Patent classifications
B01J29/7661
Process and composition for preparation of cracking catalyst suitable for enhancing LPG
The present invention relates to a catalyst product for cracking of heavy hydrocarbon feed stocks predominantly in to light olefins and processes for preparing the catalyst. More specifically the present invention relates to a process of preparing Fluidic Catalytic Cracking (FCC) catalyst additive composition. The FCC catalyst additive composition of the present invention is a LPG selective catalyst particles comprising a medium pore zeolite bonded with clay-phosphate-silica-alumina binder. The catalyst of the present invention exhibits improved selectivity towards high value components like propylene and gasoline and suppressing low value components like dry gas and bottoms.
Hydrocarbon conversion catalyst composition
A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.
Catalyst and method for preparing low aromatic hydrocarbon liquid fuel through direct conversion of syngas
A method for preparing liquid fuel by direct conversion of syngas uses the syngas as reaction raw material and conducts a catalytic conversion reaction on a fixed bed or a moving bed. The catalyst is a composite catalyst formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide, and the component II is at least one of zeolites with one-dimensional ten-membered ring porous channels; and a weight ratio of the active ingredient in the component I to that in the component II is 0.1-20. The reaction process has high product yield and selectivity. The selectivity for liquid fuel composed of C.sub.5-C.sub.11 can reach 50-80%. The selectivity for aromatic hydrocarbon is less than 40% in C.sub.5-C.sub.11, while the selectivity for methane side product is less than 15%.
NOBLE METAL AND BASE METAL DEWAXING CATALYST
Methods, catalysts, and corresponding catalyst precursors are provided for performing dewaxing of diesel or distillate boiling range fractions. The dewaxing methods, catalysts, and/or catalyst precursors can allow for production of diesel boiling range fuels with improved cold flow properties at desirable yields. The catalysts and/or catalyst precursors can correspond to supported metal catalysts and/or catalyst precursors that include at least one noble metal, such as Pt, at least one Group 8-10 base metal, preferably a non-noble Group 8-10 base metal, such as Ni and/or Co along with a Group 6 metal, such as Mo and/or W as supported metals along. The support can include a zeolitic framework structure. The catalyst precursors can be formed, for example, by impregnating a support including a zeolitic framework structure with impregnation solution(s) that also includes a dispersion agent.
Catalyst compositions and use in heavy aromatics conversion processes
Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C.sub.8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a first zeolite having a constraint index of 3 to 12, a second zeolite comprising a mordenite zeolite synthesized from TEA or MTEA, at least one first metal of Group 10 of the IUPAC Periodic Table, and at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m.sup.2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
AN ADDITIVE AND A CATALYST COMPOSITION COMPRISING THE ADDITIVE FOR FCC PROCESS
The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.
HYDROISOMERIZATION CATALYSTS
A hydroisomerization catalyst comprising a molecular sieve belonging to the ZSM-48 family of zeolites; an inorganic oxide support; one or more first modifiers selected from Groups 8 to 10; and one or more second modifiers selected from the group consisting of calcium (Ca), chromium (Cr), magnesium (Mg), lanthanum (La), barium (Ba), praseodymium (Pr), strontium (Sr), potassium (K) and neodymium (Nd). The molecular sieve comprises: a silicon oxide to aluminum oxide mole ratio of about 40 to about 220; at least about 70% polytype 6 of the total ZSM-48-type material present in the product; and an additional EUO-type molecular sieve phase in an amount of between about 0 and about 7.0 percent by weight of the total product. The molecular sieve has a morphology characterized as polycrystalline aggregates comprising crystallites collectively having an average aspect ratio of between about 1 and about 8.
AN ADDITIVE AND A CATALYST COMPOSITION COMPRISING THE ADDITIVE FOR FCC PROCESS
The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.
Hydrocarbon dehydrocyclization
The invention relates to the production of aromatic hydrocarbon by the conversion of a feed comprising C.sub.2+ non-aromatic hydrocarbon, e.g., natural gas. The invention is particularly useful in converting natural gas to liquid-phase aromatic hydrocarbon, which can be more easily transported away from remote natural gas production facilities. The conversion is carried out in the presence of a dehydrocyclization catalyst comprising dehydrogenation and molecular sieve components. The dehydrocyclization catalyst has an average residence time of 90 seconds or less.
Catalyst compositions and use in heavy aromatics conversion processes
Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C.sub.8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m.sup.2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.