Disclosed is a catalyst for production of multi-walled carbon nanotubes, in which the catalyst includes a transition metal catalyst supported on a support mixture including MgO, and thus can increase the production of multi-walled carbon nanotubes and, at the same time, reduce the number of walls of the multi-walled carbon nanotubes to thereby reduce the surface resistance of the multi-walled carbon nanotubes. Also disclosed is a method of producing multi-walled carbon nanotubes using the catalyst. The catalyst for production of multi-walled carbon nanotubes includes: a support mixture of a first support and a second support mixed with the first support; and a transition metal catalyst supported on the support mixture.

Disclosed herein are embodiments of methods for preparing aminated or alkylaminated CNTs wherein the aminated or alkylaminated CNTs are obtained in a reaction by reacting the CNTs with an aminating or alkylaminating reagent in a non-hazardous solvent or a non-hazardous solvent-deionized water mixture. The CNTs may be single-walled, double-walled or multi-walled CNTs. The disclosed processes for amination and alkylamination do not require treatment with concentrated acid, and with the use of solvent, the CNTs and aminating compound or alkylaminating compound are mixed thoroughly throughout the reaction.

The present invention provides a catalyst precursor and a catalyst suitable for preparing multi-wall carbon nanotubes. The resulting multi-wall carbon nanotubes have a narrow distribution as to the number of walls forming the tubes and a narrow distribution in the range of diameters for the tubes. Additionally, the present invention provides methods for producing multi-wall carbon nanotubes having narrow distributions in the number of walls and diameters. Further, the present invention provides a composition of spent catalyst carrying multi-wall nanotubes having narrow distribution ranges of walls and diameters.

An object of the present invention is to provide a nanotube-nanohorn complex having a high aspect ratio, also having high dispersibility, having controlled diameter, and having high durability at a low cost. According to the present invention, a carbon target containing a catalyst is evaporated with a laser ablation method to synthesize a structure including both of a carbon nanohorn aggregate and a carbon nanotube.

A composition comprising at least one high-density graphene-based monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds and having a density of at least 0.1 g/cm.sup.3. Also provided is a method comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension selected from a graphene oxide (GO) suspension and a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce a high-density graphene-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.

Carbon nanostructures are used to prepare electrode compositions for lithium ion batteries. In one example, an anode for a Li ion battery includes three-dimensional carbon nanostructures made of highly entangled nanotubes, fragments of carbon nanostructures and/or fractured nanotubes, which are derived from the carbon nanostructures, are branched and share walls with one another. Amounts of carbon nanostructures employed can be less than or equal to 0.5 weight % relative to the weight of the electrode composition.

According to example embodiments, a method includes dispersing carbon nanotubes in a mixed solution containing a solvent, the carbon nanotubes, and a dispersant, the carbon nanotubes including semiconducting carbon nanotubes, the dispersant comprising a polythiophene derivative including a thiophene ring and a hydrocarbon sidechain linked to the thiophene ring. The hydrocarbon sidechain includes an alkyl group containing a carbon number of 7 or greater. The hydrocarbon sidechain may be regioregularly arranged, and the semiconducting carbon nanotubes are selectively separated from the mixed solution. An electronic device includes semiconducting carbon nanotubes and the foregoing described polythiophene derivative.

Disclosed is a catalyst for production of multi-walled carbon nanotubes, in which the catalyst includes a transition metal catalyst supported on a support mixture including MgO, and thus can increase the production of multi-walled carbon nanotubes and, at the same time, reduce the number of walls of the multi-walled carbon nanotubes to thereby reduce the surface resistance of the multi-walled carbon nanotubes. Also disclosed is a method of producing multi-walled carbon nanotubes using the catalyst. The catalyst for production of multi-walled carbon nanotubes includes: a support mixture of a first support and a second support mixed with the first support; and a transition metal catalyst supported on the support mixture.

The present disclosure discloses a method for forming a high-density aligned carbon nanotube film. The method includes injecting a carbon nanotube solution into a container, and adding a dispersant to form a carbon nanotube-dispersant composite. The method also includes adding a substance that interacts with the carbon nanotube-dispersant composite and then dispersing the obtained carbon nanotube solution using water ultrasonic or probe ultrasonic to obtain a carbon nanotube solution containing a dispersant. Then a large-area or patterned high-quality aligned carbon nanotube film can be formed on a substrate by using processes such as pulling, injection dripping or printing. The method is low-cost and suitable for the preparation of large-area high-density aligned carbon nanotubes, and satisfies various needs for industrial application of carbon-based integrated circuits.

The present disclosure discloses a device and a method for preparing a high-density aligned carbon nanotube film. The device includes a container main body, a buffer partition plate and a solvent lead-out part. The buffer partition plate is located at a lower part of the container main body. The solvent lead-out part communicates with an interior of the container main body through a through hole in a side wall of the container main body and extends to an outside of the container main body. The method includes injecting a carbon nanotube solution into a container; immersing a substrate in the carbon nanotube solution; injecting a sealing liquid that is immiscible with the carbon nanotube solution along the substrate or the side wall of the container main body; and leading the solvent out or pulling the substrate such that the liquid surface of the substrate undergoes relative motion.