A reactor having a shell comprising one or more reactor tubes located within the shell, said reactor tube or tubes comprising a plurality of catalyst receptacles containing catalyst; means for providing a heat transfer fluid to the reactor shell such that the heat transfer fluid contacts the tube or tubes; an inlet for providing reactants to the reactor tubes; and an outlet for recovering products from the reactor tubes; wherein the plurality of catalyst receptacles containing catalyst within a tube comprises catalyst receptacles containing catalyst of at least two configurations.

A device for the through-flow of a fluid may include a fluid inlet and a fluid outlet. A porous structure with interconnected pores is arranged between the fluid inlet and the fluid outlet, and the fluid inlet and the fluid outlet define an overall flow direction. The porous structure is coupled to a wall to provide for heat conduction between the porous structure and the wall. The porous structure has a porosity gradient along a first direction, which is cross to the overall flow direction. The porosity gradient develops along the first direction between a first porosity at a first location proximal to the wall and a second porosity larger than the first porosity at a second location remote from the wall. The difference between the second porosity and the first porosity may be at least 4%.

Briefly, in one aspect, a catalytic assembly described herein comprises a module comprising at least one layer of structural catalyst bodies having an inlet face for receiving a gas stream. A diffuser assembly is arranged a distance of greater than 50 mm from the inlet face, the diffuser assembly including at least one diffuser element comprising a plurality of apertures, wherein a ratio of aperture length (L) in the gas stream flow direction to aperture hydraulic diameter (D.sub.a) is less than 1.

A reactor having a shell comprising: one or more reactor tubes located within the shell, said reactor tube or tubes comprising a plurality of catalyst receptacles containing catalyst; means for providing a heat transfer fluid to the reactor shell such that the heat transfer fluid contacts the tube or tubes; an inlet for providing reactants to the reactor tubes; and an outlet for recovering products from the reactor tubes; wherein the plurality of catalyst receptacles containing catalyst within a tube comprises catalyst receptacles containing catalyst of at least two configurations.

One aspect of the present disclosure provides a system for producing 1,3-butadiene, which includes: a first supply unit, by which a first feed including a butene raw material, oxygen and steam is supplied; a second supply unit, by which a second feed including a butene raw material and oxygen is supplied; and a reaction unit, which includes a catalyst fixed bed and in which an oxidative dehydrogenation reaction takes place, wherein the first supply unit is connected to a front end of the reaction unit, and the second supply unit is connected to an intermediate end of the reaction unit.

A device for the through-flow of a fluid may include a fluid inlet and a fluid outlet. A porous structure with interconnected pores is arranged between the fluid inlet and the fluid outlet, and the fluid inlet and the fluid outlet define an overall flow direction. The porous structure is coupled to a wall to provide for heat conduction between the porous structure and the wall. The porous structure has a porosity gradient along a first direction, which is cross to the overall flow direction. The porosity gradient develops along the first direction between a first porosity at a first location proximal to the wall and a second porosity larger than the first porosity at a second location remote from the wall. The difference between the second porosity and the first porosity may be at least 4%.

A catalytic reactor includes: a reaction-side flow channel in which a reaction fluid flows; a structured catalyst removably located in the reaction-side flow channel; and a protrusion formed in the structured catalyst or an inner surface of the reaction-side flow channel, having a height forming a clearance between the structured catalyst and the inner surface of the reaction-side flow channel.

An internal recycle reactor for catalytic inerting has a monolithic body having a motive fluid duct, a suction chamber, a mixing region, a reactor section, an outlet, and a recycle passage. The suction chamber includes a suction chamber inlet. The mixing region is configured to receive gaseous fluids from the motive fluid duct and the suction chamber inlet to produce a gaseous mixture. The reactor section includes a catalyst and is configured to receive the gaseous mixture from the mixing region. The outlet is configured to deliver an exhaust gas from the reactor section and the recycle passage is configured to deliver a portion of the exhaust gas to the suction chamber inlet.

An internal recycle reactor for catalytic inerting has a monolithic body having a motive fluid duct, a suction chamber, a mixing region, a reactor section, an outlet, and a recycle passage. The suction chamber includes a suction chamber inlet. The mixing region is configured to receive gaseous fluids from the motive fluid duct and the suction chamber inlet to produce a gaseous mixture. The reactor section includes a catalyst and is configured to receive the gaseous mixture from the mixing region. The outlet is configured to deliver an exhaust gas from the reactor section and the recycle passage is configured to deliver a portion of the exhaust gas to the suction chamber inlet.

Briefly, in one aspect, a catalytic assembly described herein comprises a module comprising at least one layer of structural catalyst bodies having an inlet face for receiving a gas stream. A diffuser assembly is arranged a distance of greater than 50 mm from the inlet face, the diffuser assembly including at least one diffuser element comprising a plurality of apertures, wherein a ratio of aperture length (L) in the gas stream flow direction to aperture hydraulic diameter (D.sub.a) is less than 1.