A method for the generation of a gas mixture including carbon monoxide, carbon dioxide and hydrogen for use in hydroformylation plants, including the steps of evaporating water to steam; feeding the steam to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while effecting a partial conversion of steam to hydrogen; utilizing the effluent SOEC gas including H.sub.2 together with CO.sub.2 from an external source as feed for a RWGS reactor in which the RWGS reaction takes place, converting some of the CO.sub.2 and H.sub.2 to CO and H.sub.2O; removing some of or all the remaining steam from the raw product gas stream; using said gas mixture comprising CO, CO.sub.2 and H.sub.2 for liquid phase hydroformylation utilizing carbon monoxide and hydrogen as reactants, while recycling CO.sub.2 to the RWGS reactor.

A method for the generation of a gas mixture comprising carbon monoxide, carbon dioxide and optionally hydrogen for use in hydroformylation plants or in carbonylation plants, including mixing an optional steam with carbon dioxide in the desired molar ratio, feeding the resulting gas to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while effecting a partial conversion of carbon dioxide to carbon monoxide and optionally of steam to hydrogen, removing some or all the remaining steam from the raw product gas stream by cooling the raw product gas stream and separating the remaining product gas from a liquid, and using said gas mixture containing CO and CO.sub.2 for liquid phase synthesis reactions utilizing carbon monoxide as one of the reactants while recycling CO.sub.2 to the SOEC or SOEC stack.

The method for recycling carbon dioxide according to the present invention includes: injecting a reaction gas containing carbon dioxide and a carbon raw material into a rotary heating furnace; reacting the reaction gas and the carbon raw material with each other in the rotary heating furnace to generate a hydrocarbon precursor containing carbon monoxide; and converting the hydrocarbon precursor into a hydrocarbon compound, thereby exhibiting excellent conversion rate of carbon dioxide.

In various aspects, systems and methods are provided for operating a molten carbonate fuel cell, such as a fuel cell assembly, with increased production of syngas while also reducing or minimizing the amount of CO.sub.2 exiting the fuel cell in the cathode exhaust stream. This can allow for improved efficiency of syngas production while also generating electrical power.

Methods and systems are provided for making gasoline. The method includes converting a resid-containing feed to a first fuel gas and a fluid coke in a fluidized bed reactor; gasifying the fluid coke with steam and air to produce a second fuel gas, said second fuel gas comprising a syngas; contacting the first fuel gas with a first conversion catalyst under first effective conversion conditions to form an effluent comprising C.sub.5+ hydrocarbon compounds; and converting the syngas to gasoline boiling range hydrocarbons by converting the syngas to a methanol intermediate product.

A power generation system that includes a membrane reformer assembly, wherein syngas is formed from a steam reforming reaction of natural gas and steam, and wherein hydrogen is separated from the syngas via a hydrogen-permeable membrane, a combustor for an oxy-combustion of a fuel, an expander to generate power, and an ion transport membrane assembly, wherein oxygen is separated from an oxygen-containing stream to be combusted in the combustor. Various embodiments of the power generation system and a process for generating power using the same are provided.

Phase-changing fuel compositions which can generate hydrogen are provided herein. The compositions can comprise a hydrogen carrier at least partially dissolved in a polar organic solvent. The hydrogen carrier includes ammonia borane and an alkylamine borane such as methylamine borane or methylenediamine bisborane. The hydrogen carrier act as the primary fuel source in the compositions and can be present in an amount of at least 60% by weight, based on the weight of the hydrogen generation composition. The hydrogen generation compositions are a liquid at temperatures of 5 C. or greater or 25 C. or greater. Methods for the production of hydrogen from the hydrogen generation compositions are further disclosed.

Methods, systems and apparatus relate to producing synthesis gas or carbon and hydrogen utilizing a reduced catalyst CuOFe.sub.2O.sub.3. The method comprises introducing CH.sub.4; reducing the CuOFe.sub.2O.sub.3 with the introduced CH.sub.4, yielding at least a reduced metal catalyst; oxidizing the reduced metal with O.sub.2 yielding CuOFe.sub.2O.sub.3; and generating heat that would be used for the hydrogen and carbon or syngas production with the reduced catalyst CuOFe.sub.2O.sub.3.

In one embodiment described herein, fuel may be converted into syngas by a method comprising feeding the fuel and composite metal oxides into a reduction reactor in a co-current flow pattern relative to one another, reducing the composite metal oxides with the fuel to form syngas and reduced composite metal oxides, transporting the reduced composite metal oxides to an oxidation reactor, regenerating the composite metal oxides by oxidizing the reduced composite metal oxides with an oxidizing reactant in the oxidation reactor, and recycling the regenerated composite metal oxides to the reduction reactor for subsequent reduction reactions to produce syngas. The composite metal oxides may be solid particles comprising a primary metal oxide and a secondary metal oxide.

A solids discharge system (SDS) is configured to separate solids from product gas. The system includes a solids separation device and at least one solids transfer conduit configured to receive solids from the solids separation device. The solids transfer conduit is selectively partitioned into a plurality of compartments (or sections) along its length by isolation valves. A gas supply conduit and a gas discharge conduits are connected to one of the sections to facilitate removal of solids. A filter in fluid communication with that section is configured to prevent solids from passing through the gas discharge conduit so that the solids can be removed from one of the sections of the solids transfer conduit. A product gas generation system incorporates first and second reactors, the latter of which receives products created by the second reactor.