A catalytic composition and process useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, hydrogen cyanide and acetonitrile and mixtures thereof, wherein the catalyst exhibiting increased selectivity to hydrogen cyanide compared to prior art catalysts.

The invention relates to an oxidation catalyst comprising at least one inorganic, oxidic or ceramic, shaped support body having a BET surface area of less than 0.5 m.sup.2/g, based on the support, which is at least partly coated with a catalytically active multielement oxide, the catalyst being precious metal-free and the shaped support body having the form of a saddle whose saddle surface is curved oppositely in the two principal directions, to a process for producing it, to its use in various catalytic gas phase oxidations, and to corresponding processes for catalytic gas phase oxidation.

The present invention relates to a high-performance polyoxometalate catalyst and a method of preparing the same. More particularly, the present invention provides a high-performance polyoxometalate catalyst, the activity and selectivity of which may be improved by controlling the content of vanadium and the like and which has superior reproducibility and may unsaturated carboxylic acid from unsaturated aldehyde in a high yield for a long time, a method of preparing the same, and the like.

A method for deoxygenating renewable oils comprised of natural oils or greases or derivatives thereof containing triglycerides or free fatty acids includes the steps of: providing a catalyst comprising a support predominantly comprised of alumina with metal compounds provided on the support based on Mo and at least one selected from the group consisting of Ni and Co, and at least one selected from the group consisting of Cu and Cr, and contacting the renewable oils with the catalyst under conditions sufficient to deoxygenate the renewable oils.

A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprises a complex of metal oxides comprising bismuth, molybdenum, iron, cerium, and at least one of samarium, praseodymium and neodymium.

A catalyst for producing butadiene using n-butene as a raw material, a process for producing the same and a process for producing butadiene using the catalyst are provided, and specifically, a catalyst for producing butadiene by gas-phase contact oxidative dehydrogenation of n-butene, which is capable of stably producing butadiene in a high yield from the beginning of the reaction, a process for producing the same and a process for producing butadiene, in which the catalyst is a shaped catalyst containing a complex metal oxide having molybdenum as an essential ingredient, wherein the pore volume of macropores is 80% or more, more preferably 90% or more, based on the total pore volume, are provided.

A micro-spherical iron-based catalyst and a preparation method thereof are disclosed. The catalyst contains a potassium promoter, and at least one transitional metal promoter M which is one or more kinds of metals selected from Cr, Cu, Mn and Zn. It also contains a structure promoter S, which is SiO.sub.2 and/or Al.sub.2O.sub.3, wherein both of SiO.sub.2 and Al.sub.2O.sub.3 are modified by MoO.sub.3, TiO.sub.2 and/or ZrO.sub.2. The weight ratio of components is Fe:M:K:S=100:3-50:1-8:3-50, in which the metal components are calculated based on metal elements, the structure promoter is calculated based on oxides. The catalyst is prepared by co-precipitation method.

Catalytic compositions are provided that are effective for providing increased acrylonitrile product without a significant decrease in hydrogen cyanide and/or acetonitrile production and provide an overall increase in production of acrylonitrile, hydrogen cyanide and acetonitrile. The catalytic compositions include a complex of metal oxides and include at least about 15% m-phase plus t-phase by weight and have a weight ratio of m-phase to m-phase plus t-phase of 0.45 or greater.

A catalyst support for manufacturing a mixture of alcohols from synthesis gas comprises a combination of nickel, molybdenum, at least one metal selected from the group consisting of palladium, ruthenium, chromium, gold, zirconium, and aluminum, and at least one of an alkali metal or alkaline earth series metal as a promoter. The catalyst may be used in a process for converting synthesis gas wherein the primary product is a mixture of ethanol (EtOH), propanol (PrOH), and butanol (BuOH), optionally in conjunction with higher alcohols.

The invention relates to catalyst compositions comprising a complex of catalytic oxides comprising molybdenum, bismuth, cerium, iron, chromium, at least one element of group A, at least one element of group B, and optionally at least one element of group C wherein the relative ratios of these elements are represented by Formula (1): Mo.sub.12Bi.sub.aCe.sub.bFe.sub.cCr.sub.dA.sub.eB.sub.fC.sub.gO.sub.x. The invention also relates to a process for the ammoxidation of an olefin comprising reacting in the vapor phase at an elevated temperature and pressure the olefin with a molecular oxygen containing gas and ammonia in the presence of the catalyst composition.