Provided are a pentasil-type zeolite that is less likely to adsorb water compared to conventional zeolites and has excellent strength when used as a molded body, and a method for producing the pentasil-type zeolite. A pentasil-type zeolite having a water adsorption amount of 4.0 g/100 g-zeolite or less under the conditions of 25° C. and a relative humidity of 90% and having a major axis diameter of primary particles of from 0.2 μm to 4.0 μm, and a method for producing the pentasil-type zeolite.

The present invention provides zeolite hollow spheres in which zeolite crystals grow to form a framework of macropore through a hydrothermal crystallization process using the hydrophilic surface of a carbon sphere as a hard template, wherein the zeolite framework is an ordered, porous crystalline zeolite material with a number of channels or pores interconnected, which has two independent pore structures including mesopores and micropores. The zeolite hollow spheres of the present invention can be used for various purposes such as catalysts and adsorbents.

To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.

It is provided a method for obtaining mesoporous silica particles with surface functionalisation comprising the steps of a) providing solutions of at least three precursors; wherein the pH of the mixture is adjusted to a range between 2 and 8 in a buffered system; b) Mixing the precursor solutions thereby allowing a reaction to take place at a temperature between 20 and 60° C., whereby surface functionalized mesoporous silica particles as solid reaction product are formed; c) Separating the surface functionalized mesoporous silica particles from the reaction mixture by centrifugation or filtration; d) Removing any pore structure directing agent present in the pores of the formed surface functionalized mesoporous silica particles by ultrasonication; e) followed by separation by centrifugation or filtration, washing and drying of the surface functionalized mesoporous silica particles.

Provided is a method for preparing a defect-free DDR molecular sieve membrane. Sigma-1 molecular sieve is used as an inducing seed crystal to prepare and obtain a continuous and compact DDR molecular sieve membrane on the surface of a porous ceramic support. An ozone atmosphere or an external field assisted technology is used to remove a template in the pores of the molecular sieve membrane at a low temperature. The invention avoids the formation of intercrystal defects and cracks, an activated DDR molecular sieve membrane has a good selectivity for separating CO2, and the membrane preparation time is significantly reduced.

Provided are a zeolite with increased hydrothermal durability and a method of manufacturing the same. One aspect of the present invention provides a method of producing the zeolite, comprising the steps of: preparing a raw material zeolite (excluding FAU-type zeolite material) containing at least Si but not Al in the framework or having a Si/Al atomic ratio of 50 or more, and bringing the zeolite material into contact with a solution containing fluoride ions or with hot water at a temperature of 50° C. or more and 250° C. or less.

An alkali metal ion modified titanium silicalite zeolite TS-1 for gas phase epoxidation of propylene and hydrogen peroxide and a preparation method thereof. The method includes: 1: preparing an alkali metal hydroxide modification solution containing a small amount of TPA.sup.+ ions; 2: conducting a controlled hydrothermal treatment on a TS-1 zeolite matrix by using the alkali metal hydroxide solution containing a small amount of TPA.sup.+ ions; and 3: conducting post-treatment on the hydrothermally modified TS-1 zeolite. In the washing process, the modified TS-1 zeolite wet material is washed with a low concentration alkali metal hydroxide solution; and alkali metal ions are reserved on the silicon hydroxyl of the modified titanium silicalite zeolite. The prepared alkali metal ion modified titanium silicalite zeolite has significantly improved catalytic performance in the gas phase epoxidation of propylene and hydrogen peroxide.

A method for forming dendritic mesoporous nanoparticles comprising preparing a mixture containing one or more polymer precursors, a silica precursor, and a compound that reacts with silica and reacts with the polymer or oligomer formed from the one or more polymer precursors, and stirring the mixture whereby nanoparticles are formed, and subsequently treating the nanoparticles to form dendritic mesoporous silica nanoparticles or dendritic mesoporous carbon nanoparticles. The silica precursor may comprise tetraethyl orthosilicate (TEOS), the one or more polymer precursors may comprise 3-aminophenol and formaldehyde and the compound may be ethylene diamine (EDA). There is a window of amount of EDA present that will result in asymmetric particles being formed. If a greater amount of EDA is present, symmetrical particles will be formed.

A method for forming dendritic mesoporous nanoparticles comprising preparing a mixture containing one or more polymer precursors, a silica precursor, and a compound that reacts with silica and reacts with the polymer or oligomer formed from the one or more polymer precursors, and stirring the mixture whereby nanoparticles are formed, and subsequently treating the nanoparticles to form dendritic mesoporous silica nanoparticles or dendritic mesoporous carbon nanoparticles. The silica precursor may comprise tetraethyl orthosilicate (TEOS), the one or more polymer precursors may comprise 3-aminophenol and formaldehyde and the compound may be ethylene diamine (EDA). There is a window of amount of EDA present that will result in asymmetric particles being formed. If a greater amount of EDA is present, symmetrical particles will be formed.

Provided is a method for producing a separation membrane including a silicalite membrane without using NaOH or the like that causes an increase in cost with respect to equipment, facilities, and process time. The method for producing a separation membrane is a method for producing a separation membrane including a porous support and a silicalite membrane that is formed on the support and has an MFI-type zeolite crystal structure, and is characterized in that the method includes a step of producing a seed crystal, a step of attaching the seed crystal onto the porous support, a step of producing a membrane synthesis raw material composition containing SiO.sub.2, an organic template, and H.sub.2O, and a step of immersing the porous support having the seed crystal attached thereto in the membrane synthesis raw material composition and performing hydrothermal synthesis, and the composition ratio of the membrane synthesis raw material composition is as follows: SiO.sub.2:organic template:H.sub.2O=1:(0.05 to 0.15):(50 to 120).