Methods and systems for processing construction and demolition (C&D) materials to produce a product gas stream and/or electricity are disclosed herein. In some embodiments, the method comprises pre-processing C&D materials to produce a C&D feed, and processing the C&D feed to produce syngas. The C&D feed can comprise untreated wood, treated wood, paper and cardboard, yard waste, plastic, rubber, and/or foam. Processing the C&D feed can comprise gasifying the C&D feed, steam, and oxygen in a gasifier at a temperature of no more than 950 C. and/or a pressure of no more than 200 psi to produce syngas.

A method of producing hydrogen includes subliming a metal salt comprising a metal and a halide to yield a gas phase metal salt comprising the metal and the halide, and contacting the gas phase metal salt with a gas phase hydrocarbon to yield the metal in elemental form, carbon in elemental form, hydrogen gas, and a hydrogen halide comprising the halide.

The invention relates to a plant for production of hydrogen, and to a method for operating this plant, comprising a steam reforming reactor having a furnace, in which reactor water and at least one carbonaceous energy carrier are reacted to form a hydrogen-containing crude synthesis gas, and at least one cleaning device for purifying the crude synthesis gas, to which the crude synthesis gas is fed from the steam reforming via at least one feed line. According to the invention, upstream of one of the at least one cleaning devices at least one return line branches off from the feed line, through which the crude synthesis gas is at least in part recirculated into the furnace of the steam reforming reactor.

An integrated process for the production of a formaldehyde-stabilised urea is described comprising the steps of: (a) generating a synthesis gas comprising hydrogen, nitrogen, carbon monoxide, carbon dioxide and steam in a synthesis gas generation unit; (b) dividing the synthesis gas into a first synthesis gas stream and a smaller second synthesis gas stream; (c) subjecting the first synthesis gas stream to one or more stages of water-gas shift in one or more water-gas shift reactors to form a shifted gas; (d) cooling the shifted gas to below the dew point and recovering condensate to form a dried shifted gas; (e) recovering carbon dioxide from the dried shifted gas in a carbon dioxide removal unit to form a carbon dioxide-depleted synthesis gas; (f) subjecting the carbon dioxide-depleted synthesis gas to a stage of methanation in one or more methanation reactors to form an ammonia synthesis gas; (g) synthesising ammonia from the ammonia synthesis gas in an ammonia production unit and recovering the ammonia; (h) reacting a portion of the ammonia and at least a portion of the recovered carbon dioxide stream in a urea production unit to form a urea stream; and (i) stabilising the urea by mixing the urea stream and a stabiliser prepared using formaldehyde to form a stabilised urea, wherein the formaldehyde is generated by steps comprising; (1) passing the second portion of synthesis gas through a scrubber to remove contaminants therefrom and form a scrubbed synthesis gas; (2) synthesising methanol from the scrubbed synthesis gas in a methanol synthesis unit, and recovering the methanol and a methanol synthesis off-gas; (3) combining the methanol synthesis off-gas with the shifted gas and (4) subjecting at least a portion of the recovered methanol to oxidation with air in a formaldehyde stabiliser production unit to produce formaldehyde.

A hydrocarbon stream is combusted within a reactor to produce soot and syngas. Sub-stoichiometric combustion of the hydrocarbon stream within the reactor converts at least 10% of the carbon in the hydrocarbon stream into soot. The syngas is mixed with a steam stream to produce a hydrogenation feed stream. A shift reactor converts at least a portion of the carbon monoxide and steam to carbon dioxide and hydrogen to produce a shifted gas stream. Water is separated from the shifted gas stream to produce a dehydrated gas stream. The dehydrated gas stream is separated to produce a hydrogen product stream and a recycle stream. The recycle stream is recycled to the reactor.

Disclosed is a single process for producing hydrogen, carbon monoxide, and carbon from methane by forming gas products comprising hydrogen and carbon monoxide, and solid products comprising carbon and an iron-based catalyst from methane in a methane-containing feedstock through pyrolysis route involving auto-thermal reduction in a rotary kiln-type reactor in the presence of an iron-based catalyst and separating and recovering respective products.

A method of forming a tire-forming additive includes converting biomass to syngas; synthesizing at least one of benzene and an alkyl-substituted benzene, from carbon monoxide and hydrogen in the syngas; synthesizing at least one of aniline and an alkyl-substituted aniline from the at least one of the benzene and the alkyl-substituted benzene; and synthesizing a tire-forming additive from the at least one of the aniline and the alkyl-substituted aniline, the tire-forming additive being selected from the group consisting of an anti-degradant, a vulcanization accelerator, and combinations thereof.

Disclosed herein are systems (e.g., moving bed redox systems) and methods for supplying thermal energy to an endothermic chemical process.

A method of forming a tire-forming additive includes converting shredded tires/tire components to syngas; synthesizing at least one of benzene and an alkyl-substituted benzene, from carbon monoxide and hydrogen in the syngas; synthesizing at least one of aniline and an alkyl-substituted aniline from the at least one of the benzene and the alkyl-substituted benzene; and synthesizing a tire-forming additive from the at least one of the aniline and the alkyl-substituted aniline, the tire-forming additive being selected from the group consisting of an anti-degradant, a vulcanization accelerator, and combinations thereof.

The present invention relates to the integration of a membrane bio-reactor in a conventional hydrogen plant to remove ammonia and other organics such as methanol from the process condensate.