Patent classifications
B01J29/743
Diesel oxidation catalyst and exhaust system
An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.
Molecular sieve intergrowths of cha and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Nano-sized zeolite catalyst having a high silica to alumina ratio
A catalyst includes a zeolite, wherein the zeolite has: a CHA framework; a particle size less than or equal to 100 nanometers; and a silica to alumina mole ratio in the range of about 50:1 to about 150:1. The catalyst can include a metal dopant. The catalyst can be used for purifying a product by flowing a reactant across the catalyst to form the product; and condensing or separating the product. The product can be an olefin or alkenes with an increased carbon chain. The catalyst can be used for selective catalytic reduction of nitrogen oxide or a gas to liquid reaction. A method of producing the catalyst can include selecting the concentration of a crystal growth inhibitor based on the ratio of the silica precursor and an alumina precursor such that the zeolite crystals have a mean particle size less than or equal to 100 nanometers.
Process for producing LPG and BTX from mixed hydrocarbons feed
The present invention relates to a process for producing LPG and BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a first hydrocracking catalyst and contacting the thus obtained first hydrocracked product in the presence of hydrogen with a second hydrocracking catalyst to produce a second hydrocracked product stream comprising LPG and BTX.
Diesel oxidation catalyst and exhaust system
An oxidation catalyst for treating an exhaust gas from a diesel engine comprises: a first washcoat region for oxidising carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material, and wherein the first washcoat region does not comprise manganese or an oxide thereof; a second washcoat region for oxidising nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material comprising a refractory metal oxide, which is silica-alumina or alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, wherein the platinum (Pt) is disposed or supported on the second support material and the manganese (Mn) is disposed or supported on the second support material; and a substrate having an inlet end and an outlet end, and wherein the first washcoat region is a first washcoat layer and the second washcoat region is a second washcoat layer, and the second washcoat layer is disposed on the first washcoat layer; and wherein when the oxidation catalyst comprises a hydrocarbon adsorbent, which is a zeolite, then the first washcoat region further comprises the hydrocarbon adsorbent.
Use of a palladium/platinum/zeolite-based catalyst as passive nitrogen oxide adsorber for purifying exhaust gas
The invention relates to the use of a catalyst as a passive nitrogen oxide adsorber, which has a carrier substrate, a zeolite, palladium, and platinum, wherein the palladium is provided in a quantity of 0.01 to 10 wt. %, based on the sum of the weights of zeolite, platinum, and palladium and calculated as a palladium metal, and platinum in a quantity of 0.1 to 10 wt. %, based on the weight of the palladium and calculated as a platinum metal. The invention also relates to the use of said catalyst in connection with a SCR catalyst in an exhaust gas system.
Selective catalytic reduction articles and systems
Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N.sub.2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings containing copper-containing molecular sieves disposed thereon, where for example a concentration of catalytic copper in an upstream zone is lower than the concentration of catalytic copper in a downstream zone.
IRON-LOADED SMALL PORE ALUMINOSILICATE ZEOLITES AND METHOD OF MAKING METAL LOADED SMALL PORE ALUMINOSILICATE ZEOLITES
The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
Hydroisomerization catalyst
The present disclosure relates to a precursor for a catalytically active material or a catalytically active material comprising platinum, a molecular sieve and a metal oxide support, characterized in at least 80%, 90% or 95% of said platinum being dispersed on said molecular sieve and at least 80%, 90% or 95% of said platinum being dispersed in clusters having a size below 2 nm or 1 nm, as well as a method of producing such materials and process for hydroisomerization involving such materials. The disclosure has the associated benefit of such a catalytically active material being highly active and selective towards hydroisomerization.
Ultrasound-assisted method for producing an SCR catalytic converter
The present invention relates to a method for producing automobile exhaust gas catalytic converters, to the catalytic converters as such and to the use thereof. In particular, the method comprises a step which results in a smaller particle size of the catalytically active material used.