Patent classifications
B01J23/8876
Ferrite-based catalyst, preparation method therefor, and method for preparing butadiene using same
The present specification provides a ferrite catalyst, a method for preparing the same and a method for preparing butadiene using the same.
Catalyst, Method for Producing Catalyst, and Method for Producing alpha,beta-Unsaturated Aldehydes, alpha,beta-Unsaturated Carboxylic Acids and alpha,beta-Unsaturated Carboxylic Acid Esters
An object of the present invention is to provide a catalyst with high selectivity for an ,-unsaturated aldehyde, an ,-unsaturated carboxylic acid, and the like. Problems are solved by a catalyst containing at least molybdenum and bismuth and having a B/A of 1.3 to 5 when a ratio of the amount of bismuth atoms to the amount of molybdenum atoms, calculated from ICP (inductively coupled plasma) atomic emission spectrometry is A, and a ratio of a peak area of bismuth atoms to a peak area of molybdenum atoms, measured by X-ray photoelectron spectrometry is B.
Multimetal oxide compositions comprising Mo, Bi, Fe and Cu
Multimetal oxide composition comprising Mo, Bi, Fe, Cu and one or more than one of the elements Co and Ni and use thereof.
Composite material containing a bismuth-molybdenum-nickel mixed oxide or a bismuth-molybdenum-cobalt mixed oxide and SiO.SUB.2
The present invention relates to a process for producing a composite material and also the composite material itself. The composite material contains a bismuth-molybdenum-nickel mixed oxide or a bismuth-molybdenum-cobalt mixed oxide and a specific SiO2 as pore former. The present invention also relates to the use of the composite material according to the invention for producing a washcoat suspension and also a process for producing a coated catalyst using the composite material according to the invention. Furthermore, the present invention also relates to a coated catalyst which has a catalytically active shell comprising the composite material according to the invention on a support body. The coated catalyst according to the invention is used for preparing [alpha],[beta]-unsaturated aldehydes from olefins.
Catalyst, Method for Producing Catalyst, and Method for Producing alpha,beta-Unsaturated Aldehyde, alpha,beta-Unsaturated Carboxylic Acid and alpha,beta-Unsaturated Carboxylic Acid Ester
An object of the present invention is to provide a catalyst with high yields of target products such as an ,-unsaturated aldehyde and an ,-unsaturated carboxylic acid. Problems are solved by a catalyst containing at least molybdenum and having a COD (chemical oxygen demand) of the catalyst of greater than 300 ppm and less than 11,000 ppm.
Method for producing butadiene
A method for producing butadiene comprises a step of obtaining a product gas containing butadiene, by feeding a raw-material gas containing straight-chain butene and an oxygen-containing gas containing molecular oxygen to a reactor and performing oxidative dehydrogenation reaction in the presence of a catalyst, wherein the catalyst comprises a composite oxide containing molybdenum and bismuth, and the concentration of hydrocarbons having 5 or more carbon atoms in the raw-material gas is 0.05 mol % to 7.0 mol %.
Process for producing unsaturated nitrile
A process for producing unsaturated nitrile, using a fluidized bed reactor having an internal space having a catalyst capable of being fluidized therein, a feed opening to feed a starting material gas comprising hydrocarbon to the internal space, and a discharge port to discharge a reaction product gas from the internal space, the process comprising a reaction step of subjecting the hydrocarbon to a vapor phase catalytic ammoxidation reaction in the presence of the catalyst in the internal space to produce the corresponding unsaturated nitrile, wherein when in the internal space, a space where an existing amount of the catalyst per unit volume is 150 kg/m.sup.3 or more is defined as a dense zone and a space where an existing amount of the catalyst per unit volume is less than 150 kg/m.sup.3 is defined as a sparse zone in the reaction step, a gas residence time in the sparse zone is 5 to 50 sec.
Ammoxidation catalyst with selective co-product HCN production
A catalytic composition and process useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, hydrogen cyanide and acetonitrile and mixtures thereof, wherein the catalyst exhibiting increased selectivity to hydrogen cyanide compared to prior art catalysts.
FUNCTIONAL STRUCTURAL BODY AND METHOD FOR MAKING FUNCTIONAL STRUCTURAL BODY
Provide is a functional structural body that can suppress aggregation of metal oxide nanoparticles and prevent functional loss of metal oxide nanoparticles, and thus exhibit a stable function over a long period of time. A functional structural body (1) includes: a skeletal body (10) of a porous structure composed of a zeolite-type compound; and at least one type of metal oxide nanoparticles (20) containing a perovskite-type oxide present in the skeletal body (10), the skeletal body (10) having channels (11) that connect with each other, and the metal oxide nanoparticles (20) being present at least in the channels (11) of the skeletal body (10).
CATALYST
A catalyst for producing unsaturated aldehyde and unsaturated carboxylic acid, wherein the cumulative pore volume (A) of pores having a pore diameter of 1 m or more and 100 m or less, in the catalyst, is 0.12 ml/g or more and 0.19 ml/g or less, and the ratio (A/B) of the cumulative pore volume (A) to the cumulative pore volume (B) of pores having a pore diameter of 1 m or more and 100 m or less, in a pulverized product not passing through a Tyler 6 mesh, in a pulverized product obtained by pulverization of the catalyst under a particular condition is 0.30 or more and 0.87 or less.