The invention relates to a method of producing an article selected from the group consisting of casting mold, core, feeder and molding compound for production of part of a casting mold, core or feeder, comprising the following steps: (S1) producing or providing in the foundry: a first component (A), comprising a first binder component (b1) of a binder system and an amount of a first mold base material and, spatially separated therefrom, a second component (B), comprising a second binder component (b2) of the binder system and an amount of a second mold base material wherein the first binder component (b1) and the second binder component (b2) are suitable for chemical reaction with one another and for curing of a mixture of the first component (A) and the second component (B), (S2) mixing by contacting the first component (A) and the second component (B) in a particular mass ratio, so as to result in a self-curing molding compound.

Described is a phenolic resin composition for use in the polyurethane cold-box and/or no-bake process. The phenolic resin composition comprises an ortho-condensed phenolic resol having etherified and/or free methylol groups in a total amount of 40 to 60% by weight based on the total mass of the phenolic resin composition, free formaldehyde in an amount of less than 0.1% by weight based on the total weight of the phenolic resin composition, one or more reaction products of formaldehyde with one or more CH-acidic reactant compounds, other constituents in a total amount of at least 38% by weight, wherein the amount of water in the phenolic resin composition is not more than 1.0% by weight in each case based on the total mass of the phenolic resin composition. Also described is a two-component binder system for use in the polyurethane cold-box and/or no-bake process, a use of a CH-acidic compound as a formaldehyde scavenger for producing a phenolic resin composition for use in the polyurethane cold-box and/or no-bake process, a process for producing a phenolic resin composition, a process for producing a two-component binder system and a process for producing a feeder, a foundry mold or a foundry core from a molding material mixture and finally corresponding feeders, foundry molds and foundry cores.

A method for additive manufacturing is provided, including: mixing a hardener with a sand material, so that the hardener is evenly coated on a surface of the sand material, and then spraying a binder through a nozzle, reacting the binder sprayed through the nozzle with the surface of the sand material evenly coated with the hardener to harden a sand mold. Therefore, the problem of nozzle clogging may be overcome, and a solid with a particle size of less than 0.6 m may be obtained by the additive manufacturing. In addition, the hardening speed can be adjusted according to the size of the sand mold. Compared with a general sand mold product, the hardening speed may be increased and the storage life of the binder may be prolonged when the sand mold has a large size.

A structure for manufacturing castings, containing an inorganic fiber, a layered clay mineral, and an inorganic particle other than the layered clay mineral and having an organic content of 5 mass % or lower or having a mass loss of 5 mass % or lower when heated at 1000 C. for 30 minutes. The inorganic particle preferably contains one or more selected from obsidian, graphite, and mullite. The inorganic fiber preferably contains carbon fiber. The inorganic fiber preferably has an average length of 0.5 to 15 mm. The layered clay mineral preferably contains one or more selected from bentonite and montmorillonite.

The object of the invention is a component system for producing a binder for metal casting on the basis of phenolic resins of the benzyl ether type and isocyanates containing non-polar solvents.

A foundry mix includes a major amount of a foundry aggregate and an effective binding amount of a binder system. The binder system cures in the presence of sulfur dioxide and a free radical initiator. The binder system may include (1) 10 to 70 parts by weight of an epoxy novolac resin; (2) 0.5 to 10 parts by weight of resorcinol; (3) 20 to 70 parts by weight of a monomeric or polymeric acrylate; and (4) an effective amount of a free radical initiator. Notably, (1), (2), (3) and (4) are separate components or mixed with another of said components, provided (4) is not mixed with (3), where said parts by weight are based upon 100 parts of the binder system.

The present invention is a granular material that can be well recoated regardless of the type of the granular material, and enables a refractory aggregate in an unprinted portion to be used without any regeneration process, in the manufacture of a three-dimensional laminated and shaped mold. This granular material is a granular material for use in three-dimensional laminated mold shaping, and obtained by adding a material that causes a hydration reaction having a moisture absorbing function and generates a catalytic effect to a coating material mixed with or coated with an acid as a catalyst which activates and hardens an organic binder for binding the granular material.

A foundry mix includes a major amount of a foundry aggregate and an effective binding amount of a binder system. The binder system cures in the presence of sulfur dioxide and a free radical initiator. The binder system may include (1) 10 to 70 parts by weight of an epoxy novolac resin; (2) 0.5 to 10 parts by weight of resorcinol; (3) 20 to 70 parts by weight of a monomeric or polymeric acrylate; and (4) an effective amount of a free radical initiator. Notably, (1), (2), (3) and (4) are separate components or mixed with another of said components, provided (4) is not mixed with (3), where said parts by weight are based upon 100 parts of the binder system.

The subject matter of the invention is mold material mixtures for producing molds or cores for metal casting, consisting of at least one refractory base mold material, a binder and an additive based on factice. The invention also relates to a component system, a method for producing molds and cores using the mold material mixtures or the component system respectively, and to molds and cores produced by said method.

Provided are a binder in the producing of a casting sand mold according to an ink jet type lamination shaping method in which a binder is printed with respect to sand, a method for producing the binder, and a method for producing a casting sand mold using the binder. Specifically, provided are a binder useful for a casting sand mold of an ink jet type, containing: a resol-type phenolic resin that is obtained by reacting aldehydes (A1), phenols (P1), and a compound (N) having two or more phenolic hydroxyl groups in one molecule or by reacting the aldehydes (A1) and a novolac-type phenolic resin (N1), in the presence of an alkali catalyst, and has a dispersion degree (Mw/Mn) of 1.0 to 3.5 and a phenolic monomer residue of 5% or less, a method for producing the binder, and a method for producing a casting sand mold.