The present invention describes a processes, systems, and catalysts for the conversion of carbon dioxide and water and electricity into low carbon or zero carbon high quality fuels and chemicals. In one aspect, the present invention provides an integrated process for the conversion of a feed stream comprising carbon dioxide to a product stream comprising hydrocarbons between 5 and 24 carbon atoms in length.

The present invention describes a processes, systems, and catalysts for the conversion of carbon dioxide and water and electricity into low carbon or zero carbon high quality fuels and chemicals. In one aspect, the present invention provides an integrated process for the conversion of a feed stream comprising carbon dioxide to a product stream comprising hydrocarbons between 5 and 24 carbon atoms in length.

Systems and methods for eliminating carbon dioxide and capturing solid carbon are disclosed. By eliminating carbon dioxide gas, e.g., from an effluent exhaust stream of a fossil fuel fired electric power production facility, the inventive concepts presented herein represent an environmentally-clean solution that permanently eliminates greenhouse gases while at the same time producing captured solid carbon products that are useful in various applications including advanced composite material synthesis (e.g., carbon fiber, 3D graphene) and energy storage (e.g., battery technology). Capture of solid carbon during the disclosed process for eliminating greenhouse gasses avoids the inefficiencies and risks associated with conventional carbon dioxide sequestration. Colocation of the disclosed reactor with a fossil fuel fired power production facility brings to bear an environmentally beneficial, and financially viable approach for permanently capturing vast amounts of solid carbon from carbon dioxide gas and other greenhouse gases that would otherwise be released into Earth's biosphere.

As a hydrocarbon production system that synthesizes hydrocarbons using water and carbon dioxide as raw materials, a hydrocarbon production system capable of producing hydrocarbons by securing hydrogen and carbon monoxide required for hydrocarbon synthesis is provided. In a hydrocarbon production system that produces hydrocarbons from at least water and carbon dioxide, the hydrocarbon production system includes at least an electrolytic reaction unit, a reverse water-gas shift reaction unit, and a hydrocarbon synthesis reaction unit.

As a hydrocarbon production system that synthesizes hydrocarbons using water and carbon dioxide as raw materials, a hydrocarbon production system capable of producing hydrocarbons by securing hydrogen and carbon monoxide required for hydrocarbon synthesis is provided. In a hydrocarbon production system that produces hydrocarbons from at least water and carbon dioxide, the hydrocarbon production system includes at least an electrolytic reaction unit, a reverse water-gas shift reaction unit, and a hydrocarbon synthesis reaction unit.

The present invention provides a method of preparing acetylene (C.sub.2H.sub.2), the method at least comprising the steps of: a) providing a methane-containing stream; b) subjecting the methane-containing stream provided in step a) to non-catalytic pyrolysis, thereby obtaining carbon and hydrogen; c) reacting the carbon obtained in step b) with CaO, thereby obtaining CaC.sub.2 and CO; d) reacting the CaC.sub.2 obtained in step c) with H.sub.2O, thereby obtaining acetylene (C.sub.2H.sub.2) and Ca(OH).sub.2; e) decomposing the Ca(OH).sub.2 obtained in step d), thereby obtaining CaO and H.sub.2O; f) using the CaO as obtained in step e) in the reaction of step c).

The present invention provides a method of preparing acetylene (C.sub.2H.sub.2), the method at least comprising the steps of: a) providing a methane-containing stream; b) subjecting the methane-containing stream provided in step a) to non-catalytic pyrolysis, thereby obtaining carbon and hydrogen; c) reacting the carbon obtained in step b) with CaO, thereby obtaining CaC.sub.2 and CO; d) reacting the CaC.sub.2 obtained in step c) with H.sub.2O, thereby obtaining acetylene (C.sub.2H.sub.2) and Ca(OH).sub.2; e) decomposing the Ca(OH).sub.2 obtained in step d), thereby obtaining CaO and H.sub.2O; f) using the CaO as obtained in step e) in the reaction of step c).

The disclosure provides for the integration of a CO-consuming process, such as a gas fermentation process, with a CO.sub.2 to CO conversion system. The disclosure is capable of utilizing a CO.sub.2-comprising gaseous substrate generated by an industrial process and provides for one or more removal modules to remove at least one constituent from a CO.sub.2-comprising gaseous substrate prior to passage of the gaseous substrate to a CO.sub.2 to CO conversion system. The disclosure may further comprise one or more pressure modules, one or more CO.sub.2 concentration modules, one or more O.sub.2 separation modules, and/or a water electrolysis module. Carbon conversion efficiency is increased by recycling CO.sub.2 produced by a CO-consuming process to the CO.sub.2 to CO conversion process.

The disclosure provides for the integration of a CO-consuming process, such as a gas fermentation process, with a CO.sub.2 to CO conversion system. The disclosure is capable of utilizing a CO.sub.2-comprising gaseous substrate generated by an industrial process and provides for one or more removal modules to remove at least one constituent from a CO.sub.2-comprising gaseous substrate prior to passage of the gaseous substrate to a CO.sub.2 to CO conversion system. The disclosure may further comprise one or more pressure modules, one or more CO.sub.2 concentration modules, one or more O.sub.2 separation modules, and/or a water electrolysis module. Carbon conversion efficiency is increased by recycling CO.sub.2 produced by a CO-consuming process to the CO.sub.2 to CO conversion process.

A method for generating carbon monoxide includes: a generation step of generating carbon monoxide by supplying carbon dioxide to a first material containing a first element included in elements of group 11 and a second element included in elements of groups 8 to 10, 12, and 13; and a reduction step of reducing the second element oxidized in the generation step by supplying hydrogen to a second material containing the oxidized second element and the first element. The generation step and the reduction step are repeated a plurality of times.