The disclosure deals with system/apparatus and corresponding and/or associated method for an open plasma reactor assembly provided to study pulsed reactive species produced in a dielectric barrier discharge (DBD) in He—H.sub.2O and He—H.sub.2O—O.sub.2 mixture in atmospheric conditions using photo fragmentation laser-induced fluorescence (PFLIF). The objective is to detect and quantify hydroxyl radicals and hydrogen peroxide produced in the DBD. An OH laser-induced fluorescence (LIF) signal is acquired from LIF (using 282 nm laser) whereas LIF from OH generated from H.sub.2O.sub.2 is measured by from the PFLIF signal (using 213 nm+ 282 nm lasers). A known concentration of H.sub.2O.sub.2 in He serves to calibrate for H.sub.2O.sub.2 while the OH is calibrated with a chemical model. For both gas mixtures, there is both OH and H.sub.2O.sub.2 production in the discharge, while the H.sub.2O.sub.2 concentration was noticeably increased for the added O.sub.2 case.

Disclosed herein is a method and device for production of a new long-term storage-stable allotropic modification of oxygen, tetraoxygen O.sub.4, using a combination of known chemical reactions into one technological sequence, including chemical interaction of negative and positive oxidation state oxygen compounds. The method involves production of dioxygen difluoride by oxidation of molecular oxygen with fluorine, followed by the reaction of dioxygen difluoride with alkali metal peroxide, forming tetraoxygen O.sub.4. Tetraoxygen is stable in its liquid state up to a temperature of +40° C. and can be used for the oxidation of rocket fuel, long-term compact storage of oxygen, and many other purposes.

Nanoparticles are synthesized by suctioning a liquid under a negative pressure with a negative-pressure suction force caused by the rotation of a rotary blade, causing cavitation by stirring the suctioned liquid by the rotary blade, generating plasma generated by a plasma generation mechanism in air bubbles generated in the liquid, and in that case, consuming an electrode containing elements constituting the nanoparticles to be synthesized.

A method of substituting an azide for hydrogen bonded to a tertiary carbon atom is provided. A liquid mixture in an oxygen-free environment has spaced-apart carbon and platinum electrodes disposed therein. The liquid mixture includes a solvent, ammonium azide, and a base material having at least one tertiary carbon atom with hydrogen bonded thereto. An electric current is applied to the electrodes where the liquid mixture undergoes a reaction. The electrochemically-induced reaction yields a liquid product and a solid product. The liquid product includes the solvent and a constituent having at least one tertiary carbon atom with an azide bonded thereto.

The present invention relates to a dielectric barrier discharge (DBD) plasma reactor comprising a catalyst bed for CO.sub.X hydrogenation in a discharge region; and a method to produce light hydrocarbons from a CO.sub.X-containing gas mixture in the DBD plasma reactor. In the DBD plasma reactor for a CO.sub.X hydrogenation reaction, the catalyst for CO.sub.X hydrogenation comprises a catalytically active component on a mesoporous support that is a dielectric. When the DBD plasma reactor for a CO.sub.X hydrogenation reaction according to the present invention is used, it is possible to convert by-product gases or waste gases into higher-value-added chemical products without additional heat supply from the outside.

Method and apparatus for synthesizing compounds by a low temperature plasma dual-electric field aided gas phase reaction are provided. The method utilizes two different electrode corona discharge fields in a plasma aided reactor to form a plasma dual-electric field, using electric energy to convert gas into gas molecules, atoms, ions and/or free radicals, and then reforming and reducing to obtain organic compounds such as aliphatic hydrocarbons, higher carbon ethers, higher carbon alcohols, higher carbon esters, lower carbon alcohols, and the like; also inorganic compounds such as N.sub.2, O.sub.2, H.sub.2SO.sub.4, NH.sub.3, and the like. The apparatus includes a reactor having a plasma region of two different corona discharge fields, wherein an alternating current corona discharge field or a positive corona discharge field is set in the first electric field, and a negative corona discharge field is set in the second electric field.

In order to attain an efficient decomposition process by water plasma, a decomposition processor includes a water plasma generator which is configured to inject water plasma, from the injection port, by arc discharge generated between negative and positive electrodes; and a supply device configured to supply a decomposition target object to a water plasma jet stream injected from the water plasma generator, wherein the decomposition target object is decomposed by the water plasma. The supply device has a nozzle for providing the decomposition target object from a tip, and the negative electrode, the injection port, the positive electrode and the nozzle are arranged in that order along the center axis line of the injection port. The tip of the nozzle is placed inside of the water plasma jet stream.

In order to stabilize injection of water plasma, a vortex water flow generator forms a vortex water flow for passing arc discharge. The vortex water flow generator includes a cylindrical portion configured to form a vortex water flow along an inner circumference, a first middle partition and a second middle partition protruding from the inner circumference of the cylindrical portion. The first middle partition and the second middle partition respectively have an opening to include a center axis line position of the cylindrical portion. An opening of the second middle partition on the side of the positive electrode is larger than an opening of the first middle partition on the side of the negative electrode.

Methods and apparatus are disclosed for triggering an exothermic reaction under a high hydrogen loading rate. It is generally understood that a high hydrogen loading ratio is an important factor. The present application teaches that a high hydrogen loading rate, that is, achieving a high hydrogen loading ratio in a short period of time, is another important factor in determining whether excess heat can be observed in an exothermic reaction. The present application discloses methods and apparatus for achieving a high hydrogen loading rate in order to trigger an exothermic reaction.

A vortex water generator forms a vortex water flow for passing arc discharge. The vortex water flow generator includes a cylindrical portion configured to form a vortex water flow along an inner circumference; first middle partition and second middle partition protruding from the inner circumference of the cylindrical portion, a rear partition formed in a rear end side of the cylindrical portion, and a front partition provided in a front end side of the cylindrical portion. Each partition has an opening to include a center axis line position of the cylindrical portion. Each opening has a different opening shape in size. The middle partition and the front partition have negative electrode side surfaces formed by tapered surfaces receding from the negative electrode as close to the center axis line. Arc-shaped beveled portions are formed between the tapered surfaces and inner circumferential surfaces of the openings.