The objective of the present invention is to provide a thermosensitive recording medium excellent in color developing property, especially excellent in bar code readability, under severe environment. Provided is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains a specific sulfone compound and a specific urea-urethane-based compound in a specific ratio.

A recording material and a recording sheet having better color-developing performance, storage stability, etc. A recording material which contains (A) at least one color former, (B) at least one compound selected from the group including compounds represented by the following formula (I), and (C) at least one compound selected from the group including compounds represented by the following formula (II)

(wherein R.sup.1 to R.sup.3 each represent a halogen atom, a nitro group, a C.sub.1 to C.sub.6 alkyl group, a C.sub.1 to C.sub.6 alkoxy group, a C.sub.2 to C.sub.6 alkenyl group or a C.sub.1 to C.sub.6 haloalkyl group, n1 and n3 each independently represent any integer of 0 to 5, n2 represents any integer of 0 to 4, and X represents SO.sub.2O or OSO.sub.2).

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The purpose of the present disclosure is to improve the sensitivity of 4,4-dihydroxydiphenylsulfone, which is a developer, in a heat-sensitive recording material. The present disclosure provides a heat-sensitive recording material that uses at least one selected from 1,2-bis(phenoxy)ethane, 1,2-bis(3-methylphenoxy)ethane, benzyloxynaphthalene, and oxalic acid di-p-methylbenzyl ester as a sensitizer for 4,4-dihydroxydiphenylsulfone, and further includes benzoin as a sensitization aid.

An offset printing process for manufacturing a laser markable packaging uses a laser markable offset ink and a laser markable varnish or a laser markable dispersion-lacquer in the process to provide a laser markable image or area on the packaging. The laser markable offset ink, offset varnish or offset dispersion-lacquer including a leuco dye and a metal free optothermal converting agent may be used in the offset printing process.

This heat-sensitive recording material is configured to contain, as a color-developing compound, at least one compound represented by one of formulas (1)-(3): ##STR00001##

Provided is a thermosensitive recording medium including a support, and a thermosensitive recording layer provided over at least one surface of the support and containing a leuco dye and a developer, wherein the developer includes 4-hydroxy-4-benzyloxydiphenylsulfone and a diphenylsulfone compound represented by general formula (1), and wherein a content of the diphenylsulfone compound represented by general formula (1) is less than 3.0 parts by mass relative to 1.0 part by mass of the 4-hydroxy-4-benzyloxydiphenylsulfone.

The invention relates to a self-adhesive, heat-sensitive recording material, comprising a carrier substrate, a heat-sensitive, color-forming layer that is applied on one side of the carrier substrate and contains at least a non-phenolic color developer in and at least one color former, a siliconized layer on the upper side of the heat-sensitive, color-forming layer that is applied on the carrier substrate, as well as an adhesive layer on the side of the carrier substrate facing away from the heat-sensitive, color-forming layer.

An object of the invention is to provide a recording material and recording sheet having excellent color-developing performance, storage stability, etc. A recording material having good color-developing performance and storage stability may be obtained by using a specific compound having a benzhydrol skeleton as an additive in a recording material employing color development through a reaction between a color former and a color-developing agent.

A heat-sensitive recording material suitable for offset printing, having a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed at least on one of the two sides of the web-shaped substrate having at least one dye precursor and at least one (color) developer reactive with the dye precursor. The heat-sensitive recording layer has particles including an organic surface whose extent in the direction of the thickness of web-shaped substrate and heat-sensitive recording layer is greater than the thickness of the heat-sensitive recording layer.

The invention relates to a heat-sensitive recording material, comprising a carrier substrate and at least one heat-sensitive thermal reaction layer, which is applied to at least one side of the carrier substrate and contains at least one fluoran color former, at least one color developer, at least one melting aid, and optionally typical additives, such as lubricants, stabilizers (anti-aging agents), and/or pigments, characterized in that the color developer is dodecyl gallate and the melting aid is an ethylene bis fatty acid amide of formula (I), wherein R.sub.1 and R.sub.2 are CH.sub.3(CH.sub.2).sub.mCH.sub.2 with m=13 and/or 15. The invention further relates to a method for producing said recording material.

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