B01J23/862

PROCESSES FOR PRODUCING TRIFLUOROIODOMETHANE AND TRIFLUOROACETYL IODIDE

The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

Method of manufacturing electrically heated catalyst device, metal thin plate for electrode of electrically heated catalyst device, and electrically heated catalyst device

A method of manufacturing an electrically heated catalyst device includes preparation of a metal thin plate as a material of a metal electrode layer. The metal thin plate includes wiring portions, a base, a terminal portion, a second base, and a pseudo terminal portion. The method includes supplying current between the terminal portion and the pseudo terminal portion of the metal thin plate after fixing layers are formed; and forming the metal electrode layer by removing a portion of the metal thin plate between a smallest cross-sectional area portion and a distal end of the pseudo terminal portion through melting and cutting of the smallest cross-sectional area portion using the Joule heat generated by the supplied current. The smallest cross-sectional area portion is a part of the metal thin plate that has a smallest area in a cross section perpendicular to the extending direction of the wiring portions.

Hybrid catalysts comprising a mixed metal oxide component for production of C2 and C3 hydrocarbons

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The at least one additional metal is present in an amount from 5.0 at % to 20.0 at %.

Processes for producing trifluoroiodomethane and trifluoroacetyl iodide

The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

Process for conversion of sulfur trioxide and hydrogen production

A process for decomposition of sulfuric acid, particularly a process for catalytically decomposing sulfuric acid is used to obtain sulfur dioxide therefrom. Catalysts are used for improving the dissociation efficiency by lowering the activation energy barrier for the reaction.

METHOD FOR IMPROVING STABILITY OF CATALYST IN RECYCLING HFC-23

Disclosed is a method for improving the stability of a catalyst in recycling HFC-23. The recycling is realized by means of a fluorine-chlorine exchange reaction with HFC-23 and a halogenated hydrocarbon. The catalyst for the fluorine-chlorine exchange reaction comprises a main body catalyst and a metal oxide, wherein the metal oxide is selected from at least one metal oxide of K, Na, Fe, Co, Cu, Ni, Zn or Ti, and has an addition amount of 0.1-5 wt %. The present invention has advantages such as a good catalyst stability, a long life, and a low content of by-product CFC-12.

Method of manufacturing a honeycomb metal structure using aluminum powder

A method of manufacturing a honeycomb metal structure includes providing a substrate comprising iron (Fe) and a container containing water; coating at least a part of the substrate with a viscid material whose viscidity is increased by moisture; attaching metal powder onto the viscid material; adhering the metal powder to the substrate due to an increase in viscidity of the viscid material by evaporating a portion of the water in the container and supplying moisture to the viscid material; and generating an uneven structure made of the metal powder bonded to the substrate by performing a heat treatment on the substrate to which the metal powder is adhered. The heat treatment may include performing a first heat treatment on the substrate to generate an intermetallic layer at an interface between the substrate and the metal powder; and performing a second heat treatment to dissolve the intermetallic compound layer.

Spinel supported metal catalyst for steam reforming

The invention relates to a catalyst useful in the steam reforming of hydrocarbons and oxygenated hydrocarbons. The invention provides a method for preparing a catalyst comprising heating a spinel of formula ANi.sub.xFe.sub.(1-X)CrO.sub.4 where A is Mn or Mg and x is from 0 to 0.75 under reducing conditions at a temperature of from 800 to 1500° C., and catalysts obtainable by said method.

HYBRID CATALYSTS COMPRISING A MIXED METAL OXIDE COMPONENT FOR PRODUCTION OF C2 AND C3 HYDROCARBONS

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The at least one additional metal is present in an amount from 5.0 at % to 20.0 at %.

Process for revamping an ammonia plant

A method is described for revamping an ammonia production facility said ammonia production facility having a front end comprising one or more reformers fed with a hydrocarbon feedstock at a hydrocarbon feed stock feed rate and a high-temperature shift reactor fed with a reformed gas obtained from said one or more reformers and containing a fixed bed of iron-containing water-gas shift catalyst, said front end operating at a first steam-to-carbon ratio and a first pressure drop, said method comprising the steps of (i) replacing the iron-containing water-gas shift catalyst with a low-steam water-gas shift catalyst to form a modified front end, (ii) operating the modified front end at a second steam-to-carbon ratio and a second pressure drop, wherein the second steam-to-carbon ratio is at least 0.2 less than the first steam-to-carbon ratio and the second pressure drop is less than the first pressure drop, and (iii) increasing the hydrocarbon feed stock feed rate to said one or more reformers.