A solid-state hydrogen storage device includes a first storage for storing a reversible solid-state hydrogen storage material, a reactor disposed in the first storage to enable a hydrolysis reaction of a non-reversible solid-state hydrogen storage material to be performed therein, and a fuel cell stack, wherein the non-reversible solid-state hydrogen storage material is stored in the reactor, and wherein the non-reversible solid-state hydrogen storage material releases heat when the hydrolysis is performed.

Provided is an integrated device for preparing magnesium hydride powder and a method for preparing magnesium hydride powder. The device comprises a heating chamber for heating a magnesium-based metal material to produce metal droplets; a powder-making chamber comprising an atomizing means used for atomizing the metal droplets which are then cooled to form a metal powder; and a reaction chamber used for performing a hydrogenation reaction on the metal powder to form the magnesium hydride powder. The device is an integrated structure monolithic with a simple structure and a convenient operation; and the entire process of preparing magnesium hydride powder can be completed in this single device and can realize automated control. The preparation method is simple and easy to operate and produces a product that has a moderate size, uniform particles, and excellent performance.

Provided is an integrated device for preparing magnesium hydride powder and a method for preparing magnesium hydride powder. The device comprises a heating chamber for heating a magnesium-based metal material to produce metal droplets; a powder-making chamber comprising an atomizing means used for atomizing the metal droplets which are then cooled to form a metal powder; and a reaction chamber used for performing a hydrogenation reaction on the metal powder to form the magnesium hydride powder. The device is an integrated structure monolithic with a simple structure and a convenient operation; and the entire process of preparing magnesium hydride powder can be completed in this single device and can realize automated control. The preparation method is simple and easy to operate and produces a product that has a moderate size, uniform particles, and excellent performance.

The invention relates to powdery, highly reactive alkali and alkaline earth hydride compounds, and to mixtures with elements of the third main group of the periodic table of elements (PTE) and to the preparation thereof by reacting alkali or alkaline earth metals in the presence of finely dispersed metals or compounds of the third main group of the PTE, wherein the latter have one or more hydride ligands or said hydride ligands are converted in situ, under the prevailing reaction conditions, i.e., in the presence of hydrogen gas or another H source, into hydride species, and to the use thereof for the preparation of complex hydrides and organometallic compounds.

The invention relates to powdery, highly reactive alkali and alkaline earth hydride compounds, and to mixtures with elements of the third main group of the periodic table of elements (PTE) and to the preparation thereof by reacting alkali or alkaline earth metals in the presence of finely dispersed metals or compounds of the third main group of the PTE, wherein the latter have one or more hydride ligands or said hydride ligands are converted in situ, under the prevailing reaction conditions, i.e., in the presence of hydrogen gas or another H source, into hydride species, and to the use thereof for the preparation of complex hydrides and organometallic compounds.

The invention discloses nano magnesium hydride and an in-situ preparation method thereof, including disposing and stirring magnesium chloride and lithium hydride in an organic solvent under a protection of an inert atmosphere, so as to obtain an organic suspension of a mixture; performing an ultrasonic treatment to the organic suspension, so as to promote a chemical reaction of the mixture. After the reaction is completed, the suspension is filtered; the solid reaction product is washed, centrifuged and dried to remove residual organic matter, so as to obtain nano-magnesium hydride.

The invention discloses nano magnesium hydride and an in-situ preparation method thereof, including disposing and stirring magnesium chloride and lithium hydride in an organic solvent under a protection of an inert atmosphere, so as to obtain an organic suspension of a mixture; performing an ultrasonic treatment to the organic suspension, so as to promote a chemical reaction of the mixture. After the reaction is completed, the suspension is filtered; the solid reaction product is washed, centrifuged and dried to remove residual organic matter, so as to obtain nano-magnesium hydride.

According to one embodiment, a magnesium-recycling hydrogen generation system includes: a by-product acquisition unit that separates a by-product from a post-reaction solution, which is a solution after reacting with a hydrogen generation material containing a hydrogen-containing magnesium compound that generates hydrogen via a reaction with the solution, to acquire the by-product including more than one type of oxygen-containing magnesium compound that contains oxygen produced by the reaction, a raw material production unit that reacts the by-product with a halogen-containing substance containing halogen and other atoms than the halogen to produce a raw material containing magnesium halide, a hydrogen generation material production unit that reduces the raw material with plasma containing hydrogen to produce the hydrogen generation material, and a hydrogen generator that reacts the hydrogen generation material with the solution to generate hydrogen.

A hydrogen storage assembly includes at least one wafer formed of a substrate material that produces metal hydride when exposed to a hydrogen-rich carrier fluid. The wafer can be supported by a housing and arranged so that the hydrogen-rich carrier fluid can flow over a reaction surface of the wafer. At least one heating element can be arranged to transfer heat to the wafer to attain an operating temperature suitable for hydrogen charging on the reaction surface. A de-activation material may be provided on the reaction surface for inhibiting formation of surface oxide that impedes hydrogen absorption during charging and hydrogen desorption during discharging. The at least one wafer can include a plurality of monolithic plate wafers spaced apart about a central axis of the assembly. The at least one wafer can include a plurality of monolithic disc wafers in at least one stacked arrangement.

A hydrogen storage assembly includes at least one wafer formed of a substrate material that produces metal hydride when exposed to a hydrogen-rich carrier fluid. The wafer can be supported by a housing and arranged so that the hydrogen-rich carrier fluid can flow over a reaction surface of the wafer. At least one heating element can be arranged to transfer heat to the wafer to attain an operating temperature suitable for hydrogen charging on the reaction surface. A de-activation material may be provided on the reaction surface for inhibiting formation of surface oxide that impedes hydrogen absorption during charging and hydrogen desorption during discharging. The at least one wafer can include a plurality of monolithic plate wafers spaced apart about a central axis of the assembly. The at least one wafer can include a plurality of monolithic disc wafers in at least one stacked arrangement.