Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.

Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.

A power supply control device of a nitrogen gas generator includes: a pipe having a nitrogen gas inlet for receiving input of nitrogen gas from a nitrogen gas generator that compresses air by a compressor to separate the nitrogen gas from the air, and a nitrogen gas outlet for outputting, to outside, the nitrogen gas received by the nitrogen gas inlet; a pressure gauge that measures pressure inside the pipe; a flowmeter that measures a flow rate of the nitrogen gas flowing inside the pipe; and a control unit that controls supply of power to the compressor and shut-off of the supply of the power in accordance with a measurement result of at least one of the pressure gauge and the flowmeter.

A power supply control device of a nitrogen gas generator includes: a pipe having a nitrogen gas inlet for receiving input of nitrogen gas from a nitrogen gas generator that compresses air by a compressor to separate the nitrogen gas from the air, and a nitrogen gas outlet for outputting, to outside, the nitrogen gas received by the nitrogen gas inlet; a pressure gauge that measures pressure inside the pipe; a flowmeter that measures a flow rate of the nitrogen gas flowing inside the pipe; and a control unit that controls supply of power to the compressor and shut-off of the supply of the power in accordance with a measurement result of at least one of the pressure gauge and the flowmeter.

A system and method to supply nitrogen gas is provided. Ambient air is compressed and stored in a storage receiver and then nitrogen is separated from the compressed air in a nitrogen membrane separation unit. The separated nitrogen is stored in a nitrogen storage tank under pressure and released through a pressure control valve. The system is confined to a small footprint and is useful as a nitrogen source where conventional compressed nitrogen tanks are a safety or space issue. Systems to prepare nitrogen infused beverages are also provided.

Nitrox-mixtures production machine comprising: a molecular separator, which is structured so as to receive at inlet a flow of air and to provide at outlet an intermediate Nitrox mixture with high oxygen percentage; a low-pressure compressor, which is adapted to feed an airflow at inlet of the molecular separator; a mixing manifold, which communicates with the molecular separator so as to receive said intermediate Nitrox mixture, and is structured so as to mix the intermediate Nitrox mixture with fresh air coming from the outside, in order to provide at outlet a final Nitrox mixture with predefined composition; at least one oxygen sensor, which is adapted to measure the oxygen percentage present in said final Nitrox mixture; at least one pressure sensor, which is adapted to measure the air pressure in the molecular separator; and an electronic control device, which is connected to said at least one oxygen sensor and is adapted to regulate the flowrate of the airflow that is sucked in by the low-pressure compressor based on the signals coming from said at least one oxygen sensor and said at least one pressure sensor.

Nitrox-mixtures production machine comprising: a molecular separator, which is structured so as to receive at inlet a flow of air and to provide at outlet an intermediate Nitrox mixture with high oxygen percentage; a low-pressure compressor, which is adapted to feed an airflow at inlet of the molecular separator; a mixing manifold, which communicates with the molecular separator so as to receive said intermediate Nitrox mixture, and is structured so as to mix the intermediate Nitrox mixture with fresh air coming from the outside, in order to provide at outlet a final Nitrox mixture with predefined composition; at least one oxygen sensor, which is adapted to measure the oxygen percentage present in said final Nitrox mixture; and an electronic control device, which is connected to said at least one oxygen sensor and is adapted to regulate the flowrate of the airflow that the low-pressure compressor feeds at inlet of the molecular separator based on the signals coming from said at least one oxygen sensor.

Disclosed herein are methods and systems to isolate nitrogen from a mixture of gases. In an embodiment, a method of isolating nitrogen from a gaseous mixture involves contacting the gaseous mixture with a superparamagnetic catalyst to form a reaction mixture, and exposing the reaction mixture to a fluctuating magnetic field at ambient conditions.

The invention concerns a CLC process, and its installation, producing high purity dinitrogen, comprising:

(a) the combustion of a hydrocarbon feed by reduction of a redox active mass brought into contact with the feed,
(b) a first step for oxidation of the reduced active mass (25) obtained from step (a) in contact with a fraction of a depleted air stream (21b), in order to produce a high purity stream of dinitrogen (28) and a stream of partially re-oxidized active mass (26);
(c) a second step for oxidation of the stream of active mass (26) in contact with air (20) in order to produce a stream of depleted air and a stream of re-oxidized active mass (24) for use in step (a);
(d) dividing the stream of depleted air obtained at the end of step (c) in order to form the fraction of depleted air used in step (b) and a fraction complementary to the depleted air extracted from the CLC.

Process and system for producing an ammonia synthesis gas, the process comprises the steps of: (a) providing a separate stream comprising nitrogen by pressure swing absorption of ambient air; (b) providing a separate stream comprising hydrogen by electrolysis of water and/or steam; (c) combining the separate streams obtained in steps a) and b) into a mixed stream comprising hydrogen and nitrogen; (d) pressurizing the mixed stream from step (c); and (e) removing residual amounts of oxygen further contained in the mixed stream by catalytic hydrogenation of the oxygen with a part of the hydrogen contained in the mixed stream upstream step (d) and/or downstream step (d) and/or during step (d) to produce the ammonia synthesis gas.