B01J23/6525

Rhodium catalyst for decomposing nitrous oxide, the production thereof, and the use thereof

The present invention relates to a nitrous oxide decomposition catalyst, the preparation and use. The catalyst contains rhodium on a catalyst carrier. The carrier is obtained by mixing zirconium dioxide powder with a silicon compound as binder, to form a kneadable composition, homogenizing the composition, shaping the composition into shaped articles, drying and calcination, wherein the binder is selected from silicon compounds of general formulae (I) to (VI)
(Hal).sub.xSiR.sub.4-x(I)
(Hal).sub.xSi(OR.sup.1).sub.4-x(II)
(Hal).sub.xSi(NR.sup.1R.sup.2).sub.4-x(III)
RxSi(OR.sup.1)4-x(IV)
R.sub.xSi(NR.sup.1R.sup.2).sub.4-x(V)
(R.sup.1O).sub.xSi(NR.sup.1R.sup.2).sub.4-x(VI) where Hal in each occurrence is independently halogen, R in each occurrence is independently H or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, arylalkyl or aryl radical, R.sup.1 and R.sup.2 in each occurrence are each independently H or a substituted or unsubstituted alkyl, acyl, arylalkyl or aryl radical, and x is from 0 to 4.

Catalyst for decomposition of nitrous oxide

The present invention relates to a catalyst for decomposition of nitrous oxide and also to its method of preparation and use.

Exhaust gas-purifying catalyst

An exhaust gas-purifying catalyst includes a support and a catalytic metal supported thereby. The support includes a composite oxide represented by AO.xB.sub.2-C.sub.O.sub.3, wherein A represents at least one of an element having a valence of 1 and an element having a valence of 2, B represents an element having a valence of 3, C represents one or more elements selected from iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, x represents a numerical value of 1 to 6, and represents a numerical value greater than 0 and less than 2. The catalytic metal includes one or more precious metals selected from rhodium, palladium, and platinum.

Production and Use of Liquid Fuel as a Hydrogen and/or Syngas Carrier

The present invention is generally directed to the efficient production of low-carbon methanol, ethanol or mixtures of methanol and ethanol from captured CO.sub.2 and renewable H.sub.2 at a generation site. The H.sub.2 is generated from water using an electrolyzer powered by renewable electricity, or from any other means of low-carbon H.sub.2 production. An improved catalyst and process is described that efficiently converts H.sub.2 and CO.sub.2 mixture to syngas in a one-step process, and alcohols, such as methanol and ethanol, are produced from the syngas in a second step. The liquid methanol and ethanol, which are excellent H.sub.2 carriers, are transported to a production site, where another improved catalyst and process efficiently converts them to syngas. The syngas can then be used at the production site for the synthesis of low carbon fuels and chemicals, or to produce purified low carbon H.sub.2. The low carbon H.sub.2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.

ALLOY, AGGREGATE OF ALLOY NANOPARTICLES, AND CATALYST

An alloy composed of two types of elements, wherein all the standard deviation of distribution in the alloy of each element constituting the alloy are 18 atomic % or less provides a novel alloy composed of three or more types of elements and having a high solid solution uniformity.

ALKANE ACTIVATION WITH SINGLE AND BI-METALLIC CATALYSTS
20190062235 · 2019-02-28 ·

Methods, compositions, and articles of manufacture for alkane activation with single- or bi-metallic catalysts on crystalline mixed oxide supports.

ALKANE OXIDATIVE DEHYDROGENATION (ODH)

Processes and associated reaction systems for the oxidative dehydrogenation of an alkane containing 2 to 6 carbon atoms, preferably ethane or propane, more preferably ethane, are provided. In particular, a process is provided that comprises supplying a feed gas comprising the alkane and oxygen to a reactor vessel that comprises an upstream and downstream catalyst bed; contacting the feed gas with an oxidative dehydrogenation catalyst in the upstream catalyst bed, followed by contact with an oxidative dehydrogenation/oxygen removal catalyst in the downstream catalyst bed, to yield a reactor effluent comprising the alkene; and supplying an upstream coolant to an upstream shell space of the reactor vessel from an upstream coolant circuit and a downstream coolant to a downstream shell space of the reactor vessel from a downstream coolant circuit.

CATALYST FOR PRODUCING LIGHT AROMATICS WITH HEAVY AROMATICS, METHOD FOR PREPARING THE CATALYST, AND USE THEREOF

A catalyst for producing light aromatics with heavy aromatics, a method for preparing the catalyst, and a use thereof are disclosed. The catalyst comprises a carrier, component (1), and component (2), wherein component (1) comprises one metal element or more metal elements selected from a group consisting of Pt, Pd, Ir, and Rh, and component (2) comprises one metal element or more metal elements selected from a group consisting of IA group, IIA group, IIIA group, IVA group, IB group, IIB group, IIIB group, IVB group, VB group, VIB group, VIIB group, La group, and VIII group other than Pt, Pd, Ir, and Rh. The catalyst can be used for producing light aromatics with heavy aromatics, whereby heavy aromatics hydrogenation selectivity and light aromatics yield can be improved.

Method for preparing a catalyzed fabric filter and a catalyzed fabric filter

A catalyzed fabric filter substrate and a method of preparing the substrate comprising the steps of a) providing a fabric filter substrate b) providing an aqueous impregnation liquid comprising an aqueous hydrosol of one or more catalyst metal precursor compounds dispersed on nanoparticles of an oxidic metal carrier, a surfactant and a dispersing agent selected from the group of primary amines; c) impregnating the fabric filter substrate with the impregnation liquid; and d) drying and thermal activating the impregnated fabric filter substrate at a temperature below 300? C. to convert the one or more metal compounds of the catalyst precursor to their catalytically active form.

CATALYST AND HYDROCARBON CONVERSION PROCESS UTILIZING THE CATALYST

The present invention relates to a hydrocarbon conversion catalyst comprising i) a catalyst, in oxidic form, metals M1, M2, M3 and M4, wherein: M1 is selected from Si, Al, Zr, and mixtures thereof; M2 is selected from Pt, Cr, and mixtures thereof; M3 is selected from W, Mo, Re and mixtures thereof; M4 is selected from Sn, K, Y, Yb and mixtures thereof; and ii) a hydrogen scavenger selected from at least one alkali and/or alkaline earth metal derivative, preferably in metallic, hydride, salt, complex or alloy form; as well as a hydrocarbon conversion process utilizing this catalyst.