B01J2219/1245

Chemical reaction method

A chemical reaction method having steps of preparing a chemical reaction apparatus by partitioning an inside of a horizontal flow reactor into multiple chambers by multiple partition plates, and flowing a liquid horizontally with an unfilled space being provided thereabove, generating microwaves with a microwave generator, and transmiting the microwaves, with at least one waveguide, to the unfilled space in the reactor. Also forming a top portion of the partition plates act as a weir, inclining the reactor such that, in each of the chambers, a weir height on the inlet side is higher than a weir height on the outlet side by at least an overflow depth at the partition plate on the outlet side, flowing content over each of the partition plates inside the reactor, and configuring the weir heights of the partition plates in the reactor are the same in a state where the reactor is not inclined.

FERROMAGNETIC-PARTICLE MANUFACTURING APPARATUS

A method for manufacturing a ferromagnetic-particle includes preparing a manufacturing apparatus including an induction heating coil; a radiofrequency power source electrically connected to the induction heating coil and configured to form an alternating field inside the induction heating coil; a pipe disposed to pass through the induction heating coil, in which at least a partial area of the pipe in an axial direction thereof is formed of a dielectric material and an area, which is nearer to one end of the pipe than the area formed of a dielectric material, is formed of a conductive material; and a pump configured to introduce, from the one end of the pipe, an alkaline reaction liquid in which metal ions of a ferromagnetic metal and hydroxide ions are dissolved; reacting the reaction liquid in the pipe, introduced by the pump, by forming an alternating field inside the induction heating coil; and generating the ferromagnetic-particle in the pipe based on the reaction of the reaction liquid in the pipe.

FERROMAGNETIC-PARTICLE MANUFACTURING APPARATUS

A method for manufacturing a ferromagnetic-particle includes preparing a manufacturing apparatus including a single mode cavity that resonates with a microwave of a predetermined wavelength; a microwave oscillator electrically connected to the single mode cavity and configured to introduce the microwave of a predetermined wavelength into the single mode cavity; a pipe disposed to pass linearly through an inside of the single mode cavity, the pipe being formed of a dielectric material; and a pump configured to introduce, from one end of the pipe, an alkaline reaction liquid in which metal ions of a ferromagnetic metal and hydroxide ions are dissolved; and reacting the reaction liquid in the pipe, introduced by the pump, by introducing the microwave into the single mode cavity so as to generate the ferromagnetic-particle in the pipe.

MICROWAVE-ASSISTED CATALYSIS FOR HYDROGEN SULFIDE TREATMENT
20240189792 · 2024-06-13 ·

A Traveling Wave Reactor (TWR) includes an inner microwave-transparent tube including an inlet and an outlet; an outer resonant tube surrounding a section of the microwave-transparent tube; a microwave source operable to provide microwave radiation to the resonant tube, wherein the microwave radiation creates a traveling microwave field in the resonant tube; and a tube rotator operable to rotate the microwave-transparent tube. A method for H.sub.2S treatment includes introducing a gas comprising H.sub.2S into a Traveling Wave Reactor (TWR), wherein the TWR includes a microwave source and a microwave-transparent tube including a catalyst bed; contacting the gas with the catalyst bed; and irradiating the catalyst bed with microwaves emitted by the microwave source, thereby activating a conversion of H.sub.2S.

Microwave reactor vessel
10245574 · 2019-04-02 ·

A microwave reactor constructed to produce a homogeneous heat distribution across the body of the microwave reactor subsequent exposure to microwave irradiation. The microwave reactor includes a body having an exterior wall transparent to microwave irradiation. A microwave sensitized element layer is adjacent the exterior wall and is comprised of a carbide mixture wherein the carbide mixture includes a carbide mixed with either a metal oxide, a ferrite or a nitride. The carbide mixture is in granular form wherein the carbide has a larger particle size than the other component. The microwave sensitized element layer further includes a metal layer that extends the length thereof. The metal layer is positioned in various arrangements within or adjacent to the carbide mixture. The body further includes an inner layer adjacent to the microwave sensitized layer opposite the exterior wall. The inner layer is transparent to microwave irradiation.

Device and process for producing undecylenic acid methyl ester using methyl ricinoleate as raw material

A device and a process for producing undecylenic acid methyl ester using methyl ricinoleate as raw material are provided. The device comprises a feed pump, a raw material pre-heater, a microwave catalytic reactor, a microwave generator, a temperature controller and an infrared sensor, a condenser, a product tank and a discharge pump. The feed pump is connected with the raw material pre-heater, which is connected with the inlet of the microwave catalytic reactor. The outlet of the microwave catalytic reactor is connected with the condenser, which is connected to the product tank and the discharge pump. The microwave catalytic reactor is located in the microwave generator, which is connected with the temperature controller and the infrared sensor. The process is as follows: high-purity methyl ricinoleate, used as the raw material, is converted to methyl undecene and heptaldehyde by microwave-assisted pyrolysis process, followed by isolation and purification to produce methyl undecene.

Heavy Fossil Hydrocarbon Conversion and Upgrading Using Radio-Frequency or Microwave Energy

Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RE) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.

FERROMAGNETIC-PARTICLE MANUFACTURING APPARATUS

A ferromagnetic-particle manufacturing apparatus includes: a single mode cavity that resonates with a microwave of a predetermined wavelength; a microwave oscillator electrically connected to the single mode cavity and configured to introduce the microwave of a predetermined wavelength into the single mode cavity; a pipe disposed to pass through an inside of the single mode cavity, the pipe being formed of a dielectric material; a pump configured to introduce, from one end of the pipe, an alkaline reaction liquid containing metal ions of a ferromagnetic metal; an impedance measuring device configured to measure an impedance of the single mode cavity; and a pump-flowrate deciding unit configured to decide, based on a measurement result of the impedance measuring device, a pump flowrate by which the impedance of the single mode cavity becomes a predetermined value or more; wherein the pump is configured to introduce the reaction liquid at the pump flowrate decided by the pump-flowrate deciding unit; and wherein ferromagnetic particles are generated by reacting the reaction liquid.

Heavy fossil hydrocarbon conversion and upgrading using radio-frequency or microwave energy

Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RF) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.

CHEMICAL REACTION APPARATUS

In order to suppress discharge of an unreacted content in a chemical reaction apparatus for irradiating a content with microwaves, a chemical reaction apparatus includes: a horizontal flow-type reactor in which a liquid content horizontally flows with an unfilled space being provided thereabove; a microwave generator that generates microwaves; and a waveguide that transmits the microwaves generated by the microwave generator to the unfilled space in the reactor, wherein the inside of the reactor is partitioned into multiple chambers to by overflow-type partition plates and that allow the content to flow thereover and an underflow-type partition plate that allows the content to flow thereunder.