The present invention is to provide a method for producing nanodiamonds doped with a Group 14 element, the method comprising: detonating by exploding an explosive composition containing at least one explosive and at least one Group 14 element compound in a sealed container to obtain nanodiamonds doped with at least one Group 14 element selected from the group consisting of Si, Ge, Sn, and Pb, and removing the Group 14 element and/or oxide thereof by subjecting the nanodiamonds doped with a Group 14 element to an alkali treatment.

Systems and methods for eliminating carbon dioxide and capturing solid carbon are disclosed. By eliminating carbon dioxide gas, e.g., from an effluent exhaust stream of a fossil fuel fired electric power production facility, the inventive concepts presented herein represent an environmentally-clean solution that permanently eliminates greenhouse gases while at the same time producing captured solid carbon products that are useful in various applications including advanced composite material synthesis (e.g., carbon fiber, 3D graphene) and energy storage (e.g., battery technology). Capture of solid carbon during the disclosed process for eliminating greenhouse gasses avoids the inefficiencies and risks associated with conventional carbon dioxide sequestration. Colocation of the disclosed reactor with a fossil fuel fired power production facility brings to bear an environmentally beneficial, and financially viable approach for permanently capturing vast amounts of solid carbon from carbon dioxide gas and other greenhouse gases that would otherwise be released into Earth's biosphere.

The invention discloses equipment and preparation method for open and continuous growth of a carbon nanomaterial. The equipment comprises a metal foil tape feeding system, a CVD system and a collection system. The method includes continuously conveying a metal foil tape pretreated or not into the CVD system via the metal foil tape feeding system, depositing a required carbon nanomaterial on the surface of the metal foil tape by CVD, directly collecting by the collection system or directly post-treating the carbon nanomaterial by a post-treatment system, and even directly producing a end product of the carbon nanomaterial. All the systems in the invention are arranged in the open atmosphere rather than an air-isolated closed space. The invention can realize round-the-clock continuous operation to greatly improve the production efficiency of carbon nanomaterials.

Systems and methods for eliminating carbon dioxide and capturing solid carbon are disclosed. By eliminating carbon dioxide gas, e.g., from an effluent exhaust stream of a fossil fuel fired electric power production facility, the inventive concepts presented herein represent an environmentally-clean solution that permanently eliminates greenhouse gases while at the same time producing captured solid carbon products that are useful in various applications including advanced composite material synthesis (e.g., carbon fiber, 3D graphene) and energy storage (e.g., battery technology). Capture of solid carbon during the disclosed process for eliminating greenhouse gasses avoids the inefficiencies and risks associated with conventional carbon dioxide sequestration. Colocation of the disclosed reactor with a fossil fuel fired power production facility brings to bear an environmentally beneficial, and financially viable approach for permanently capturing vast amounts of solid carbon from carbon dioxide gas and other greenhouse gases that would otherwise be released into Earth's biosphere.

The purpose of the present technology is to provide an electrode for power storage device and a power storage device that make it possible to involve more lithium ions in a charge-discharge reaction. A lithium-ion secondary battery has: a positive electrode current collector; a positive electrode active material layer on the positive electrode current collector; a negative electrode current collector; and a negative electrode active material layer on the negative electrode current collector. The negative electrode active material layer has a carbon nanowall. The carbon nanowall is capable of involving, in the charge-discharge reaction, two or more lithium ions per carbon atom in a single charge or discharge.

The embodiments of the present disclosure relate to a method and apparatus for producing a carbon nanomaterial product (CNM) product that may comprise carbon nanotubes and various other allotropes of nanocarbon. The method and apparatus employ a consumable carbon dioxide (CO.sub.2) and a renewable carbonate electrolyte as reactants in an electrolysis reaction in order to make CNTs. In some embodiments of the present disclosure, operational conditions of the electrolysis reaction may be varied in order to produce the CNM product with a greater incidence of a desired allotrope of nanocarbon or a desired combination of two or more allotropes.

The present invention provides a metal-carbon composite of a core-shell structure and a method of synthesizing the same. The method includes preparing a first polymer-covered glass substrate with a nano-thickness metal film deposited thereon; immersing the first polymer-covered glass substrate with the metal film to delaminate one or more 2D freestanding organic-metal nanosheets from the first polymer-covered glass substrate; transferring the one or more 2D freestanding organic-metal nanosheets onto a second target substrate; and annealing the one or more 2D freestanding organic-metal nanosheets to decompose an organic portion of the organic-metal nanosheet into an amorphous carbon-containing shell forming a metal-carbon nanocomposite of a core-shell structure.

The present invention provides a metal-carbon composite of a core-shell structure and a method of synthesizing the same. The method includes preparing a first polymer-covered glass substrate with a nano-thickness metal film deposited thereon; immersing the first polymer-covered glass substrate with the metal film to delaminate one or more 2D freestanding organic-metal nanosheets from the first polymer-covered glass substrate; transferring the one or more 2D freestanding organic-metal nanosheets onto a second target substrate; and annealing the one or more 2D freestanding organic-metal nanosheets to decompose an organic portion of the organic-metal nanosheet into an amorphous carbon-containing shell forming a metal-carbon nanocomposite of a core-shell structure.

A system and process for producing doped carbon nanomaterials is disclosed. A carbonate electrolyte including a doping component is provided during the electrolysis between an anode and a cathode immersed in carbonate electrolyte contained in a cell. The carbonate electrolyte is heated to a molten state. An electrical current is applied to the anode, and cathode, to the molten carbonate electrolyte disposed between the anode and cathode. A morphology element maximizes carbon nanotubes, versus graphene versus carbon nano-onion versus hollow carbon nano-sphere nanomaterial product. The resulting carbon nanomaterial growth is collected from the cathode of the cell.

A system and process for producing doped carbon nanomaterials is disclosed. A carbonate electrolyte including a doping component is provided during the electrolysis between an anode and a cathode immersed in carbonate electrolyte contained in a cell. The carbonate electrolyte is heated to a molten state. An electrical current is applied to the anode, and cathode, to the molten carbonate electrolyte disposed between the anode and cathode. A morphology element maximizes carbon nanotubes, versus graphene versus carbon nano-onion versus hollow carbon nano-sphere nanomaterial product. The resulting carbon nanomaterial growth is collected from the cathode of the cell.