reactor, the one-step process includes supplying the support and a catalyst source into the high-temperature high-pressure closed reactor; supplying an atmosphere forming gas of the reactor into the reactor; perfectly sealing the high-temperature high-pressure closed reactor and heating the reactor to produce the catalyst structure in the reactor under self-generated pressure and synthesis temperature conditions, the catalyst structure including the plurality of nanostructured catalyst particles dispersed in the support; removing internal gases of the reactor to allow the reactor to be in a high-temperature, atmospheric pressure state and supplying an inert gas into the reactor to remove unreacted materials and byproducts remaining in the reactor; and cooling the reactor to room temperature while supplying the inert gas to synthesize the catalyst structure.
PROCESS FOR MODIFYING A HETEROGENEOUS CATALYST WITH AN ORGANOMETALLIC COMPOUND, A HETEROGENEOUS CATALYST AND SYSTEM THEREOF
The present disclosure relates to a process and system for modifying heterogeneous catalysts by contacting them with chemical compounds. Specifically, the present disclosure relates to an easy and convenient process for surface functionalizing of a heterogeneous catalyst such as polymetallic catalyst including bimetallic catalyst by employing precursor of inorganic compound, wherein the precursor is organometallic compound and wherein the inorganic compound includes but is not limited to a metal based inorganic compound such as aluminium oxide. The present disclosure thus provides for easy and convenient process and system for surface modification/functionalization of heterogeneous catalysts by employing precursor of inorganic compound at conditions including but not limiting to room temperature and atmospheric pressure.