An electric current based on electric charge produced on the piezoelectric body changes by going through a first path, a second path, a third path, and a fourth path in this order. On the first path, the electric current becomes larger as the voltage becomes higher. On the second path, the electric current becomes smaller as the voltage becomes higher. On the third path, the electric current becomes larger as the voltage becomes higher. On the fourth path, the electric current becomes smaller as the voltage becomes higher.

There is provided a liquid discharge head, including: a nozzle member formed having nozzle rows extending in a first direction, the nozzle rows being arranged in a second direction; driving elements; a first channel member disposed at one side of the nozzle member in a third direction; a second channel member disposed at the one side of the first channel member in the third direction; and a third channel member disposed at the one side of the second channel member in the third direction.

A piezoelectric element including a piezoelectric layer having a perovskite structure including lead, zirconium, and titanium, and an electrode provided on the piezoelectric layer is provided. In the piezoelectric layer, in a range of 50 nm or smaller from an interface between the piezoelectric layer and the electrode in a thickness direction, a ratio c/a of a lattice spacing a in a direction perpendicular to the thickness direction and a lattice spacing c in the thickness direction satisfies 0.986≤c/a≤1.014.

There is provided a liquid discharge head including a piezoelectric body having a plurality of individual electrodes and a first common electrode, and a plurality of conductor layers. The plurality of individual electrodes have first to fourth individual electrode arrays, and the first common electrode has first and second extending portions, a plurality of first projecting portions, and a plurality of second projecting portions. Each of the first projecting portions overlaps partially with one of the plurality of individual electrodes forming the second individual electrode array along the stacking direction, and each of the second projecting portions overlaps partially with one of the plurality of individual electrodes forming the third individual electrode array along the stacking direction. The plurality of conductor layers are formed between the plurality of first projecting portions and the plurality of second projecting portions, without contacting the first common electrode and without contacting each other.

A liquid discharge head includes a common flow channel extending along a first direction, and individual flow channels arranged along the first direction. Each individual flow channel includes a first pressure chamber and a second pressure chamber arranged along the first direction, each of which communicates with the common flow channel, a nozzle located away from the first and second pressure chambers in a second direction orthogonal to the first direction, and a connection flow channel connecting the first pressure chamber, the second pressure chamber, and the nozzle with each other. One end of the connection flow channel in the second direction communicates with the first pressure chamber and the second pressure chamber, and the other end thereof in the second direction communicates with the nozzle. The connection flow channel extends along the second direction from the one end to the other end thereof in the second direction.

A liquid discharge apparatus includes a nozzle plate with nozzles and actuators and a drive controller. First and second nozzles are directly adjacent to each other in a first direction. First and third nozzles are directly adjacent to each other in a second direction. The drive controller is configured to apply a drive signal to first, second, and third actuators corresponding to the first, second, and third nozzles, respectively, during a drive cycle. A difference between a first timing at which the drive signal is applied to the first actuator and a second timing at which the drive signal is applied to the second actuator and a difference between the first timing and a third timing at which the drive signal is applied to the third actuator is an odd number multiple of a half of an inherent vibration cycle of the liquid discharge apparatus.

A piezoelectric thin film 3 contains a metal oxide, the metal oxide contains bismuth, potassium, titanium, iron and element M, the element M is at least one of magnesium and nickel, at least a part of the metal oxide is a crystal having a perovskite structure, and a (001) plane, a (110) plane or a (111) plane of the crystal is oriented in a normal direction dn of the surface of the piezoelectric thin film 3.

A piezoelectric element includes: a first electrode and a second electrode; and a piezoelectric layer provided between the first electrode and the second electrode and having a perovskite structure, in which 0<P1/P2≤0.5 and 0<P1 where, when a positive predetermined voltage is applied to the piezoelectric layer, then a voltage applied to the piezoelectric layer is set to 0 V for 0.1 seconds, and then a triangular wave voltage waveform having a maximum voltage of the predetermined voltage is applied to the piezoelectric layer to obtain a hysteresis curve drawn counterclockwise, P1 is a residual polarization amount at a start point of the hysteresis curve and P2 is a residual polarization amount at an end point of the hysteresis curve.

A liquid discharging head includes a nozzle configured to discharge liquid, a pressure chamber communicated with the nozzle, and an individual channel communicated with the pressure chamber through a narrow part. The liquid discharging head also includes a common channel communicated with the individual channel, an energy generation element configured to generate energy, and a diaphragm configured to convey the energy to the pressure chamber. A metal oxide film is formed at inner walls of the nozzle, the pressure chamber, the narrow part, the diaphragm, and the individual channel, and a hydroxyl group has come out from the metal oxide film.

An actuator includes a substrate, a diaphragm on the substrate, a lower electrode on the diaphragm, a piezoelectric body on the lower electrode, and an upper electrode on the piezoelectric body. A ratio of lead (Pb) and zirconium (Zr) in atomic percent (atm %) present at a grain boundary in the piezoelectric body satisfies a relation of Pb/Zr>1.7.