Patent classifications
B01J31/2234
Catalyst composition for hydroformylation and method of preparing aldehyde using the same
The present invention relates to a catalyst composition for hydroformylation and a method of preparing an aldehyde using the same. More specifically, the present invention provides a catalyst composition for hydroformylation including a specific phosphite-based ligand and a transition metal compound in a specific amount range, thereby being capable of greatly lowering a use amount of an expensive transition metal compound and exhibiting excellent catalyst activity or stability. In addition, by using the catalyst composition in hydroformylation, excellent reaction efficiency may be provided and iso-aldehyde may be generated in high yield.
Branched Alcohols
A process for producing isomerized olefins, branched aldehydes and branched alcohols through isomerization, hydroformylation and hydrogenation.
METHODS FOR PREPARING SUBSTITUTED CHROMANONE DERIVATIVES
The present disclosure relates to a method for preparing a compound of formula (I).
##STR00001##
In the compound of formula (I), n may be 0 to 5 and each of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 may be independently selected from the group consisting of H, —O-Alkyl, halo, alkyl, —CN, or —NO.sub.3.
METAL-OXO COMPLEX AND METHOD FOR PRODUCTION THEREOF
The present invention provides a metal-oxo complex represented by the following general formula (1),
##STR00001## wherein in the general formula (1) above, “M” represents a molybdenum atom or a tungsten atom; “A” represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom; X.sup.1 and X.sup.2 each independently represent a halogen atom; R.sup.1 to R.sup.5 each independently represent a hydrogen atom, a straight or branched chain alkyl group that is substituted or unsubstituted and has 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms; each of R.sup.1 to R.sup.3 may be bonded to one another to form a ring.
METHOD FOR CONVERTING MONOISOCYANATES TO UREAS
Organic isocyanates are converted to ureas by heating in the presence of certain cobalt, magnesium, chromium and lanthanide series organometallic catalysts. The process requires no water or other reactants. The process is particularly useful for removing small quantities of monoisocyanates from a solvent stream recovered from a polyisocyanate manufacturing process. The urea compounds in some instances can be recycled back into the polyisocyanate manufacturing process and reacted with polyisocyanate compounds to form biurets.
Thermally conductive silicone composition
With respect to an addition-curable thermally conductive silicone composition in which a silver filler is blended, a catalyst having a specific structure and an organohydrogen polysiloxane having a specific structure are used for the purpose of extending the working life at room temperature, while maintaining the flexibility, so that a thermally conductive silicone composition which is able to have a good balance between flexibility after curing and storage stability in one pack, while having extremely low thermal resistance and excellent reliability is achieved.
Process for preparing short-chain olefins in the gas phase
A hydroformylation process can be used for short-chain olefins, especially C2 to C5 olefins, wherein the catalyst system is heterogenized on a support that contains a porous ceramic material. Systems can also be used for carrying out said process.
Process for the hydroformylation of olefins using a cobalt precatalyst and a diphosphine ligand
Process for the hydroformylation of olefins using a cobalt precatalyst and a diphosphine ligand.
Ru-catalyzed domino hydroformylation/hydrogenation/esterification using phosphine ligands
Ru-catalysed domino hydroformylation/hydrogenation/esterification using phosphine ligands.
PROCESS FOR PREPARING 3-(CYCLOHEX-1-EN-1-YL)PROPANAL DERIVATIVES
The present invention relates to the field of perfumery. More particularly, it concerns valuable new chemical intermediates for producing perfuming ingredients. Moreover, the present invention comprises also a process for producing compound of formula (I).
##STR00001##