Systems and methods for separating CO.sub.2 and H.sub.2S from a natural gas stream are provided herein. The system includes a first loop of co-current contacting systems configured to remove H.sub.2S and CO.sub.2 from a natural gas stream and a second loop of co-current contacting systems configured to remove the H.sub.2S from the CO.sub.2.

The present invention discloses a hydrogen sulfide reactor vessel with an external heating system that is conductively and removably attached to an exterior portion of the reactor vessel. Also disclosed are processes for producing hydrogen sulfide utilizing the reactor vessel.

To provide a hydrogen sulfide mixture hardly corroding metals. The hydrogen sulfide mixture contains hydrogen sulfide and water. The hydrogen sulfide mixture is filled into a filling container so that at least one part of the hydrogen sulfide mixture is liquid and the moisture concentration of a gaseous phase is 0.001 mol ppm or more and less than 75 mol ppm.

To provide a hydrogen sulfide mixture hardly corroding metals. The hydrogen sulfide mixture contains hydrogen sulfide and water. The hydrogen sulfide mixture is filled into a filling container so that at least one part of the hydrogen sulfide mixture is liquid and the moisture concentration of a gaseous phase is 0.001 mol ppm or more and less than 75 mol ppm.

Systems and methods for removing hydrogen sulfide from an ammonia stream in the NH3 purification and liquefaction stage of a conventional two-column sour water stripping system using an adsorbent bed.

The composite amine absorbing solution according to the present invention absorbs CO.sub.2 or H.sub.2S or both in a gas, and is obtained by dissolving a linear monoamine, a diamine, and an amide group-containing compound in water. By adopting this composite amine absorbing solution, the composites are interacting in a composite manner, due to an integrated effect of the components, the absorption property of CO.sub.2 or H.sub.2S or both is favorable, the desorption properties of the CO.sub.2 or H.sub.2S absorbed when regenerating the absorbing solution become favorable, and the amount of steam from a reboiler used when regenerating the absorbing solution in a CO.sub.2 recovery device can be reduced.

A process for recovering sulfur in a sulfur recovery unit comprising the steps of reacting hydrogen sulfide and oxygen in the reaction furnace at a minimum reaction temperature to produce a reaction effluent; reducing the temperature of the reaction effluent from the minimum reaction temperature to a boiler section outlet temperature to produce a cooled effluent, the cooled effluent comprises hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants; reacting the hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants in the catalytic extension to produce a boiler catalytic effluent; reducing the boiler catalytic effluent temperature such that the elemental sulfur condenses to form liquid sulfur and a gases stream; reacting the hydrogen sulfide and sulfur-containing contaminants with the oxygen to produce an oxidizer outlet stream comprises sulfur dioxide; and separating the sulfur dioxide in the scrubbing unit to produce a recycle stream and an effluent gases, the recycle stream comprises sulfur dioxide.

A process for recovering sulfur in a sulfur recovery unit comprising the steps of reacting hydrogen sulfide and oxygen in the reaction furnace at a minimum reaction temperature to produce a reaction effluent; reducing the temperature of the reaction effluent from the minimum reaction temperature to a boiler section outlet temperature to produce a cooled effluent, the cooled effluent comprises hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants; reacting the hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants in the catalytic extension to produce a boiler catalytic effluent; reducing the boiler catalytic effluent temperature such that the elemental sulfur condenses to form liquid sulfur and a gases stream; reacting the hydrogen sulfide and sulfur-containing contaminants with the oxygen to produce an oxidizer outlet stream comprises sulfur dioxide; and separating the sulfur dioxide in the scrubbing unit to produce a recycle stream and an effluent gases, the recycle stream comprises sulfur dioxide.

In a process for separating at least one heavy impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one light impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the light impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed light impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.

A process for recovering sulfur in a sulfur recovery unit comprising the steps of reacting hydrogen sulfide and oxygen in the reaction furnace at a minimum reaction temperature to produce a reaction effluent; reducing the temperature of the reaction effluent from the minimum reaction temperature to a boiler section outlet temperature to produce a cooled effluent, the cooled effluent comprises hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants; reacting the hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants in the catalytic extension to produce a boiler catalytic effluent; reducing the boiler catalytic effluent temperature such that the elemental sulfur condenses to form liquid sulfur and a gases stream; reacting the hydrogen sulfide and sulfur-containing contaminants with the oxygen to produce an oxidizer outlet stream comprises sulfur dioxide; and separating the sulfur dioxide in the scrubbing unit to produce a recycle stream and an effluent gases, the recycle stream comprises sulfur dioxide.