The invention relates to a plant for production of hydrogen, and to a method for operating this plant, comprising a steam reforming reactor having a furnace, in which reactor water and at least one carbonaceous energy carrier are reacted to form a hydrogen-containing crude synthesis gas, and at least one cleaning device for purifying the crude synthesis gas, to which the crude synthesis gas is fed from the steam reforming via at least one feed line. According to the invention, upstream of one of the at least one cleaning devices at least one return line branches off from the feed line, through which the crude synthesis gas is at least in part recirculated into the furnace of the steam reforming reactor.

A method of generating a reaction product from a feedstock via a centrifuge reactor that includes introducing a flow of feedstock to a centrifuge reactor, the centrifuge reactor including: a central rotational axis X, and a centrifuge assembly having a reaction chamber with the centrifuge assembly configured to rotate about the central rotational axis X. The method further includes rotating the centrifuge assembly about the central rotational axis X at a tip speed to generate an acceleration gradient from the central rotational axis X and from a first reaction chamber end to a second reaction chamber end and generating reaction conditions in the reaction chamber, the reaction conditions and acceleration gradient causing a separation of products from a reaction of the feedstock within the reaction chamber.

The invention is directed to a process for the preparation of a syngas comprising hydrogen and carbon monoxide from a methane comprising gas, which process comprises the steps of: (a) reacting the methane comprising gas with an oxidising gas in an autothermal reformer to obtain a hot raw syngas comprising carbon monoxide and hydrogen; (b) cooling the hot raw syngas resulting from step (a) to obtain the syngas, wherein step (b) comprises cooling the hot raw syngas by indirect heat exchange against the methane comprising gas used in step (a) and wherein sulphur is added upstream of cooling step (b). The invention also relates to a process for the preparation of hydrocarbon products in which a feed syngas is prepared in the process as described above followed by a desulphurisation treatment and the desulphurised syngas is subsequently converted into hydrocarbon products in a Fischer-Tropsch process.

A system and method for converting waste and secondary materials into synthesis gas (syngas) through the use of a molten metal bath gasifier for the initial breakdown of waste feeds and an A/C plasma reactor for complete dissociation of waste feeds into syngas, and an anaerobic digester. The system includes a heat recovery and steam power generation process for the production of electricity. The system produces a net output of electricity above plant load sufficient for the co-production of renewable Hydrogen and Oxygen. The process does not require the use of fossil fuels or fossil feedstocks during normal operations, and it eliminates combustion produced stack emissions or landfill residuals.

Disclosed is a hydrocarbon gas reforming supported catalyst, and methods for its use, that includes a catalytic material capable of catalyzing the production of a gaseous mixture comprising hydrogen (H.sub.2) and carbon monoxide (CO) from a hydrocarbon gas and a clay support material comprising a clay mineral, wherein the catalytic material is chemically bonded to the clay support material, and wherein the chemical bond is a M1-M2 bond, where M1 is a metal from the catalytic material and M2 is a metal from the clay support material, or the chemical bond is a M1-O bond, where M1 is a metal from the catalytic material and oxygen (O) is from the clay support material, wherein the supported catalyst comprises at least 70% or more by weight of the clay support material.

A heat recovery system for plasma reformers is comprised of a cascade of regenerators and recuperators that are arranged to transfer in stages the heat at high temperatures for storage, transport, and recirculation. Recirculation of heat increases the efficiency of plasma reformers and heat exchanging reduces temperature of the product for downstream applications.

The present invention comprises a process for producing hydrogen, wherein in a first stage hydrocarbons are decomposed into solid carbon and into a hydrogen-containing gaseous product mixture, the hydrogen-containing gaseous product mixture, which has a composition in respect of the main components CH4, N2, and H2 of 20% to 95% by volume H2 and 80% to 5% by volume CH4 and/or N2, is discharged from the first stage at a temperature of 50 to 300° C., and this is supplied at a temperature differing from this exit temperature by not more than 100° C. to an electrochemical separation process and, in this second stage, the hydrogen-containing product mixture is separated in the electrochemical separation process at a temperature of 50 to 200° C. into hydrogen having a purity of >99.99% and a remaining residual gas mixture.

Disclosed is a lanthanide oxide coated catalyst, and methods for its use, that includes a supported catalyst comprising a support material, a catalytic material, and a lanthanide oxide, wherein the lanthanide oxide is attached to at least a portion of the surface of the supported catalyst.

In a process for the elimination of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) formed as by-products in the shift section (SS) of an ammonia plant, a carbon dioxide (C0.sub.2) stream from a vent line, which is arranged downstream from the shift section and the C0.sub.2 removal section, is recycled to the primary reformer (TR) of the ammonia plant. This way, the oxygenates contained in the carbon dioxide vent will be decomposed in the primary reformer burners, and the total emission of VOCs and HAPs will be considerably reduced.

A carbonaceous substance dry powder gasification device and method, the device comprising from bottom to top a lower cooling and purification section (1), a gasification reaction section (2), a cooling reaction section (3) and an upper cooling and purification section (4); an initial cooling device is disposed at the connection between the cooling reaction section and the gasification reaction section; and a plurality of nozzles are circumferentially arranged in the gasification reaction section. The method comprises: a gasification reaction is conducted between a carbonaceous substance and an oxygenated gasifying agent to generate crude synthesis gas and ash; part of the crude synthesis gas and most of the ash go downstream for cooling and gasification, and the cooled and ash removed crude synthesis gas is transferred to subsequent processes, and the quenched ash is discharged through an ash outlet; the remaining crude synthesis gas and fly ash go upstream to mix with a cooling substance for cooling, and then are transferred to the cooling reaction section for reacting with the incompletely reacted carbon and added gasification agent; the crude synthesis gas and the fly ash are cooled and purified to remove the fly ash, and the clean low-temperature crude synthesis gas is transferred to subsequent processes. The method avoids ash blocking at an ash outlet in an upstream air-exhaust method, and also avoids overheating at the top in a downstream air-exhaust method, thus improving the carbon conversion rate.